S-type AGB stars have a C/O ratio which suggests that they are transition
objects between oxygen-rich M-type stars and carbon-rich C-type stars. As such,
their circumstellar compositions of gas and dust are thought to be sensitive to
their precise C/O ratio, and it is therefore of particular interest to examine
their circumstellar properties.
We present new Herschel HIFI and PACS sub-millimetre and far-infrared line
observations of several molecular species towards the S-type AGB star W Aql. We
use these observations, which probe a wide range of gas temperatures, to
constrain the circumstellar properties of W Aql, including mass-loss rate and
molecular abundances. We used radiative transfer codes to model the
circumstellar dust and molecular line emission to determine circumstellar
properties and molecular abundances. We assumed a spherically symmetric
envelope formed by a constant mass-loss rate driven by an accelerating wind.
Our model includes fully integrated H2O line cooling as part of the solution of
the energy balance. We detect circumstellar molecular lines from CO, H2O, SiO,
HCN, and, for the first time in an S-type AGB star, NH3. The radiative transfer
calculations result in an estimated mass-loss rate for W Aql of 4.0e-6 Msol
yr-1 based on the 12CO lines. The estimated 12CO/13CO ratio is 29, which is in
line with ratios previously derived for S-type AGB stars. We find an H2O
abundance of 1.5e-5, which is intermediate to the abundances expected for M and
C stars, and an ortho/para ratio for H2O that is consistent with formation at
warm temperatures. We find an HCN abundance of 3e-6, and, although no CN lines
are detected using HIFI, we are able to put some constraints on the abundance,
6e-6, and distribution of CN in W Aql's circumstellar envelope using
ground-based data. We find an SiO abundance of 3e-6, and an NH3 abundance of
1.7e-5, confined to a small envelope.Comment: 17 pages, 15 figure
