Thermal rearrangements in the tetra-arylcyclopropene series

The literature provides many examples of thermal rearrangements of small-ring compounds to yield systems involving less bond-angle strain. In the arylcyclopropene series these involve, in many cases, fairly complex pathways, and only formalized mechanisms have been suggested

Modified Korteweg-de Vries Hierachies in Multiple-Times Variables and the Solutions of Modified Boussinesq Equations

We study solitary-wave and kink-wave solutions of a modified Boussinesq equation through a multiple-time reductive perturbation method. We use appropriated modified Korteweg-de Vries hierarchies to eliminate secular producing terms in each order of the perturbative scheme. We show that the multiple-time variables needed to obtain a regular perturbative series are completely determined by the associated linear theory in the case of a solitary-wave solution, but requires the knowledge of each order of the perturbative series in the case of a kink-wave solution. These appropriate multiple-time variables allow us to show that the solitary-wave as well as the kink-wave solutions of the modified Botussinesq equation are actually respectively a solitary-wave and a kink-wave satisfying all the equations of suitable modified Korteweg-de Vries hierarchies.Comment: RevTex file, submitted to Proc. Roy. Soc. London

Reliability analysis of dynamic systems by translating temporal fault trees into Bayesian networks

Classical combinatorial fault trees can be used to assess combinations of failures but are unable to capture sequences of faults, which are important in complex dynamic systems. A number of proposed techniques extend fault tree analysis for dynamic systems. One of such technique, Pandora, introduces temporal gates to capture the sequencing of events and allows qualitative analysis of temporal fault trees. Pandora can be easily integrated in model-based design and analysis techniques. It is, therefore, useful to explore the possible avenues for quantitative analysis of Pandora temporal fault trees, and we identify Bayesian Networks as a possible framework for such analysis. We describe how Pandora fault trees can be translated to Bayesian Networks for dynamic dependability analysis and demonstrate the process on a simplified fuel system model. The conversion facilitates predictive reliability analysis of Pandora fault trees, but also opens the way for post-hoc diagnostic analysis of failures

The Potassium abundance in the globular clusters NGC104, NGC6752 and NGC6809

We derived Potassium abundances in red giant branch stars in the Galactic globular clusters NGC104 (144 stars), NGC6752 (134 stars) and NGC6809 (151 stars) using high-resolution spectra collected with FLAMES at the ESO - Very Large Telescope. In the considered samples we do not find significant intrinsic spreads in [K/Fe] (confirming the previous findings by Carretta et al.), at variance with the cases of the massive clusters NGC2419 and NGC2808. Additionally, marginally significant [K/Fe]-[O/Fe] anti-correlations are found in NGC104 and NGC6809, and [K/Fe]-[Na/Fe] correlations are found in NGC104 and NGC6752. No evidence of [K/Fe]-[Mg/Fe] anti-correlation are found. The results of our analysis are consistent with a scenario in which the process leading to the multi-populations in globular clusters implies also enrichment in the K abundance, the amplitude of the associated [K/Fe] enhancement becoming measurable only in stars showing the most extreme effects of O and Mg depletion. Stars enhanced in [K/Fe] have been found so far only in clusters harbouring some Mg-poor stars, while the other globulars, without a Mg-poor sub-population, show small or null [K/Fe] spreads.Comment: 9 pages, 7 figures, 3 tables, accepted for publication in A&

The Impacts of Farm Size and Economic Risk on No-Till Rice Whole-Farm Profitability

This study evaluated the impacts of farm size and stochastic return variability on no-till (NT) rice profitability at the whole-farm level. Mixed integer programming was used to determine optimal machinery complements, fuel consumption, and machinery labor requirements for conventional till (CT) and NT rice-soybean farms of 1200, 2400, and 3600 acres in size. Crop yields, market prices, and prices for key production inputs were simulated to construct stochastic whole-farm net returns for each farm size under CT and NT management, and both first and second degree stochastic dominance analysis were used to rank cumulative distribution functions of whole-farm returns according to specified risk preferences. The results indicate NT farms exhibit second degree stochastic dominance over CT farms regardless of farm size, and high input prices have less downward effect on the profitability of NT farms relative to CT farms.mixed integer programming, no-till, profitability, rice, risk, simulation, stochastic dominance, whole-farm, Farm Management, Production Economics, Risk and Uncertainty,

Potassium: a new actor on the globular cluster chemical evolution stage. The case of NGC 2808

We derive [K/Fe] abundance ratios for 119 stars in the globular cluster NGC 2808, all of them having O, Na, Mg and Al abundances homogeneously measured in previous works. We detect an intrinsic star-to-star spread in the Potassium abundance. Moreover [K/Fe] abundance ratios display statistically significant correlations with [Na/Fe] and [Al/Fe], and anti-correlations with [O/Fe] and [Mg/Fe]. All the four Mg deficient stars ([Mg/Fe]<0.0) discovered so far in NGC 2808 are enriched in K by ~0.3 dex with respect to those with normal [Mg/Fe]. NGC 2808 is the second globular cluster, after NGC 2419, where a clear Mg-K anti-correlation is detected, albeit of weaker amplitude. The simultaneous correlation/anti-correlation of [K/Fe] with all the light elements usually involved in the chemical anomalies observed in globular cluster stars, strongly support the idea that these abundance patterns are due to the same self-enrichment mechanism that produces Na-O and Mg-Al anti-correlations. This finding suggests that detectable spreads in K abundances may be typical in the massive globular clusters where the self-enrichment processes are observed to produce their most extreme manifestations.Comment: Accepted for publication by ApJ, 5 pages, 3 figure

IP Eri: A surprising long-period binary system hosting a He white dwarf

We determine the orbital elements for the K0 IV + white dwarf (WD) system IP Eri, which appears to have a surprisingly long period of 1071 d and a significant eccentricity of 0.25. Previous spectroscopic analyses of the WD, based on a distance of 101 pc inferred from its Hipparcos parallax, yielded a mass of only 0.43 M$_\odot$, implying it to be a helium-core WD. The orbital properties of IP Eri are similar to those of the newly discovered long-period subdwarf B star (sdB) binaries, which involve stars with He-burning cores surrounded by extremely thin H envelopes, and are therefore close relatives to He WDs. We performed a spectroscopic analysis of high-resolution spectra from the HERMES/Mercator spectrograph and concluded that the atmospheric parameters of the K0 component are $T_{\rm eff} = 4960$ K, $\log{g} = 3.3$, [Fe/H] = 0.09 and $\xi = 1.5$ km/s. The detailed abundance analysis focuses on C, N, O abundances, carbon isotopic ratio, light (Na, Mg, Al, Si, Ca, Ti) and s-process (Sr, Y, Zr, Ba, La, Ce, Nd) elements. We conclude that IP Eri abundances agree with those of normal field stars of the same metallicity. The long period and non-null eccentricity indicate that this system cannot be the end product of a common-envelope phase; it calls instead for another less catastrophic binary-evolution channel presented in detail in a companion paper (Siess et al. 2014).Comment: 14 pages, 10 figures, 4 tables, accepted for publication in A&A (Update of Table 3, Fig. 8 and text in Sect. 5.1, 5.3 and 6 due to minor corrections on N and Y II

The Elements of the Neutrino Mass Matrix: Allowed Ranges and Implications of Texture Zeros

We study the range of the elements of the neutrino mass matrix m_nu in the charged lepton basis. Neutrino-less double beta decay is sensitive to the ee element of m_nu. We then analyze the phenomenological implications of single texture zeros. In particular, interesting predictions for the effective mass can be obtained, in the sense that typically only little cancellation due to the Majorana phases is expected. Some cases imply constraints on the atmospheric neutrino mixing angle.Comment: 21 pages, 7 figures. Minor corrections, matches version in PR

An Economic Risk Analysis of Tillage and Cropping Systems on the Arkansas Grand Prairie

No-till (NT) has been shown to reduce fuel, labor, and machinery costs compared to conventional-till (CT) but very few rice producers in Arkansas practice NT. The low adoption rate is most likely due to difficulties in management but also limited information on the profitability and risk of NT. Most rice producers are knowledgeable on NT costs savings but consider it less profitable due to yield reductions offsetting costs savings. This study evaluates production costs, crop yields, and economic risk of both NT and CT in five rice-based cropping systems (continuous rice, rice-soybean, rice-corn, rice-wheat, and rice-wheat-soybean-wheat). Yields, crop prices, and key input prices are simulated to create net return distributions. Stochastic efficiency with respect to a function (SERF) is used to evaluate profitability and risk efficiency. Results indicate that a risk-neutral and risk-averse producer in either NT or CT would prefer a rice-soybean rotation. NT would be preferred over CT in the rice-soybean rotation across all risk preferences. Overall, risk-neutral producers would prefer NT in four of five cropping systems while risk-averse producers would prefer NT in three of five cropping systems.cropping systems, rice, no-till, certainty equivalent, risk premium, Crop Production/Industries, Farm Management, Financial Economics, Land Economics/Use, Production Economics, Risk and Uncertainty,