The complex binder based on Portland cement andash-and-slag wastes from thermal power stations

Increase in the balance of boiler and furnace fuel of the energy sector of the Republic of Belarus the proportion of own energy resources (milling peat and wood chips) places priority on resolving the issues of utilization of ash-and-slag wastes and reducing the area of ash-and-slag disposal sites, which cause irreparable damage to the environment. A considerable amount of research has been devoted to the utilization of ash-and-slag wastes. There are more than 300 technologies of their recycling and use. Ash and slag wastes are used in the production of concrete, mortars, ceramics, heat and water insulating materials, road construction. The world experience shows the potential of 70-80% utilization of ash and slag, as, for example, in some European countries. However, the cost of the recycling of ash-and-slag wastes with the production and simultaneous neutralization of wastes can be higher than the cost of the production. One of the directions of the use of ash and slag wastes is the production on their basis of new types of complex binder that have increased strength and low prime cost. The replacement of a part of cement with active mineral additive allows to achieve significant saving of binder. The existing methods of the production of complex binders include the stages of joint or separate grinding of cement clinker and mineral additive with following mixing. Significant energy costs for grinding increase the cost of binder. In this regard, the development of the effective complex binder with the use of ash-and-slag wastes of the Belarussian state district power station in Orekhovsk using resource-saving technology is the actual research objective

The reaction of slag in cement: theory and computer modelling

In this study, theoretical models available for the reaction of both pure slag\ud (alkali-activated) and slag-blended cement are reviewed. They were developed by using stoichiometric computations

Prognostic value of thyroid hormone levels in patients evaluated for liver transplantation

The thyroid hormones T4, T3, rT3 and TSH were assayed in 134 adult patients evaluated and accepted as potential liver transplant candidates at the Universty of Pittsburgh from March, 1981 to December, 1983. The subsequent course of these patients was evaluated with respect to the levels of these hormones obtained at the time of acceptance for transplantation. T4 levels were increased significantly while their T3 levels were reduced (both p < 0.01) in those who survived and were discharged home as compared to either those who died waiting to be transplanted or died following the procedure. As a result, the ratio of T3/T4 was reduced markedly (p < 0.01) in those who were transplanted and survived as compared to those not transplanted or dying following transplantation. Importantly, the rT3 levels clearly separated (p < 0.01) those who would die prior to transplantation from those who would survive to be transplanted. Finally, the ratio rT3/T3 even more clearly separates those who will die prior to transplantation (p < 0.01) from the other two groups. These data suggest that thyroid hormone levels, particularly rT3 levels, might be useful in setting priorities for which patients referred for a transplantation evaluation should be accepted into the program and in determining who among accepted patients should be operated upon in preference to others also accepted and waiting to be transplanted. Copyright © 1985 American Association for the Study of Liver Disease

Functional glass-ceramic foams from \u2018inorganic gel casting\u2019 and sintering of glass/slag mixtures

The here described investigation was essentially aimed at exploring the chemical stabilization and reutilization of iron-rich slag from copper metallurgy, by the manufacturing of glass-ceramic foams. The foams were developed according to a new method, recently reported for pure recycled soda-lime glass. Mixtures of soda-lime glass/slag powders (with slag content ranging from 10 to 30\u202fwt%), suspended in alkaline aqueous solution, underwent progressive low temperature (80\u202f\ub0C) hardening, owing to the formation of hydrated calcium silicate compounds (CSH). Before complete setting, an extensive foaming could be achieved by vigorous mechanical stirring, with the help of a surfactant. After foaming, glass/slag mixtures could be sintered at 800\u20131000\u202f\ub0C; the mutual interaction caused an extensive crystallization, with precipitation of CaFe silicates and iron oxides (hematite and magnetite), promoting the mechanical properties (up to 4.4\u202fMPa, with a porosity of about 80%). Leaching test confirmed the stabilization of pollutants, from the slag, in the final ceramics. Owing to the separation of iron oxides, particularly magnetite, the newly obtained foams exhibited a ferrimagnetic behavior, that could be exploited in electromagnetic shielding applications

Laboratory Investigation of Skid Resistance for Steel Slag Utilization as Chip Seal

Slag as waste material of steel-making process has similar characteristics with aggregate that has been widely used in pavement construction. The use of slag as chip seal aggregate to provide skid resistance needs to be analyzed. In this laboratory study, the chip seal samples are made using steel slag and natural aggregate. The bonding materials used are asphalt and epoxy resin. Skid resistance tests for all chip seal samples and also hot rolled sheet pavement without chip seal application are performed using the Portable British Pendulum Tester. The results show the variations of chip seal aggregate weight are inconsistent. The natural aggregate used as chip seal material could produce high skid resistance value of 10.3% higher than that using steel slag. Also the skid resistance of chip seal with the ALD 3 mm are not significantly different with that of ALD 6 mm. Similar results occur on the skid resistance of chip seals using epoxy resin and asphalt

Evaluation of copper slag blast media for railcar maintenance

Copper slag was tested as a blasting substitute for zirconium silicate which is used to remove paint from railroad cars. The copper slag tested is less costly, strips paint faster, is produced near the point of need, provides a good bonding surface for paint, and permits the operator to work in a more comfortable position, i.e., standing nearly erect instead of having to crouch. Outdoor blasting with the tested Blackhawk (20 to 40 mesh) copper slag is also environmentally acceptable to the State of Utah. Results of tests for the surface erosion rate with copper slag blasting are included

To develop a new mineral carbonation process that have a high efficiency in CO2 absorption into industry slag using low energy mechanical milling

Increase in the CO2 emission in atmosphere due to the combustion of fossil fuels has caused serious global warming. Electricity generation, tranportation, and industrial waste are the main sectors indentified to contribute to the emission of CO2 in Malaysia. In dealing with this issue, the absorption of CO2 into industrial waste was experimentally studied by the utilization of mechanical grinding method. This research is to aim a development of new mineral carbonation process that has a high efficiency in the capture and storage of CO2 with low energy consumption. In the first stage of this study, the behavior of CO2 absorption on electric arc furnace and ladle furnace slag was studied by low energy mechanical milling It was found that the absorption is occured during milling. CO2 was stored into the slag mainly as CaCO3. Thus this indicates that the CO2 can be stored permanently inside the slag with this method. In the next stage, the effect of dissolution of metal element into water on the behavior of CO2 absorption was investigated by leaching test experiment. It was found that , concentration value of Fe in pure water is higher but in river water the concentration is lower, the dissolve concentration decreased with the increased in the number of the leaching time. Concentration will be increased at the earlier stage before it decreased at final of concentration. This case because the liquid became saturated and cannot be to dissolved. After the pH steeply increased gradually at an early stage of the elution of slag, it slightly decreased. The pH decreased with the increased in the number of elution. The changes of pH in leaching test it seemed to depend on the content of CaO in the slag. For mechanism of CO2 absorption, morphological change of slag were study and the slag were characteried by using XRD, FE-SEM, and EDS

Interactive industrial application to represent isothermal sections of multi component phase diagram

“Make the slag and the steel will make itself” is an old phrase in steelmaking. The converter or basic oxygen furnace (BOF) process is a necessary step in the steel production during which carbon, phosphorus and other impurities present in the hot metal, coming from the blast furnace, are removed and steel is produced. This steel is tapped from the converter and further refined, next cast, rolled and finished. The BOF process is complex due to many reasons: high temperatures, multiple phases present, interactions of kinetics and thermodynamics, etc. Emphasis in this work is put upon the BOF steelmaking slag. Yet, even though this has been topic of many research projects no full understanding of all the slag related phenomena has been far from achieved. One of the difficulties is the multi-component nature of the slag. In its most simplified form, the slag is a three component system consisting of CaO, SiO2 and FeOn. However, in practical applications this slag contains more than three components, making graphical representations of equilibria complex and difficult. This work shows the potential to apply CALPHAD based data for industrial applications via an interactive visual tool. Isothermal sections of multi-components phase diagrams were constructed with Factsage 7.1 software. Addition of extra components to the calculated isothermal sections, gives a graphical representation which can be used to gain insight in certain observed phenomena in the BOF process. To illustrate that the interactive visualisation yields an interesting tool to integrate CALPHAD based calculations in industry two case studies from steelmaking are discussed: the effect of MgO upon the refractory wear and the effect of MgO upon dephosphorization

Influences of chloride immersion on zeta potential and chloride in concentration of cement-based materials

In this paper, the zeta potential of freshly mixed cement paste and hardened cement pastes, as well as the concentration index, was measured. The influences of chloride concentration in mixing water and slag content on zeta potential of freshly mixed pastes were studied. A proposed model was expressed to explain the relationship of zeta potential and concentration index of hardened cement pastes immersed in chloride solution. The results showed that the increase of chloride concentration in mixing water and slag replacement improved the zeta potential of freshly mixed cement, the hydration rate and concentration of ions in mixed water affects the zeta potential. With the increase of chloride concentration in soaking solution, the chloride concentration index and zeta potential of hardened cement paste all gradually decreased. The addition of slag gave some changes on chloride in concentration and zeta potential. The relationship among chloride concentration index, chloride concentration in soaking solution and slag replacement revealed by Gouy-Chapman model was in good agreement with the measured results