5 research outputs found

    光子探测激光测距的目标跟踪建模与仿真

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    单个光子的探测技术能提升普通探测器的灵敏度,在测距方面有着很重要的应用价值。光子探测激光测距技术是对于在先验信息未知的情况下,从大量回波数据中提取目标的运动轨迹。文章通过模拟光子计数探测目标的回波信息,用图像处理的方法从大量的回波数据中提取了目标的运动轨迹,与目标理论运动轨迹相比,误差在5 m以内。光子探测激光测距可作为北斗导航系统的一个辅助定位模块,利用其近程定位优势解决了光缆巡线过程中由于外部环境导致的北斗终端定位不精准的问题

    特高压电网超长距传输新方向:塔内光中继

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    针对特高压电网建设对超长距传输提出的更高要求,提出了新的技术方向——塔内光中继。分析了塔内光中继的理论依据并设计了技术方案,在哈密郑州特高压直流输电光纤通信工程石城至环县段实现了我国首个塔内光中继实验工程,工程顺利开通,运行稳定,验证了塔内光中继方案的可行性。随着我国电网建设的不断发展,塔内光中继将得到更广泛的应用

    Surface Chemical Properties of Mo2C, W2C, Mo2N and W2N Probed with CO, CO2and O2 Adsorption: A DFT Analysis

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    作为具有吸引力的电极材料,过渡金属碳化物与氮化物被应用在许多电化学储能及能量转换领域. 本工作中,通过密度泛函理论计算,以及一氧化碳 (CO), 二氧化碳(CO2)和 氧气(O2)分子的吸附来表征钼和钨的碳化物及氮化物,如碳化钼(Mo2C)、碳化钨(W2C)、氮化钼(Mo2N)和氮化钨(Mo2C)的表面化学性质. 这些探针分子可为研究钼和钨的碳化物及氮化物表面在酸性/碱性的氧化还原性质提供衡量方法. 计算结果表明,CO2分子的吸附发生在路易斯碱位,其碱性降低顺序为α-W2C(001) > α-W2N(001) > β-Mo2C(001) > γ-Mo2N(100). 此外,CO和O2分子吸附可用于评估上述碳化物及氮化物的还原能力,其还原性减小顺序为β-W2C(100) > α-Mo2C(100) > α-W2N(001) > α-W2C(001) > β-Mo2C(001) > γ-Mo2N(100). 由于还原本性,使得上述这些碳化物和氮化物成为在各种催化反应中有可能取代贵金属的良好候选材料.Transition metal carbides and nitrides are attractive materials for electrodes in many electrochemical energy storage and conversion applications. In the present study, we use density functional theory slab calculations to characterize the surface chemical properties of molybdenum (Mo) and tungsten (W) carbides and nitrides, namely, Mo2C, W2C, Mo2N and W2N with the adsorption of CO, CO2 and O2. These probing molecules provide measures of in both acidity/basicity and redox property of for the surfaces of these carbides and nitrides. Our results show that Lewis basic sites were responsible for CO2 adsorption and the basicity follows followed an order of α-W2C(001) > α-W2N(001) > β-Mo2C(001) > γ-Mo2N(100). Both CO and O2 adsorption provide measures of in the reducing ability of these carbides and nitrides. The results showed a reducing ability in the order of β-W2C(100) > α-Mo2C(100) > α-W2N(001) > α-W2C(001) > β-Mo2C(001) > γ-Mo2N(100). The reducing nature of these carbides and nitrides make them good candidates to substitute noble metals in various catalytic reactions.We acknowledge the support of NSF-CBET program (Award no. CBET-1438440).We acknowledge the support of NSF-CBET program (Award no. CBET-1438440).作者联系地址:美国南伊利诺伊大学化学与生物化学系, 卡本代尔, 伊利诺伊 62901Author's Address: Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, IL 62901, US

    Ziprasidone versus other atypical antipsychotics for schizophrenia

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