Electromagnetic Interference Shielding Effectiveness of Interlayered Systems Containing Metal-Oxide, Conducting Polymer and Carbon Nanotube Reinforced Polymeric Composites

The Electromagnetic Interference (EMI) Shielding Effectiveness (SE) has become one of the important requirements for the devices associated with telecommunication systems consisting of large frequency bands. The degradation of the quality of transmitting signal influenced by frequencies emitting from external sources can be reduced by covering the circuits of the devices by EMI Shielding materials like polymer composites, metal-based nanofiber mats, the metal of oxide films, etc. The investigation strives for the attenuation of EMI by introducing two composite mats from conducting polymer-based, multiwalled carbon nanotubes (MWCNTs) coated Nylon 6 nanofiber composites. Two other composite mats are also developed by the Forcespinning® method using sol solution of functionalized multiwalled carbon nanotubes (f-MWCNTs) and magnetite (Fe3O4) into as-prepared polyacrylonitrile (PAN) which is then carbonized at elevated temperature to convert it into carbon nanofiber (CNF). A total of four layers of mats are stacked and compression molded together to develop one multilayered composite (MLC 1). The Fe3O4 has higher magnetic properties which may provide a good magnetic loss effect. The focus is to investigate the synergistic effects between higher magnetic Fe3O4, conductive MWCNTs nanofillers with the dielectric CNF, conducting polymer, and functionalized MWCNTs coated nanofiber composite which can provide information about the dominating mechanism. (Absorption, reflection, or multiple reflections) for EMI SE. The multilayered composite (MLC 2) consisting 8 layers (repeating the stacking sequence again) has given the highest obtained value more than 40 dB EMI SE in the frequency range from 300–500 MHz. The results will bring some findings of optimized materials yielding good EMI SE in lightweight applications

Sensors and Biosensors Related to Magnetic Nanoparticles

This book describes interesting examples of magnetic materials with magnetic nanoparticles or compact devices using composites with nanoparticles, including new engineering solutions and theoretical contributions on the magnetic biosensing of soft matter composites. Authors from different countries formed international team of experts sharing 10 contributed papers, 1 feature paper, and 1 topical review

Engineering 3D architected metamaterials for enhanced mechanical properties and functionalities.

Compared with conventional materials, architected metamaterials have shown unprecedented mechanical properties and functionalities applications. Featured with controlled introduction of porosity and different composition, architected metamaterials have demonstrated unprecedent properties not found in natural materials. Such design strategies enable researchers to tailor materials and structures with multifunctionalies and satisfy conflicting design requirements, such as high stiffness and toughness; high strength with vibration mitigation properties, etc. Furthermore, with the booming advancement of 3D printing technologies, architected materials with precisely defined complex topologies can be fabricated effortlessly, which in turn promotes the research significantly. The research objectives of this dissertation are to achieve the enhanced mechanical properties and multifunctionalities of architected metamaterials by integrative design, computational modeling, 3D printing, and mechanical testing. Phononic crystal materials are capable of prohibiting the propagation of mechanical waves in certain frequency ranges. This certain frequency ranges are represented by phononic band gaps. Formally, band gaps are formed through two main mechanisms, Bragg scattering and local resonance. Band gaps induced by Bragg scattering are dependent on periodicity and the symmetry of the lattice. However, phononic crystals with Bragg-type band gaps are limited in their application because they do not attenuate vibration at lower frequencies without requiring large geometries. It is not practical to build huge models to achieve low frequency vibration mitigation. Alternatively, band gaps formed by local resonance are due to the excitation of resonant frequencies, and these band gaps are independent of periodicity. Therefore, lower frequency band gaps have been explored mostly through the production of phononic metamaterials that exploit locally resonant masses to absorb vibrational energy. However, despite research advances, the application of phononic metamaterials is sill largely hindered by their limited operation frequency ranges. Designing lightweight phononic metamaterials with low-frequency vibration mitigation capability is still a challenging topic. On the other hand, conventional phononic crystals usually exhibit very poor mechanical properties, such as low stiffness, strength, and energy absorption. This could largely limit their practical applications. Ideally, multifunctional materials and structures with both vibration mitigation property and high mechanical performance are demanded. In this work, we propose architected polymer foam material to overcome the challenges. Beside altering the topological architecture of metamaterials, tailoring the composition of materials is another approach to enhance the mechanical properties and realize multifunctionalities. Natural materials have adopted this strategy for long period of time. Biological structural materials such as nacre, glass sea sponges feature unusual mechanical properties due to the synergistic interplay between hard and soft material phases. These exceptional mechanical performance are highly demanded in engineering applications. As such, intensive efforts have been devoted to developing lightweight structural composites to meet the requirements. Despite the significant advances in research, the design and fabrication of low-cost structural materials with lightweight and superior mechanical performance still represent a challenge. Taking inspiration from cork material, we propose a new type of multilayered cellular composite (MCC) structure composed of hard brittle and soft flexible phases to tackle this challenge. On the other hand, piezoelectric materials with high sensitivity but low energy absorption have largely limited their applications, especially during harsh environment where external load could significantly damage the materials. Enlightened by the multiphase composite concept, we apply this design motif to develop a new interpenetrating-phased piezoelectric materials by combining PZT material as skeleton and PDMS material as matrix. By using a facial camphene-templated freeze-casting method, the co-continuous composites are fabricated with good quality. Through experiment and simulation studies, the proposed composite demonstrates multifunction with exceptional energy absorption and high sensitivity. Based on the above experimental studies, we further propose to use topology optimization framework to obtain the composites with the best performance of multifunctionalities. Specifically, we will use the solid isotropic material with penalization (SIMP) approach to optimize the piezoelectric materials with multi-objectives of 1) energy absorption and 2) electric-mechanical conversion property. The materials for the optimization design will be elastic PZT as skeleton and elatic material PDMS as matrix. To enable the gradient search of objective function efficiently, we will use adjoint method to derive the shape sensitivity analysis

Unscrambling Structured Chirality with Structured Light at Nanoscale Using Photo-induced Force

We introduce a microscopy technique that facilitates the prediction of spatial features of chirality of nanoscale samples by exploiting photo-induced optical force exerted on an achiral tip in the vicinity of the test specimen. The tip-sample interactive system is illuminated by structured light to probe both the transverse and longitudinal (with respect to the beam propagation direction) components of the sample magnetoelectric polarizability as the manifestation of its sense of handedness, i.e., chirality. We specifically prove that although circularly polarized waves are adequate to detect the transverse polarizability components of the sample, they are unable to probe the longitudinal component. To overcome this inadequacy, we propose a judiciously engineered combination of radially and azimuthally polarized beams, as optical vortices possessing pure longitudinal electric and magnetic field components along their vortex axis, respectively, hence probing longitudinal chirality. The proposed technique may benefit branches of science like stereochemistry, biomedicine, physical and material science, and pharmaceutic

Unscrambling Structured Chirality with Structured Light at the Nanoscale Using Photoinduced Force

We show that the gradient force generated by the near field of a chiral nanoparticle carries information about its chirality. On the basis of this physical phenomenon we propose a new microscopy technique that enables the prediction of spatial features of chirality of nanoscale samples by exploiting the photoinduced optical force exerted on an achiral tip in the vicinity of the test specimen. The tip-sample interactive system is illuminated by structured light to probe both the transverse and longitudinal (with respect to the beam propagation direction) components of the sample's magnetoelectric polarizability as the manifestation of its sense of handedness, i.e., chirality. We specifically prove that although circularly polarized waves are adequate to detect the transverse polarizability components of the sample, they are unable to probe the longitudinal component. To overcome this inadequacy and probe the longitudinal chirality, we propose a judiciously engineered combination of radially and azimuthally polarized beams as optical vortices possessing pure longitudinal electric and magnetic field components along their vortex axis, respectively. The proposed technique may benefit branches of science such as stereochemistry, biomedicine, physical and material science, and pharmaceutics

Computational aspects of electromagnetic NDE phenomena

The development of theoretical models that characterize various physical phenomena is extremely crucial in all engineering disciplines. In nondestructive evaluation (NDE), theoretical models are used extensively to understand the physics of material/energy interaction, optimize experimental design parameters and solve the inverse problem of defect characterization. This dissertation describes methods for developing computational models for electromagnetic NDE applications. Two broad classes of issues that are addressed in this dissertation are related to (i) problem formulation and (ii) implementation of computers;The two main approaches for solving physical problems in NDE are the differential and integral equations. The relative advantages and disadvantages of the two approaches are illustrated and models are developed to simulate electromagnetic scattering from objects or inhomogeneities embedded in multilayered media which is applicable in many NDE problems. The low storage advantage of the differential approach and the finite solution domain feature of the integral approach are exploited. Hybrid techniques and other efficient modeling techniques are presented to minimize the storage requirements for both approaches;The second issue of computational models is the computational resources required for implementation. Implementations on conventional sequential computers, parallel architecture machines and more recent neural computers are presented. An example which requires the use of massive parallel computing is given where a probability of detection model is built for eddy current testing of 3D objects. The POD model based on the finite element formulation is implemented on an NCUBE parallel computer. The linear system of equations is solved using direct and iterative methods. The implementations are designed to minimize the interprocessor communication and optimize the number of simultaneous model runs to obtain a maximum effective speedup;Another form of parallel computing is the more recent neurocomputer which depends on building an artificial neural network composed of numerous simple neurons. Two classes of neural networks have been used to solve electromagnetic NDE inverse problems. The first approach depends on a direct solution of the governing integral equation and is done using a Hopfield type neural network. Design of the network structure and parameters is presented. The second approach depends on developing a mathematical transform between the input and output space of the problem. A multilayered perceptron type neural network is invoked for this implementation. The network is augmented to build an incremental learning network which is motivated by the dynamic and modular features of the human brain

Photothermal Single Particle Detection in Theory & Experiments

The dissertation presents theoretical and experimental studies on the physical origin of the signal in photothermal microscopy of single particles. This noninvasive optical far field microscopy scheme allows the imaging and detection of single absorbing nanoparticles. Based on a heat-induced pertur- bation in the refractive index in the embedding medium of the nanoscopic absorber, a corresponding probe beam modification is measured and quantified. The method is well established and has been applied since its first demonstration in 2002 to the imaging and characterization of various absorbing particle species, such as quantum dots, single molecules and nanoparticles of different shapes. The extensive theoretical developments presented in this thesis provide the first quantitative assess- ment of the signal and at the same time enlarge its phenomenology and thereby its potential. On the basis of several approximation schemes to the Maxwell equations, which fundamentally gov- ern the interaction of light with inhomogeneities, several complementing models are devised which describe the photothermal signal both qualitatively and quantitatively. In succession an interdepen- dent and self-consistent set of theoretical descriptions is given and allows important experimental consequences to be drawn. In consequence, the photothermal signal is shown to correspond to the action of a nanoscopic (thermal) lens, represented by the spherically symmetric refractive index pro- file n(r) which accompanies the thermal expansion of the absorber’s environment. The achieved quantification allows the direct measurement of absorption cross-sections of nanoparticles. Further, a qualitatively new phenomenology of the signal is unraveled and experimentally demonstrated. The separate roles of the probing and the heating beams in photothermal microscopy is dismantled and the influence of their relative alignment shown to allow for a controlled adjustment of the effective detection volume. For the first time, both positive and negative signals are demonstrated to occur and to be the characteristic signature of the lens-like action on the probe beam. The detection of the probe beam’s modification is also shown to sensitively depend on the aperture used in the detection chan- nel, and a signal optimization is shown to be feasible. Also, a generalization of the detectable signal via the use of a quadrant photodiode is achieved. Specifically, measuring the far field beam deflec- tion the result of the beam passing the lens off-center manifests in a laterally split detection volume. Hereby, finally each classical photothermal spectroscopic techniques has been shown to possess its microscopic counterpart. Central to the understanding of this generalized and new phenomenology is a scalar wave-optical model which draws an analogy between the scattering of a massive particle wave-packet by a Coulomb potential and the deflection of a focused beam by a photonic potential connected with the thermal lens. The significance of the findings is demonstrated by its methodological implications on photother- mal correlation spectroscopy in which the diffusion dynamics of absorbing colloidal particles can be studied. The unique split focal detection volumes are shown to allow the sensitive measurement of a deterministic velocity field. Finally, the method is supplemented by a newly introduced sta- tistical analysis method which is capable of characterizing samples containing a heterogeneous size distribution.:Contents Bibliographic description Abbreviations 1 Introduction 2 Theoretical Background 2.1 The current literature on the subject of the photothermal signal 2.2 Thermal conduction, and the temperature field around heated nanoparticles 2.3 The linear thermo-refractive response and the thermal lens 2.4 MAXWELL equations and approximation schemes 2.4.1 The MAXWELL equations 2.4.2 HELMHOLTZ equations 2.4.3 Paraxial HELMHOLTZ equation for the field components 2.4.4 Geometrical optics and the eikonal ansatz 2.5 Diffraction and the optical resolution limit in far field microscopy 2.5.1 Transmission scanning microscopy 2.5.2 Point spread functions and aberrations 2.5.3 Scalar diffraction approximation for weakly focused beams 2.5.4 Vectorial diffraction for highly focused electromagnetic fields 2.5.5 Theoretical description of transmission signals 2.6 Elastic scattering of light 2.6.1 Overview of optical elastic scattering theory 2.6.2 The integral equation of potential scattering and the BORN approximation 2.6.3 The generalized LORENZ-MIE theory 2.6.4 The electromagnetic fields 2.6.5 Description of the incident field: beam shape coefficients 2.6.6 Multilayered scatterers 2.6.7 POYNTING vector and field decomposition 2.6.8 Energy balance & total cross-sections 2.6.9 Optical theorem & the extinction paradox 2.6.10 Small particle scattering: the RAYLEIGH-limit 2.7 Optical properties of gold nanoparticles & Surface plasmon resonances 2.7.1 Dielectric function of gold 2.7.2 Total cross-sections of plasmonic nanoparticles properties of gold nanoparticles & Surface plasmon resonances 2.8 (Hot) BROWNian motion, diffusion and their statistical analysis 2.8.1 (Hot) BROWNian motion 2.8.2 Diffusion and correlation analysis 2.8.3 Methods regarding the signal statistics of diffusing tracer particles 2.9 RUTHERFORD scattering of charged particles 2.9.1 Classical RUTHERFORD scattering 2.9.2 Quantum mechanical COULOMB scattering 3 Experimental Setup 3.1 Sample preparation 3.2 Photothermal microscopy setup 4 Photothermal Imaging: Results and Discussion 4.1 MAXWELL equations: Exact treatment of the PT signal 4.1.1 Angularly resolved powers: Fractional cross-sections 4.1.2 Incident power and background normalization 4.1.3 Fractional scattering and extinction cross-sections (off-axis) 4.1.4 Fractional scattering and extinction cross-sections (on-axis) 4.1.5 Small particle approximation(on-axis) 4.1.6 General properties of transmission scans 4.1.7 The thermal lens n(r) in the MIE-scattering framework 4.1.8 The photothermal signal F in the MIE scattering framework 4.2 Geometrical optics: Photonic RUTHERFORD scattering (ray optics) 4.2.1 FERMAT’s principle for a thermal lens medium 4.2.2 Gaussian beam transformation by a thermal lens 4.2.3 Experiments using weakly focused, i.e. nearly Gaussian beams 4.3 HELMHOLTZ equation: Photonic RUTHERFORD scattering (wave optics) 4.3.1 Plane-wave scattering 4.3.2 Focused beam scattering 4.3.3 Connection to the far field 4.3.4 Photothermal Rutherford scattering microscopy 4.3.5 Photothermal half-aperture measurements 4.4 Paraxial HELMHOLTZ equation: FRESNEL diffraction by a thermal lens 4.4.1 The diffraction integral and the phase mask for a thermal lens 4.4.2 The photothermal signal expressed via the image plane field 4.4.3 Experimental demonstration of the signal inversion 4.4.4 Connection to photothermal RUTHERFORD scattering 4.5 Plane-wave extinction & scattering by a thermal lens 4.5.1 The BORN approximation for the ideal and time-dependent thermal lens 4.5.2 The eikonal approximation for the ideal thermal lens and x>>1 4.5.3 Lessons to be learned from plane-wave scattering by thermal lenses 4.6 What is a lens? And is n(r) a lens? 5 Methodological Applications of the Results 5.1 Generalized photothermal correlation spectroscopy (incl. twin-PhoCS) 5.2 Photothermal signal distribution analysis (PhoSDA) 6 Summary and Outlook 6.1 Summary of the results 6.2 Outlook 7 Appendix 7.1 Material parameters 7.2 Calculation parameters 7.3 Interactive simulation scripts (Processing) 7.4 Vectorial scattering in the BORN-approximation 7.5 Details regarding the scattering framework 7.5.1 Connection between Gmn,TE,TM of Ref.1 and gmn,TE,TM in the GLMT 7.5.2 Off-axis BSCs including aberration (single interface) 7.5.3 Details on the incidence power Pinc 7.5.4 Details on the incidence power Pinc for arbitrary beams 7.5.5 Explicit expressions for the spherical field components of Es,i and Hs,i 7.5.6 Note on the time-dependence and the corresponding sign-conventions in M 7.5.7 Recurrence relation for Pn and tn 7.5.8 Gaussian beam shape coefficients: Off-axis 7.5.9 Multilayered Scatterer 7.5.10 POYNTING-vector and energy flow fields 7.5.11 Convergence 7.5.12 Further evaluations in the GLMT framework 7.5.13 Diffraction model: Comparison of angular PT signal pattern to the GLMT 7.6 Details on geometrical optics models 7.6.1 Geometrical optics: Exact solution r(f) for |bx|<1 7.6.2 Correspondences in photonic and partile RUTHERFORD scattering 7.6.3 On the difference in the definition of optical energy 7.6.4 Ray-opticsphotothermalsignal 7.6.5 Thick lens raytracing and the equivalent lens shape for a given aberration 7.7 Thermal lens around a wire of radius R 7.8 Twin-PhoCS: Graphic illustration of the CCF integrand Curriculum Vitae Publications Declaration Acknowledgements List of Tables List of Figures Bibliograph

Helicity and duality symmetry in light matter interactions: Theory and applications

In my thesis, I first develop the theoretical basis and tools for the use of helicity and duality in the study, understanding and engineering of interactions between electromagnetic radiation and material systems. Then, within the general framework of symmetries and conservation laws, I apply the theoretical results to several different problems: Optical activity, zero backscattering, metamaterials for transformation optics and nanophotonics phenomena involving the electromagnetic angular momentum. The tool has provided new insights and design guidelines in all these cases.Comment: PhD Thesis, Department of Physics and Astronomy, Macquarie University. Fixed a very slow figure from the previous versio

Synthesis of sub-5 nm Co-doped SnO2_2 nanoparticles and their structural, microstructural, optical and photocatalytic properties

A swift chemical route to synthesize Co-doped SnO$_2$ nanopowders is described. Pure and highly stable Sn$_{1-x}$Co$_x$O$_{2-\delta}$ (0 $\le$ x $\le$ 0.15) crystalline nanoparticles were synthesized, with mean grain sizes < 5 nm and the dopant element homogeneously distributed in substitutional sites of the SnO$_2$ matrix. The UV-visible diffuse reflectance spectra of the Sn$_{1-x}$Co$_x$O$_{2-\delta}$ samples reveal red shifts, the optical bandgap energies decreasing with increasing Co concentration. The Urbach energies of the samples were calculated and correlated with their bandgap energies. The photocatalytic activity of the Sn$_{1-x}$Co$_x$O$_{2-\delta}$ samples was investigated for the 4-hydroxylbenzoic acid (4-HBA) degradation process. A complete photodegradation of a 10 ppm 4-HBA solution was achieved using 0.02% (w/w) of Sn$_{0.95}$Co$_{0.05}$O$_{2-\delta}$ nanoparticles in 60 min of irradiation.Comment: 29 pages, 2 tables, 10 figure