Biomimetic flow fields for proton exchange membrane fuel cells: A review of design trends

Bipolar Plate design is one of the most active research fields in Polymer Electrolyte Membrane Fuel Cells (PEMFCs) development. Bipolar Plates are key components for ensuring an appropriate water management within the cell, preventing flooding and enhancing the cell operation at high current densities. This work presents a literature review covering bipolar plate designs based on nature or biological structures such as fractals, leaves or lungs. Biological inspiration comes from the fact that fluid distribution systems found in plants and animals such as leaves, blood vessels, or lungs perform their functions (mostly the same functions that are required for bipolar plates) with a remarkable efficiency, after millions of years of natural evolution. Such biomimetic designs have been explored to date with success, but it is generally acknowledged that biomimetic designs have not yet achieved their full potential. Many biomimetic designs have been derived using computer simulation tools, in particular Computational Fluid Dynamics (CFD) so that the use of CFD is included in the review. A detailed review including performance benchmarking, time line evolution, challenges and proposals, as well as manufacturing issues is discussed.Ministerio de Ciencia, Innovación y Universidades ENE2017-91159-EXPMinisterio de Economía y Competitividad UNSE15-CE296

Characteristics of liquids lugs in gas–liquid Taylor flow in microchannels

The hydrodynamics of liquid slugs in gas–liquid Taylor flow in straight and meandering microchannels have been studied using micro Particle Image Velocimetry. The results confirm a recirculation motion in the liquid slug, which is symmetrical about the center line of the channel for the straight geometry and more complex and three-dimensional in the meandering channel. An attempt has also been made to quantify and characterize this recirculation motion in these short liquid slugs (Ls/w<1.5) by evaluating the recirculation rate, velocity and time. The recirculation velocity was found to increase linearly with the two-phase superficial velocity UTP. The product of the liquid slug residence time and the recirculation rate is independent of UTP under the studied flow conditions. These results suggest that the amount of heat or mass transferred between a given liquid slug and its surroundings is independent of the total flow rate and determined principally by the characteristics of the liquid slug

Current methods for characterising mixing and flow in microchannels

This article reviews existing methods for the characterisation of mixing and flow in microchannels, micromixers and microreactors. In particular, it analyses the current experimental techniques and methods available for characterising mixing and the associated phenomena in single and multiphase flow. The review shows that the majority of the experimental techniques used for characterising mixing and two-phase flow in microchannels employ optical methods, which require optical access to the flow, or off-line measurements. Indeed visual measurements are very important for the fundamental understanding of the physics of these flows and the rapid advances in optical measurement techniques, like confocal scanning laser microscopy and high resolution stereo micro particle image velocimetry, are now making full field data retrieval possible. However, integration of microchannel devices in industrial processes will require on-line measurements for process control that do not necessarily rely on optical techniques. Developments are being made in the areas of non-intrusive sensors, magnetic resonance techniques, ultrasonic spectroscopy and on-line flow through measurement cells. The advances made in these areas will certainly be of increasing interest in the future as microchannels are more frequently employed in continuous flow equipment for industrial applications

A general perspective of the characterization and quantification of nanoparticles: Imaging, spectroscopic, and separation techniques

This article gives an overview of the different techniques used to identify, characterize, and quantify engineered nanoparticles (ENPs). The state-of-the-art of the field is summarized, and the different characterization techniques have been grouped according to the information they can provide. In addition, some selected applications are highlighted for each technique. The classification of the techniques has been carried out according to the main physical and chemical properties of the nanoparticles such as morphology, size, polydispersity characteristics, structural information, and elemental composition. Microscopy techniques including optical, electron and X-ray microscopy, and separation techniques with and without hyphenated detection systems are discussed. For each of these groups, a brief description of the techniques, specific features, and concepts, as well as several examples, are described.Junta de Andalucía FQM-5974CEI-Biotic Granada CEI2013- MP-1

How coherent structures dominate the residence time in a bubble wake: an experimental example

Mixing timescales and residence times in reactive multiphase flows can be essential for product selectivity. For instance when a gas species is consumed e.g. by a competitive consecutive reaction with moderate reaction kinetics where reaction timescales are comparable to relevant mixing timescales. To point out the importance of the details of the fluid flow, we analyze experimental velocity data from a Taylor bubble wake by means of Lagrangian methods. By adjusting the channel diameter in which the Taylor bubble rises, and thus the rise velocity, we obtain three different wake regimes. Remarkably the normalized residence times of passive particles advected in the wake velocity field show a peak for intermediate rise velocities. This fact seems unintuitive at first glance because one expects a faster removal of passive tracers for a faster overall flow rate. However, the details of the flow topology analyzed using Finite Time Lyapunov Exponent (FTLE) fields and Lagrangian Coherent Structures (LCS) reveal the existence of a very coherent vortical pattern in the bubble wake which explains the long residence times. The increased residence times within the vortical structure and the close bubble interface acting as a constant gas species source could enhance side product generation of a hypothetical competitive consecutive reaction, where the first reaction with the gas species forms the desired product and the second the side product.Comment: 13 pages, 7 figures, 1 tabl

Reynolds-number effects and anisotropy in transverse-jet mixing

Experiments are described which measured concentration fields in liquid-phase strong transverse jets over the Reynolds-number range 1.0×10^3 ≤ Rej ≤ 20×10^3. Laser-induced-fluorescence measurements were made of the jet-fluid-concentration fields at a jet-to-freestream velocity ratio of Vr =10. The concentration-field data for far-field (x/dj =50) slices of the jet show that turbulent mixing in the transverse jet is Reynolds number dependent over the range investigated, with a scalar-field PDF that evolves with Reynolds number. A growing peak in the PDF, indicating enhanced spatial homogenization of the jet-fluid concentration field, is found with increasing Reynolds number. Comparisons between transverse jets and jets discharging into quiescent reservoirs show that the transverse jet is an efficient mixer in that it entrains more fluid than the ordinary jet, yet is able to effectively mix and homogenize the additional entrained fluid. Analysis of the structure of the scalar field using distributions of scalar increments shows evidence for well-mixed plateaux separated by sharp cliffs in the jet-fluid concentration field, as previously shown in other flows. Furthermore, the scalar field is found to be anisotropic, even at small length scales. Evidence for local anisotropy is seen in the scalar power spectra, scalar microscales, and PDFs of scalar increments in different directions. The scalar-field anisotropy is shown to be correlated to the vortex-induced large-scale strain field of the transverse jet. These experiments add to the existing evidence that the large and small scales of high-Schmidt-number turbulent mixing flows can be linked, with attendant consequences for the universality of small scales of the scalar field for Reynolds numbers up to at least Re=20×10^4

Holographic flow visualization

Holographic visualization techniques are presented of the vortex wake of a lifting wing. The motions of tracer particles in vortical flows are described along with the development of a liquid-drop tracer generator. An analysis is presented of the motion of particles of arbitrary density and size in solid body and potential vortex flows

Characterization of two-phase flow in a transparent PEM fuel cell using simultaneous anode and cathode visualization and digital image processing

Proton exchange membrane (PEM) fuel cells have emerged as a potential alternative to internal combustion engines in order to curb dependency on fossil fuels and reduce harmful CO2 emissions. Water management has been identified as a key research area for the advancement of PEM fuel cell technology, especially as it affects the purge protocol prior to cell shutdown. The presence of water in the cell is necessary to sustain membrane hydration, but the accumulation of excess liquid water, referred to as flooding, can lead to increased mass transport losses and reductions in performance and durability. In this work, a technique was developed to characterize the two-phase flow in the anode and cathode flow field channels simultaneously using a transparent fuel cell with dual-visualization capability. The transparent fuel cell used in this work was designed to represent actual full scale automotive fuel cell geometry. A video processing algorithm was developed to automatically detect dynamic and static liquid water present in the gas channels and generate relevant quantitative information. The water coverage ratio is introduced as a parameter to capture the time-averaged flow field water content information through recorded video sequences. The algorithm also yields information pertaining to the distribution of water among different two-phase flow structures. The water coverage ratio and distribution metrics were employed in comparing the performance of Freudenberg and Toray gas diffusion layers (GDLs) from a water management perspective, including direct anode to cathode comparisons for each GDL sample. This technique was able to provide a unique and comprehensive characterization of liquid water in an operating fuel cell which can be used towards the optimization of water management and purge strategies, as well as data generation for model validation purposes