Design and additive manufacture for flow chemistry

This thesis aims to investigate the use of additive manufacturing (AM) as a novel manufacturing process for the production of milli-scale chemical reaction systems. Five well developed additive manufacturing techniques; stereolithography (SL), selective laser melting (SLM), fused deposition modelling (FDM), ultrasonic additive manufacture (UAM) and selective laser sintering (SLS) were used to manufacture a number of miniaturised flow devices which were tested using a range of organic and inorganic reactions. SL was used to manufacture a range of functioning milli-scale flow devices from Accura 60 photoresin, with both simple and complex internal channel networks. These devices were used to perform a range of organic and inorganic reactions, including aldehyde and ketone functional group interconversions. Conversion of products within these reactors, were shown to be comparable to commercially available milli-scale coil reactors. More complex designs, which allowed SL parts to be integrated to existing flow and analytical instrumentation, allowed us to develop an automated reaction analysis and optimisation platform. This platform allowed precise control over the reaction conditions, including flow rate, temperature and reagent composition. We also designed a simplex type reaction optimisation software package that could input data in the form of reaction conversions, peak intensities, and thermocouple data, and generate a new set of optimal reaction conditions. SL parts which incorporated embedded analytical components were also manufactured, which allowed us to perform inline reaction analysis as a feedback method for input into the optimisation platform. Stereolithography was shown to be a highly versatile manufacturing method for designing and producing these flow devices, however the process was shown to be still limited by the range of processable materials currently commercially available. SLM was also used to manufacture a number of functioning milli-scale flow devices from stainless steel and titanium, which had simplistic internal channel designs of diameters ranging from 1 to 3 mm. Again, SLM parts were manufactured which incorporated embedded analytical components, which could be integrated into an automated reaction platform. These devices, unlike parts produced via SL, could be attached to heating platforms to allow us to perform high temperature reactions. This control over the reaction temperature formed an essential part of the reaction optimisation platform. These parts were again used to perform a ketone functional group interconversion. Internal structures of these SLM parts were also visualised via micro computed tomography (µCT or microCT) scanning as well as optical microscopy. FDM was used throughout the project as an inexpensive method of prototyping parts which were to be manufactured via more expensive manufacturing processes. This prototyping allowed the optimisation of intricate design features, such as the manufacture of an inline spectroscopic flow cell for integration with a commercially available LC system. FDM was also proposed as a customisable approach to designing and manufacturing flow devices with embedded components, however the current limitations in build resolution and materials choices severely limited the use of FDM for this application. UAM was also proposed as a novel manufacturing process whereby the build process would allow discrete components to be embedded directly into a flow channel. This was demonstrated by embedding a type-k thermocouple across a 2 mm channel. The data from this thermocouple was monitored during a heated reaction, and used as a method of determining the exact reaction conditions the reaction medium was being exposed to. SLS was also proposed as a possible manufacturing method for milli-scale flow devices, however it proved difficult to remove un-sintered powder from parts with internal channel diameters as high as 5 mm. It was shown that this powder was forming a dense semi solid, due to the large degree of shrinkage upon cooling of the SLS parts, which was compressing the powder. More research into optimum processing conditions is required before SLS could be used for the production of intricate channel networks

An investigation into using laser micro channelling to assist fibre integration via Ultrasonic Consolidation

Ultrasonic Consolidation (UC) is a layer-by-layer metal-based additive manufacturing process. Bonding between two layers is accomplished by energy transmission in form of ultrasonic oscillations inducing localised plastic deformation. The benefit of localised plastic deformation and bonding below melting temperatures has been effectively used for fibre integration. Thus, UC presents a feasible alternative to other metal-manufacturing processes as well as an attractive method for novel engineering materials production such as smart structures.Yet, high volume fibre embedding has been shown to result in delamination of foils and greater porosity at the bonding interfaces due to insufficient plastic flow around the fibres. Furthermore, post-functionality of delicate fibre types was limited. In this study a novel hybrid approach aiming to reduce the necessary plastic flow around fibres and high fibre volume embedding is presented. [Continues.

The Public Service Media and Public Service Internet Manifesto

This book presents the collectively authored Public Service Media and Public Service Internet Manifesto and accompanying materials.The Internet and the media landscape are broken. The dominant commercial Internet platforms endanger democracy. They have created a communications landscape overwhelmed by surveillance, advertising, fake news, hate speech, conspiracy theories, and algorithmic politics. Commercial Internet platforms have harmed citizens, users, everyday life, and society. Democracy and digital democracy require Public Service Media. A democracy-enhancing Internet requires Public Service Media becoming Public Service Internet platforms – an Internet of the public, by the public, and for the public; an Internet that advances instead of threatens democracy and the public sphere. The Public Service Internet is based on Internet platforms operated by a variety of Public Service Media, taking the public service remit into the digital age. The Public Service Internet provides opportunities for public debate, participation, and the advancement of social cohesion. Accompanying the Manifesto are materials that informed its creation: Christian Fuchs’ report of the results of the Public Service Media/Internet Survey, the written version of Graham Murdock’s online talk on public service media today, and a summary of an ecomitee.com discussion of the Manifesto’s foundations

Designing parametric matter:Exploring adaptive material scale self-assembly through tuneable environments

3D designs can be created using generative processes, which can be transformed and adapted almost infinitely if they remain within their digital design software. For example, it is easy to alter a 3D object's colour, size, transparency, topology and geometry by adjusting values associated with those attributes. Significantly, these design processes can be seen as morphogenetic, where form is grown out of bottom-up logic’s and processes. However, when the designs created using these processes are fabricated using traditional manufacturing processes and materials they lose all of these abilities. For example, even the basic ability to change a shapes' size or colour is lost. This is partly because the relationships that govern the changes of a digital design are no longer present once fabricated. The motivating aim is: how can structures be grown and adapted throughout the fabrication processes using programmable self-assembly? In comparison the highly desirable attribute of physical adaptation and change is universally present within animals and biological processes. Various biological organisms and their systems (muscular or skeletal) can continually adapt to the world around them to meet changing demands across different ranges of time and to varying degrees. For example, a cuttlefish changes its skin colour and texture almost immediately to hide from predators. Muscles grow in response to exercise, and over longer time periods bones remodel and heal when broken, meaning biological structures can adapt to become more efficient at meeting regularly imposed demands. Emerging research is rethinking how digital designs are fabricated and the materials they are made from, leading to physically responsive and reconfigurable structures. This research establishes an interdisciplinary and novel methodology for building towards an adaptive design and fabrication system when utilising material scale computation process (e.g. self-assembly) within the fabrication process, which are guided by stimuli. In this context, adaption is the ability of a physical design (shape, pattern) to change its local material and or global properties, such as: shape, composition, texture and volume. Any changes to these properties are not predefined or constrained to set limits when subjected to environmental stimulus, (temperature, pH, magnetism, electrical current). Here, the stimulus is the fabrication mechanisms, which are governed and monitored by digital design tools. In doing so digital design tools will guide processes of material scale self-assembly and the resultant physical properties. The fabrication system is created through multiple experiments based on various material processes and platforms, from paint and additives, to ink diffusion and the mineral accretion process. A research through design methodology is used to develop the experiments, although the experiments by nature are explorative and incremental. Collectively they are a mixture of analogue and digital explorations, which establish principles and a method of how to grow physical designs, which can adapt based on digital augmentations by guiding material scale self-assembly. The results demonstrate that it is possible to grow physical 2D and 3D designs (shapes and patterns) that could have their properties tuned and adapted by creating tuneable environments to guide the mineral accretion process. Meaning, the desirable and dynamic traits of digital computational designs can be leveraged and extended the as they are made physical. Tuneable environments are developed and defined thought the series experiments within this thesis. Tuneable environments are not restricted to the mineral accretion process, as it is demonstrated how they can manipulate ink cloud patterns (liquid diffusion), which are less constrained in comparison to the mineral accretion process. This is possible due to the use of support mediums that dissipate energy and also contrast materially (they do not diffuse). Combining contrasting conditions (support mediums, resultant material effects) with the idea of tuneable environments reveals how: 1) material growth and properties can be monitored and 2) the possibilities of growing 3D designs using material scale self-assembly, which is not confined to a scaffold framework. The results and methodology highlight how tuneable environments can be applied to advance other areas of emerging research, such as altering environmental conditions during methods of additive manufacturing, such as, suspended deposition, rapid liquid printing, computed axial lithography or even some strategies of bioprinting. During the process, deposited materials and global properties could adapt because of changing conditions. Going further and combining it with the idea of contrasting mediums, this could lead to new types 3D holographic displays, which are grown and not restricted to scaffold frameworks. The results also point towards a potential future where buildings and infrastructure are part of a material ecosystem, which can share resources to meet fluctuating demands, such as, solar shading, traffic congestion, live loading

Structural Health Monitoring Damage Detection Systems for Aerospace

This open access book presents established methods of structural health monitoring (SHM) and discusses their technological merit in the current aerospace environment. While the aerospace industry aims for weight reduction to improve fuel efficiency, reduce environmental impact, and to decrease maintenance time and operating costs, aircraft structures are often designed and built heavier than required in order to accommodate unpredictable failure. A way to overcome this approach is the use of SHM systems to detect the presence of defects. This book covers all major contemporary aerospace-relevant SHM methods, from the basics of each method to the various defect types that SHM is required to detect to discussion of signal processing developments alongside considerations of aerospace safety requirements. It will be of interest to professionals in industry and academic researchers alike, as well as engineering students. This article/publication is based upon work from COST Action CA18203 (ODIN - http://odin-cost.com/), supported by COST (European Cooperation in Science and Technology). COST (European Cooperation in Science and Technology) is a funding agency for research and innovation networks. Our Actions help connect research initiatives across Europe and enable scientists to grow their ideas by sharing them with their peers. This boosts their research, career and innovation

Management of Technological Innovation in Developing and Developed Countries

It is widely accepted that technology is one of the forces driving economic growth. Although more and more new technologies have emerged, various evidence shows that their performances were not as high as expected. In both academia and practice, there are still many questions about what technologies to adopt and how to manage these technologies. The 15 articles in this book aim to look into these questions. There are quite many features in this book. Firstly, the articles are from both developed countries and developing countries in Asia, Africa and South and Middle America. Secondly, the articles cover a wide range of industries including telecommunication, sanitation, healthcare, entertainment, education, manufacturing, and financial. Thirdly, the analytical approaches are multi-disciplinary, ranging from mathematical, economic, analytical, empirical and strategic. Finally, the articles study both public and private organizations, including the service industry, manufacturing industry, and governmental organizations. Given its wide coverage and multi-disciplines, the book may be useful for both academic research and practical management