ICT approaches to integrating institutional and non-institutional data services for better understanding of hydro-meteorological phenomena

It is widely recognised that an effective exploitation of Information and Communication Technologies (ICT) is an enabling factor to achieve major advancements in Hydro-Meteorological Research (HMR). Recently, a lot of attention has been devoted to the use of ICT in HMR activities, e.g. in order to facilitate data exchange and integration, to improve computational capabilities and consequently model resolution and quality. Nowadays, ICT technologies have demonstrated that it is possible to extend monitoring networks by integrating sensors and other sources of data managed by volunteer's communities. These networks are constituted by peers that span a wide portion of the territory in many countries. The peers are "location aware" in the sense that they provide information strictly related with their geospatial location. The coverage of these networks, in general, is not uniform and the location of peers may follow random distribution. The ICT features used to set up the network are lightweight and user friendly, thus, permitting the peers to join the network without the necessity of specialised ICT knowledge. In this perspective it is of increasing interest for HMR activities to elaborate of Personal Weather Station (PWS) networks, capable to provide almost real-time, location aware, weather data. <br><br> Moreover, different big players of the web arena are now providing world-wide backbones, suitable to present on detailed map location aware information, obtained by mashing up data from different sources. This is the case, for example, with Google Earth and Google Maps. <br><br> This paper presents the design of a mashup application aimed at aggregating, refining and visualizing near real-time hydro-meteorological datasets. In particular, we focused on the integration of instant precipitation depths, registered either by widespread semi-professional weather stations and official ones. This sort of information has high importance and usefulness in decision support systems and Civil Protection applications. As a significant case study, we analysed the rainfall data observed during the severe flash-flood event of 4 November 2011 over Liguria region, Italy. The joint use of official observation network with PWS networks and meteorological radar allowed for the making of evident finger-like convection structure

A Critical Analysis on the Current Design Criteria for Cathodic Protection of Ships and Superyachts

Classification Society and ISO standard regulate the design of cathodic protection (CP) plans of ships and superyachts. However, due to shipyards’ long experience, the hull vessel protection plans often rely on an adaptation of previous CP designs for similar ships. This simple practice could expose ships to low protection or overprotection. Here, the protection plan of an existing 42 m superyacht is considered to highlight critical CP design issues. The numerical analysis gives evidence of discrepancies between the CP design proposed in accordance with ISO standard and the protection plan that was actually implemented. Indeed, for a proper protection plan, the anode weight according to the ISO standard is 2.7 kg, whereas the real protection plan uses a 7 kg anode. The numerical optimization highlights an optimal anode mass of 5 kg (−28.5% in weight). It provides sufficient protection for the expected lifetime, and will preserve the system in cases of damage to the hull and a consequent increase in the breakdown factor. This new solution underlines the importance and necessity of improving cathodic protection plan design

Application of electro-fenton process for the treatment of methylene blue

The electrochemical removal of an aqueous solution containing 0.25 mM of methylene blue (MB), one of the most important thiazine dye, has been investigated by electro-Fenton process using a graphite-felt cathode to electrogenerate in situ hydrogen peroxide and regenerate ferrous ions as catalyst. The effect of operating conditions such as applied current, catalyst concentration, and initial dye content on MB degradation has been studied. MB removal and mineralization were monitored during the electrolysis by UV\u2013Vis analysis and TOC measurements. The experimental results showed that MB was completely removed by the reaction with \u2022OH radicals generated from electrochemically assisted Fenton\u2019s reaction, and in any conditions the decay kinetic always follows a pseudo-first-order reaction. The faster MB oxidation rate was obtained applying a current of 300 mA, with 0.3 mM Fe2+at T=35 \ub0C. In these conditions, 0.25 mM MB was completely removed in 45 min and the initial TOC was removed in 90 min of electrolysis, meaning the almost complete mineralization of the organic content of the treated solution

A Performance-Based Methodology to Improve Grid Exploitation

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Characterisation of La0.6Sr0.4Co0.2Fe0.8O3-\u3b4- Ba0.5Sr0.5Co0.8Fe0.2O3-\u3b4composite as cathode for solid oxide fuel cells

Mixture of La0.6Sr0.4Co0.2Fe0.8O3-\u3b4 and Ba0.5Sr0.5Co0.8Fe0.2O3-\u3b4, was investigated as promising cathode for intermediate temperature solid oxide fuel cells (IT-SOFCs). The two perovskites possess high catalytic activity for the oxygen reduction (ORR), although some problems related to their chemical and structural stability have still to be overcome in view of improving durability of the cell performance. The achievement of a stable and high-performing composite material is the aim of this study. In principle, chemical equilibrium at the LSCF-BSCF interface may be reached through ions interdiffusion during the sintering process, resulting in the chemical stabilization of the material. The composite-cathode deposited on Ce0.8Sm0.2O2-\u3b4 electrolyte was then investigated by Electrochemical Impedance Spectroscopy (EIS) as a function of temperature, overpotential and time. The results exhibited an interesting electrochemical behavior of the electrode toward oxygen reduction reaction. XRD analysis was performed to detect structural modification during thermal or operation stages and it was found that after the sintering the two starting perovskites were no longer present; a new phase with a rhombohedral La0,4Sr0,6FeO3-type structure (LSF) is formed. An improvement in composite cathode durability has been detected under the considered operating conditions (200 mAcm-2, 700 \ub0C) in comparison with the pure BSCF electrode. The results confirmed this new electrode as promising system for further investigation as IT-SOFC cathode

A Comprehensive Approach to Improve Performance and Stability of State-of-the- Art Air Electrodes for Intermediate Temperature Reversible Cells: An Impedance Spectroscopy Analysis

Solid oxide fuel cells (SOFC) are devices for the transformation of chemical energy in electrical energy. SOFC appear very promising for their very high efficiency, in addition to the capability to work in reverse mode, which makes them suitable for integration in production units powered with renewables. Research efforts are currently addressed to find chemically and structurally stable materials, in order to improve performance stability during long-term operation. In this work, we examine different approaches for improving stability of two state-of-the-art perovskite materials, La0.6Sr0.4Co0.2Fe0.8O3-\uf064 (LSCF) and Ba0.5Sr0.5Co0.8Fe0.2O3-\uf064 (BSCF), very promising as air electrodes. Two different systems are considered: (i) LSCF and BSCF porous electrodes impregnated by a nano-sized La0.8Sr0.2MnO3-\uf064 layer and (ii) LSCF-BSCF composites with the two phases in different volume proportions. The study considers the results obtained by electrochemical impedance spectroscopy investigation, observing the polarisation resistance (Rp) of each system to evaluate performance in typical SOFC operating conditions. Furthermore, the behaviour of polarisation resistance under the effect of a net current load (cathodic) circulating for hundreds of hours is examined, as parameter to evaluate long-term performance stability

Hydrometeorological multi-model ensemble simulations of the 4 November 2011 flash flood event in Genoa, Italy, in the framework of the DRIHM Project

The e-Science environment developed in the framework of the EU-funded DRIHM project was used to demonstrate its ability to provide relevant, meaningful hydrometeorological forecasts. This was illustrated for the tragic case of 4 November 2011, when Genoa, Italy, was flooded as the result of heavy, convective precipitation that inundated the Bisagno catchment. The Meteorological Model Bridge (MMB), an innovative software component developed within the DRIHM project for the interoperability of meteorological and hydrological models, is a key component of the DRIHM e-Science environment. The MMB allowed three different rainfall-discharge models (DRiFt, RIBS and HBV) to be driven by four mesoscale limited-area atmospheric models (WRF-NMM, WRF-ARW, Meso-NH and AROME) and a downscaling algorithm (RainFARM) in a seamless fashion. In addition to this multi-model configuration, some of the models were run in probabilistic mode, thus giving a comprehensive account of modelling errors and a very large amount of likely hydrometeorological scenarios (> 1500). The multi-model approach proved to be necessary because, whilst various aspects of the event were successfully simulated by different models, none of the models reproduced all of these aspects correctly. It was shown that the resulting set of simulations helped identify key atmospheric processes responsible for the large rainfall accumulations over the Bisagno basin. The DRIHM e-Science environment facilitated an evaluation of the sensitivity to atmospheric and hydrological modelling errors. This showed that both had a significant impact on predicted discharges, the former being larger than the latter. Finally, the usefulness of the set of hydrometeorological simulations was assessed from a flash flood early-warning perspective