Sulphur molecules in the circumstellar envelopes of M-type AGB stars

The sulphur compounds SO and SO$_2$ have not been widely studied in the circumstellar envelopes of asymptotic giant branch (AGB) stars. By presenting and modelling a large number of SO and SO$_2$ lines in the low mass-loss rate M-type AGB star R Dor, and modelling the available lines of those molecules in a further four M-type AGB stars, we aim to determine their circumstellar abundances and distributions. We use a detailed radiative transfer analysis based on the accelerated lambda iteration method to model circumstellar SO and SO$_2$ line emission and molecular data files for both SO and SO$_2$ that are more extensive than those previously available. Using 17 SO lines and 98 SO2 lines to constrain our models for R Dor, we find an SO abundance of 6.7x10$^{-6}$ and an SO$_2$ abundance of 5x10$^{-6}$ with both species having high abundances close to the star. We also modelled $^{34}$SO and found an abundance of 3.1x10$^{-7}$, giving an $^{32}$SO/$^{34}$SO ratio of 21.6. We derive similar results for the circumstellar SO and SO$_2$ abundances and their distributions for the low mass-loss rate object W Hya. For these stars, the circumstellar SO and SO$_2$ abundances are much higher than predicted by chemical models and these two species may account for all available sulphur. For the higher mass-loss rate stars, we find shell-like SO distributions with peak abundances that decrease and peak abundance radii that increase with increasing mass-loss rate. The positions of the peak SO abundance agree very well with the photodissociation radii of H$_2$O. We find evidence that SO is most likely through the photodissociation of H$_2$O and the subsequent reaction between S and OH. The S-bearing parent molecule appears not to be H$_2$S. The SO$_2$ models suggest an origin close to the star for this species, also disagreeing with current chemical models.Comment: 25 page

Classifying the secondary component of the binary star W Aquilae

AIMS: The object W Aql is an asymptotic giant branch (AGB) star with a faint companion. By determining more carefully the properties of the companion, we hope to better constrain the properties of the AGB star. METHODS: We present new spectral observations of the binary star W Aql at minimum and maximum brightness and new photometric observations of W Aql at minimum brightness. RESULTS: The composite spectrum near minimum light is predominantly from the companion at wavelengths $\lambda$ < 6000 $\AA$. This spectrum can be classified as F8 to G0, and the brightness of the companion is that of a dwarf star. Therefore, it can be concluded that the companion is a main sequence star. From this, we are able to constrain the mass of the AGB component to 1.04 - 3 $M_\odot$ and the mass of the W Aql system to 2.1 - 4.1 $M_\odot$ . Our photometric results are broadly consistent with this classification and suggest that the main sequence component suffers from approximately 2 mag of extinction in the V band primarily due to the dust surrounding the AGB component.Comment: 5 pages, 1 figure, research not

Silicate dust in a Vega-excess system

The 10-µm spectrum of the K5V star SAO 179815 ( = HD 98800) is presented, and conclusively demonstrates the presence of small silicate dust grains (probably in a disc) around this star. The 9.7-µm silicate dust feature is unusually broad and shallow in this system. This, together with the slow fall-off of flux at longer wavelengths, constrains the size and density distributions of dust grains in models of the disc. We find that there must be a significant population of small grains (radii at least as small as 0.01 µm), as well as a population of large grains (radii at least as large as 100 µm) in order to explain all the observed properties of the disc

Oxygen in dense interstellar gas - the oxygen abundance of the star forming core rho Oph A

Oxygen is the third most abundant element in the universe, but its chemistry in the interstellar medium is still not well understood. In order to critically examine the entire oxygen budget, we attempt here initially to estimate the abundance of atomic oxygen, O, in the only one region, where molecular oxygen, O2, has been detected to date. We analyse ISOCAM-CVF spectral image data toward rho Oph A to derive the temperatures and column densities of H2 at the locations of ISO-LWS observations of two [OI] 3P_J lines. The intensity ratios of the (J=1-2) 63um to (J=0-1) 145um lines largely exceed ten, attesting to the fact that these lines are optically thin. This is confirmed by radiative transfer calculations, making these lines suitable for abundance determinations. For that purpose, we calculate line strengths and compare them to the LWS observations. Excess [OI] emission is observed to be associated with the molecular outflow from VLA 1623. For this region, we determine the physical parameters, T and N(H2), from the CAM observations and the gas density, n(H2), is determined from the flux ratio of the [O I]63um and [O I]145um lines. For the oxygen abundance, our analysis leads to essentially three possibilities: (1) Extended low density gas with standard ISM O-abundance, (2) Compact high density gas with standard ISM O-abundance and (3) Extended high density gas with reduced oxygen abundance, [O/H] ~ 2E-5. As option (1) disregards valid [O I] 145um data, we do not find it very compelling; we favour option (3), as lower abundances are expected as a result of chemical cloud evolution, but we are not able to dismiss option (2) entirely. Observations at higher angular resolution than offered by the LWS are required to decide between these possibilities.Comment: Accepted for publication in A&

Near-infrared observations of water-ice in OH/IR stars

A search for the near-infrared water-ice absorption band was made in a number of very red OH/IR stars which are known to exhibit the 10um silicate absorption. As a by-product, accurate positions of these highly reddened objects are obtained. We derived a dust mass loss rate for each object by modelling the spectral energy distribution and the gas mass loss rate by solving the equation of motion for the dust drag wind. The derived mass loss rates show a strong correlation with the silicate optical depth as well as that of the water-ice. The stars have a high mass loss rate (> 1.0E-4 Msun/yr) with an average gas-to-dust mass ratio of 110. In objects which show the 3.1um water-ice absorption, the near-IR slope is much steeper than those with no water-ice. Comparison between our calculated mass loss rates and those derived from OH and CO observations indicates that these stars have recently increased their mass loss rates.Comment: 10 pages, 6 figures : accepted for publication in A&

Detailed modelling of the circumstellar molecular line emission of the S-type AGB star W Aquilae

S-type AGB stars have a C/O ratio which suggests that they are transition objects between oxygen-rich M-type stars and carbon-rich C-type stars. As such, their circumstellar compositions of gas and dust are thought to be sensitive to their precise C/O ratio, and it is therefore of particular interest to examine their circumstellar properties. We present new Herschel HIFI and PACS sub-millimetre and far-infrared line observations of several molecular species towards the S-type AGB star W Aql. We use these observations, which probe a wide range of gas temperatures, to constrain the circumstellar properties of W Aql, including mass-loss rate and molecular abundances. We used radiative transfer codes to model the circumstellar dust and molecular line emission to determine circumstellar properties and molecular abundances. We assumed a spherically symmetric envelope formed by a constant mass-loss rate driven by an accelerating wind. Our model includes fully integrated H2O line cooling as part of the solution of the energy balance. We detect circumstellar molecular lines from CO, H2O, SiO, HCN, and, for the first time in an S-type AGB star, NH3. The radiative transfer calculations result in an estimated mass-loss rate for W Aql of 4.0e-6 Msol yr-1 based on the 12CO lines. The estimated 12CO/13CO ratio is 29, which is in line with ratios previously derived for S-type AGB stars. We find an H2O abundance of 1.5e-5, which is intermediate to the abundances expected for M and C stars, and an ortho/para ratio for H2O that is consistent with formation at warm temperatures. We find an HCN abundance of 3e-6, and, although no CN lines are detected using HIFI, we are able to put some constraints on the abundance, 6e-6, and distribution of CN in W Aql's circumstellar envelope using ground-based data. We find an SiO abundance of 3e-6, and an NH3 abundance of 1.7e-5, confined to a small envelope.Comment: 17 pages, 15 figure

Methanol Ice in the Protostar GL 2136

We present ground-based spectra in the 10 and 20 micron atmospheric windows of the deeply embedded protostar GL 2136. These reveal narrow absorption features at 9.7 and 8.9 microns, which we ascribe to the CO-stretch and CH3 rock (respectively) of solid methanol in grain mantles. The peak position of the 9.7 micron band implies that methanol is an important ice mantle component. However, the CH3OH/H2O abundance ratio derived from the observed column densities is only 0.1. This discrepancy suggests that the solid methanol and water ice are located in independent grain components. These independent components may reflect chemical differentiation during grain mantle formation and/or partial outgassing close to the protostar

The nature of dust around the post-asymptotic giant branch objects HD 161796 and HD 179821

Ground-based 7.4-24-micron spectra of two post-AGB objects, HD 161796 and HD 179821, are reported, and they are compared to those of other preplanetary nebulae. HD 161796 and HD 17982 show emission features at 10-12 microns and at 10 microns, and they exhibit a very rapid increase in flux between 13 and 15.5 microns. In view of the O-rich photosphere of HD 161796 and the presence of OH maser emission around all three objects, these features are ascribed to various oxides. The observed spectral features are quite different from the canonical silicate features observed in most O-rich giants. It is argued that HD 161796 and the bipolar nebulae Roberts 22 and NGC 6302 have all undergone the third dredge-up, with most of the dredged-up carbon having been converted to nitrogen by envelope-burning. It is concluded that carbon-rich grain material, produced during the interval between the end of the third dredge-up and the moment when envelope burning finally reduced the C/O ratio below unity again, could be responsible for the UIR bands now being excited in Roberts 22 and NGC 6302