Ion beam effect on Ge-Se chalcogenide glass films: Non-volatile memory array formation, structural changes and device performance

The conductive bridge non-volatile memory technology is an emerging way to replace traditional charge based memory devices for future neural networks and configurable logic applications. An array of the memory devices that fulfills logic operations must be developed for implementing such architectures. A scheme to fabricate these arrays, using ion bombardment through a mask, has been suggested and advanced by us. Performance of the memory devices is studied, based on the formation of vias and damage accumulation due to the interactions of Ar+ ions with GexSe1-x (x=0.2, 0.3 and 0.4) chalcogenide glasses as a function of the ion energy and dose dependence. Blanket films and devices were created to study the structural changes, surface roughness, and device performance. Raman Spectroscopy, Atomic Force Microscopy (AFM), Energy Dispersive X-Ray Spectroscopy (EDS) and electrical measurements expound the Ar+ ions behavior on thin films of GexSe1-x system. Raman studies show that there is a decrease in area ratio between edge-shared to corner-shared structural units, revealing occurrence of structural reorganization within the system as a result of ion/film interaction. AFM results demonstrate a tendency in surface roughness improvement with increased Ge concentration, after ion bombardment. EDS results reveal a compositional change in the vias, with a clear tendency of greater interaction between ions and the Ge atoms, as evidenced by greater compositional changes in the Ge rich films

Thermodynamics of Ion Separation by Electrosorption

We present a simple, top-down approach for the calculation of minimum energy consumption of electrosorptive ion separation using variational form of the (Gibbs) free energy. We focus and expand on the case of electrostatic capacitive deionization (CDI), and the theoretical framework is independent of details of the double-layer charge distribution and is applicable to any thermodynamically consistent model, such as the Gouy-Chapman-Stern (GCS) and modified Donnan (mD) models. We demonstrate that, under certain assumptions, the minimum required electric work energy is indeed equivalent to the free energy of separation. Using the theory, we define the thermodynamic efficiency of CDI. We explore the thermodynamic efficiency of current experimental CDI systems and show that these are currently very low, less than 1% for most existing systems. We applied this knowledge and constructed and operated a CDI cell to show that judicious selection of the materials, geometry, and process parameters can be used to achieve a 9% thermodynamic efficiency (4.6 kT energy per removed ion). This relatively high value is, to our knowledge, by far the highest thermodynamic efficiency ever demonstrated for CDI. We hypothesize that efficiency can be further improved by further reduction of CDI cell series resistances and optimization of operational parameters

Hydrogen vs. Battery in the long-term operation. A comparative between energy management strategies for hybrid renewable microgrids

The growth of the world’s energy demand over recent decades in relation to energy intensity and demography is clear. At the same time, the use of renewable energy sources is pursued to address decarbonization targets, but the stochasticity of renewable energy systems produces an increasing need for management systems to supply such energy volume while guaranteeing, at the same time, the security and reliability of the microgrids. Locally distributed energy storage systems (ESS) may provide the capacity to temporarily decouple production and demand. In this sense, the most implemented ESS in local energy districts are small–medium-scale electrochemical batteries. However, hydrogen systems are viable for storing larger energy quantities thanks to its intrinsic high mass-energy density. To match generation, demand and storage, energy management systems (EMSs) become crucial. This paper compares two strategies for an energy management system based on hydrogen-priority vs. battery-priority for the operation of a hybrid renewable microgrid. The overall performance of the two mentioned strategies is compared in the long-term operation via a set of evaluation parameters defined by the unmet load, storage efficiency, operating hours and cumulative energy. The results show that the hydrogen-priority strategy allows the microgrid to be led towards island operation because it saves a higher amount of energy, while the battery-priority strategy reduces the energy efficiency in the storage round trip. The main contribution of this work lies in the demonstration that conventional EMS for microgrids’ operation based on battery-priority strategy should turn into hydrogen-priority to keep the reliability and independence of the microgrid in the long-term operation

Фізика: лабораторний практикум

Present book contains theory ,description of experimental equipment ,procedure and analysis recommendations to the physics laboratory experiments for foreign students studying in Ukraine

Development of silicon nitride and cermet resistors for use in a binary counter, metal insulator field effect transistor circuit Final report, 1 Dec. 1966 - 31 Mar. 1968

Silicon nitride and cermet resistors for binary counter metal insulator field effect transistor circui