536 research outputs found
L1521E: A Starless Core in the Early Evolutionary Stage ?
We have studied the physical and chemical properties of a quiescent starless
core L1521E with various molecular lines. It is found that there exists a
compact dense core traced by the H^13CO^+, HN^13C, CCS, and HC_3N lines; their
distributions have a single peak at the same position. The core radius is as
small as 0.031 pc, whereas the H_2 density at the peak position is as high as
(1.3-5.6)times10^5 cm^-3. Although the density is high enough to excite the
inversion transitions of NH_3, these lines are found to be very faint in
L1521E. The distributions of NH_3 and CCS seem to be different from those of
well-studied starless cores, L1498 and L1544, where the distribution of CCS
shows a shell-like structure while that of NH_3 is concentrated at the center
of the core. Abundances of carbon-chain molecules are higher in L1521E than the
other dark cloud cores, and especially those of sulfur-bearing molecules C_nS
are comparable to the cyanopolyyne peak of TMC-1. Our results suggest that
L1521E would be in a very early stage of physical and chemical evolution.Comment: 10 pages, 3 EPS figures, uses aaspp4.sty and epsf.sty, AAS LaTeX
macros v4.0, The Astrophysical Journal, in pres
Mapping Observations of DNC and HN^13C in Dark Cloud Cores
We present results of mapping observations of the DNC, HN^13C, and H^13CO^+
lines (J=1-0) toward 4 nearby dark cloud cores, TMC-1, L1512, L1544, and L63,
along with observations of the DNC and HN^13C lines (J=2-1) toward selected
positions. By use of statistical equilibrium calculations based on the LVG
model, the H_2 densities are derived to be (1.4-5.5)*10^5 cm^-3, and the
[DNC]/[HN^13C] ratios are derived to be 1.25-5.44 with a typical uncertainty by
a factor of 2. The observed [DNC]/[HNC] ratios range from 0.02 to 0.09,
assuming the [^12C]/[^13C] ratio of 60. Distributions of DNC and HN^13C are
generally similar to each other, whereas the distribution of H^13CO^+ is more
extended than those of DNC and HN^13C, indicating that they reside in an inner
part of the cores than HCO^+. The [DNC]/[HN^13C] ratio is rather constant
within each core, although a small systematic gradients are observed in TMC-1
and L63. Particularly, no such systematic gradient is found in L1512 and L1544,
where a significant effect of depletion of molecules is reported toward the
central part of the cores. This suggests that the [DNC]/[HNC] ratio would not
be very sensitive to depletion factor, unlike the [DCO^+]/[HCO^+] ratio. On the
other hand, the core to core variation of the [DNC]/[HNC] ratio, which range an
order of magnitude, is more remarkable than the variation within each core.
These results are interpreted qualitatively by a combination of three competing
time-dependent processes; gas-phase deuterium fractionation, depletion of
molecules onto grain surface, and dynamical evolution of a core.Comment: 22 pages, 8 EPS figures, aasLaTex 5.0, accepted to The Astrophysical
Journa
Quantum states and linear response in dc and electromagnetic fields for charge current and spin polarization of electrons at Bi/Si interface with giant spin-orbit coupling
An expansion of the nearly free-electron model constructed by Frantzeskakis,
Pons and Grioni [Phys. Rev. B {\bf 82}, 085440 (2010)] describing quantum
states at Bi/Si(111) interface with giant spin-orbit coupling is developed and
applied for the band structure and spin polarization calculation, as well as
for the linear response analysis for charge current and induced spin caused by
dc field and by electromagnetic radiation. It is found that the large
spin-orbit coupling in this system may allow resolving the spin-dependent
properties even at room temperature and at realistic collision rate. The
geometry of the atomic lattice combined with spin-orbit coupling leads to an
anisotropic response both for current and spin components related to the
orientation of the external field. The in-plane dc electric field produces only
the in-plane components of spin in the sample while both the in-plane and
out-of-plane spin components can be excited by normally propagating
electromagnetic wave with different polarizations.Comment: 10 pages, 9 figure
On the Influence of Uncertainties in Chemical Reaction Rates on Results of the Astrochemical Modelling
With the chemical reaction rate database UMIST95 (Millar et al. 1997) we
analyze how uncertainties in rate constants of gas-phase chemical reactions
influence the modelling of molecular abundances in the interstellar medium.
Random variations are introduced into the rate constants to estimate the
scatter in theoretical abundances. Calculations are performed for dark and
translucent molecular clouds where gas phase chemistry is adequate. Similar
approach was used by Pineau des Forets & Roueff (2000) for the study of
chemical bistability. All the species are divided into 6 sensitivity groups
according to the value of the scatter in their model abundances computed with
varied rate constants. It is shown that the distribution of species within
these groups depends on the number of atoms in a molecule and on the adopted
physical conditions. The simple method is suggested which allows to single out
reactions that are most important for the evolution of a given species.Comment: 4 pages. To appear in the proceedings of the 4th Cologne-Bonn Zermatt
Symposiu
Low energy high angular resolution neutral atom detection by means of micro-shuttering techniques: the BepiColombo SERENA/ELENA sensor
The neutral sensor ELENA (Emitted Low-Energy Neutral Atoms) for the ESA
cornerstone BepiColombo mission to Mercury (in the SERENA instrument package)
is a new kind of low energetic neutral atoms instrument, mostly devoted to
sputtering emission from planetary surfaces, from E ~20 eV up to E~5 keV,
within 1-D (2x76 deg). ELENA is a Time-of-Flight (TOF) system, based on
oscillating shutter (operated at frequencies up to a 100 kHz) and mechanical
gratings: the incoming neutral particles directly impinge upon the entrance
with a definite timing (START) and arrive to a STOP detector after a flight
path. After a brief dissertation on the achievable scientific objectives, this
paper describes the instrument, with the new design techniques approached for
the neutral particles identification and the nano-techniques used for designing
and manufacturing the nano-structure shuttering core of the ELENA sensor. The
expected count-rates, based on the Hermean environment features, are shortly
presented and discussed. Such design technologies could be fruitfully exported
to different applications for planetary exploration.Comment: 11 page
Hierarchically Porous ZSM-5 Synthesized by Nonionic- and Cationic-Templating Routes and Their Catalytic Activity in Liquid-Phase Esterification
Hierarchically porous MFI zeolites (ZSM-5) have been synthesized by hydrothermal treatment in the presence of trialkoxysilylated-derivatives of nonionic poly(oxyethylene) alkyl ether or alkyl quaternary ammonium cation as mesopore-generating agent, along with tetrapropylammonium cation as zeolite structure-directing agent. Powder X-ray diffraction revealed that zeolites have been crystallized, and scanning electron microscopy showed rugged surface morphology that was quite different from conventional ZSM-5. The mesoporosity was confirmed by nitrogen adsorption-desorption measurement showing type IV isotherms with narrow distribution of mesopore diameters. The catalytic activity of these mesoporous ZSM-5 was tested in liquid-phase esterification of benzyl alcohol with hexanoic acid. The conversion of benzyl alcohol on mesoporous ZSM-5 prepared via cationic-templating route was almost 100%, being much higher than on mesoporous ZSM-5 prepared with silylated nonionic surfactant as well as on conventional ZSM-5 with no mesopores. The presence of Brønsted acid sites, together with the mesopores, was responsible for this catalytic conversion, as confirmed by pyridine adsorption monitored by in situ infrared and 27Al magic angle spinning nuclear magnetic resonance spectroscopy
Future evolution of an eddy rich ocean associated with enhanced east Atlantic storminess in a coupled model projection
Improved representation of air-sea fluxes afforded by eddy-rich oceans in high-resolution coupled ocean-atmosphere models may modify the tracks and intensity of storms and their response to climate change. We examine changes in winter surface ocean conditions and storminess associated with moving from an eddy-permitting (1/4°, HM) to an eddy-rich (1/12°, HH) ocean in control and climate change (SSP585) simulations of the HadGEM3-GC3.1 model in which atmosphere resolution is kept at 25 km. Differences in North Atlantic climate in the control runs stem from a revised location of the Gulf Stream in the eddy-rich model. Projections reveal greater warming in the western Atlantic in HH than HM and a pronounced increase in eastern Atlantic storminess with changes six times greater than in the eddy-permitting model. This increase is associated with the distinctive long-term evolution of the North Atlantic warming hole and the Gulf Stream separation in the eddy-rich model
Electronic transport, structure, and energetics of endohedral Gd@C82 metallofullerenes
Electronic structure and transport properties of the fullerene C and
the metallofullerene Gd@C are investigated with density functional
theory and the Landauer-Buttiker formalism. The ground state structure of
Gd@C is found to have the Gd atom below the C-C bond on the C
molecular axis of C. Insertion of Gd into C deforms the carbon
chain in the vicinity of the Gd atoms. Significant overlap of the electron
distribution is found between Gd and the C cage, with the transferred Gd
electron density localized mainly on the nearest carbon atoms. This charge
localization reduces some of the conducting channels for the transport, causing
a reduction in the conductivity of the Gd@C species relative to the
empty C molecule. The electron transport across the metallofullerene is
found to be insensitive to the spin state of the Gd atom.Comment: 13 pages, 7 figures, submitted Nano Let
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