Defect chemistry of Ti and Fe impurities and aggregates in Al2O3

We report a theoretical evaluation of the properties of iron and titanium impurities in sapphire (corundum structured α-Al2O3). Calculations using analytical force fields have been performed on the defect structure with the metals present in isolated, co-doped and tri-cluster configurations. Crystal field parameters have been calculated with good agreement to available experimental data. When titanium and iron are present in neighbouring face and edge-sharing orientations, the overlap of the d-orbitals facilitates an intervalence charge transfer (FeIII/TiIII → FeII/TiIV) with an associated optical excitation energy of 1.85 eV and 1.76 eV in the respective configurations. Electronic structure calculations based on density functional theory confirm that FeIII/TiIII is the ground-state configuration for the nearest-neighbour pairs, in contrast to the often considered FeII/TiIV pair. Homonuclear intervalence charge transfer energies between both FeIII/FeII and TiIV/TiIII species have also been calculated, with the energy lying in the infra-red region. Investigation of multiple tri-clusters of iron and titanium identified one stable configuration, TiIII–(TiIV/FeII), with the energy of electron transfer remaining unchanged

Microscopic origin of the optical processes in blue sapphire

Al2O3 changes from transparent to a range of intense colours depending on the chemical impurities present. In blue sapphire, Fe and Ti are incorporated; however, the chemical process that gives rise to the colour has long been debated. Atomistic modelling identifies charge transfer from Ti(III) to Fe(III) as being responsible for the characteristic blue appearance

Terahertz Waveguiding in Silicon-Core Fibers

We propose the use of a silicon-core optical fiber for terahertz (THz) waveguide applications. Finite-difference time-domain simulations have been performed based on a cylindrical waveguide with a silicon core and silica cladding. High-resistivity silicon has a flat dispersion over a 0.1 - 3 THz range, making it viable for propagation of tunable narrowband CW THz and possibly broadband picosecond pules of THz radiation. Simulations show the propagation dynamics and the integrated intensity, from which transverse mode profiles and absorption lengths are extraced. It is found that for 140 - 250 micron core diameters the mode is primarily confined to the core, such that the overall absorbance is only slightly less than in bulk polycrystalline silicon.Comment: 6 pages, 3 figures, journal submissio

Ultrastructure of the anterior organ and posteriorfunnel-shaped canal of Gyrocotyle urna Wagener, 1852(Cestoda: Gyrocotylidea)

Using scanning and transmission electron microscopy, ultrastructure of the anterior organ and posterior funnel-shaped canal of Gyrocotyle urna Wagener, 1852 (Cestoda: Gyrocotylidea) from ratfish, Chimaera monstrosa (Holocephali), was studied for the first time. The proper anterior organ is localised at a short distance (about 170 µm) from an apical pore surrounded by a receptor field, whereas its distal end is marked by a muscular sphincter. The tegumental surface of this organ is covered with short filitriches of irregular length; large area of muscle layers traverse beneath the tegumental layer. The funnel-shaped canal of G. urna (2.5-3.0 mm long) is a specialised, muscular part of the posterior attachment organ; it opens on the rounded elevation on the dorsal body surface. The tegumental layer bears conical sclerite-like structures (up to 1.5 µm long). It produces electron-dense bodies that are transported into a canal lumen and surrounded thick muscle area mixed with numerous nerve fibres. The present ultrastructural study of G. urna indicates that gyrocotylideans share some ultrastructural characters of the anterior organ with spathebothriidean cestodes with a single anterior attachment sucker-like organ. In contrast, the unique posterior rosette attachment organ with funnel-shaped canal of the Gyrocotylidea resembles the haptor of polyopisthocotylean monogeneans in its position at the posterior end of the body and presumed origin. The above-mentioned features add more clarity to support the basal position of the Gyrocotylidea Poche, 1926 among cestodes. In addition, they also indicate a possible relationship of gyrocotylidean ancestors with monogeneans.publishedVersio

Inhibition of histone deacetylase as a treatment for cardiac hypertrophy

The present invention provides for methods of treating and preventing cardiac hypertrophy. Class II HDACs, which are known to participate in regulation of chromatin structure and gene expression, have been shown to have beneficial effects on cardiac hypertrophy. Surprisingly, the present invention demonstrates that HDAC inhibitors inhibit cardiac hypertrophy by inhibiting fetal cardiac gene expression and interfering with sarcomeric organization.Board of Regents, University of Texas Syste

Weighting Matrix Design for Robust Monotonic Convergence in Norm Optimal Iterative Learning Control

In this paper we examine the robustness of norm optimal ILC with quadratic cost criterion for discrete-time, linear time-invariant, single-input single-output systems. A bounded multiplicative uncertainty model is used to describe the uncertain system and a sufficient condition for robust monotonic convergence is developed. We find that, for sufficiently large uncertainty, the performance weighting can not be selected arbitrarily large, and thus overall performance is limited. To maximize available performance, a time-frequency design methodology is presented to shape the weighting matrix based on the initial tracking error. The design is applied to a nanopositioning system and simulation results are presented

Aircraft aerodynamic prediction method for V/STOL transition including flow separation

A numerical procedure was developed for the aerodynamic force and moment analysis of V/STOL aircraft operating in the transition regime between hover and conventional forward flight. The trajectories, cross sectional area variations, and mass entrainment rates of the jets are calculated by the Adler-Baron Jet-in-Crossflow Program. The inviscid effects of the interaction between the jets and airframe on the aerodynamic properties are determined by use of the MCAIR 3-D Subsonic properties are determined by use of the MCAIR 3-D Subsonic Potential Flow Program, a surface panel method. In addition, the MCAIR 3-D Geometry influence Coefficient Program is used to calculate a matrix of partial derivatives that represent the rate of change of the inviscid aerodynamic properties with respect to arbitrary changes in the effective wing shape

Mode mixing in asymmetric double trench photonic crystal waveguides

e investigate both experimentally and theoretically the waveguiding properties of a novel double trench waveguide where a conventional single-mode strip waveguide is embedded in a two dimensional photonic crystal (PhC) slab formed in silicon on insulator (SOI) wafers. We demonstrate that the bandwidth for relatively low-loss (50dB/cm) waveguiding is significantly expanded to 250nm covering almost all the photonic band gap owing to nearly linear dispersion of the TE-like waveguiding mode. The flat transmission spectrum however is interrupted by numerous narrow stop bands. We found that these stop bands can be attributed to anti-crossing between TE-like (positive parity) and TM-like (negative parity) modes. This effect is a direct result of the strong asymmetry of the waveguides that have an upper cladding of air and lower cladding of oxide. To our knowledge this is the first demonstration of the effects of cladding asymmetry on the transmission characteristics of the PhC slab waveguides.Comment: 7 pages, 6 figure

Participation in domestic energy retrofit programmes: key spatio-temporal drivers

The Canadian government created the EcoENEGY Retrofit for Homes programme (2007–12) to improve residential energy efficiency and reduce emissions produced through energy use. The uptake of retrofits varied both spatially and temporally. This research examines spatio-temporal patterns of retrofit adoption to understand the drivers behind participation in the grant programme and assess how future grant-based programmes might improve the uptake of efficiency measures. Temporal analysis demonstrated continued growth of programme participation over its original period of availability, and this accelerated once the programme was extended for an additional year after its original closure date. However, some spatial correlations weakened, which may be attributable to changes in programme design during the extension period. Seasonal variation was also observed, with spikes in retrofit activity occurring in winter. A regression analysis for conversion rates in Ontario and British Columbia displayed significant positive correlations for high shelter costs (>30% of household income) and households occupied by usual residents (regular occupants). Population density, median property value (only in Ontario) and units that were recently occupied demonstrated negative correlations. Spatial variation at both the city and neighbourhood levels suggests a greater degree of programme customisation is required to ensure uniform building stock improvement