Microfibers for juice analysis by solid-phase microextraction.

In view of the interest in analyzing volatile compounds by SPME, the following five microfibers were tested, polydimethylsiloxane; polyacrylate; polydimethylsiloxane/divinylbenzene; carboxen/polydimethylsiloxane, and carbowax/divinylbenzene, to select the one which presents the best performance for the adsorption of the volatile compounds present in the headspace of acid lime juice samples. Sample stabilization time variations (30 and 60 minutes) were assessed as well the addition of NaCl to the samples. It was verified that the chromatogram with the most adsorbed volatile compounds was obtained with PDMS/DVB microfiber at 30 minutes and the addition of 0.2 g NaCl

Polydimethylsiloxane as an elastic material applied in a capacitive accelerometer

Polydimethylsiloxane is a silicone rubber. It has a unique flexibility, resulting in one of the lowest glass-transition temperatures of any polymer. Furthermore, it shows a low elasticity change versus temperature, a high thermal stability, chemical inertness, dielectric stability, shear stability and high compressibility. Because of its high flexibility and the very low drift of its properties with time and temperature, polydimethylsiloxane could be well suited for mechanical sensors, such as accelerometers. A novel capacitive accelerometer with polydimethylsiloxane layers as springs has been realized. The obtained measurement results are promising and show a good correspondence with the theoretical values

Low outgassing polydimethylsiloxane material and preparation thereof

A fluid polydimethylsiloxane resin having improved outgassing properties in the cured state is described. The fluid resin is obtained by pouring, to a height of up to about 2 inches a starting polydimethylsiloxane resin such as RTV-602 silicone resin and devolatilizing the starting resin at a temperature of about 125 to 150 C under a vacuum of at least 0.00001 torr

Polydimethylsiloxane based microfluidic diode

In this paper, we present a novel elastomer-based microfluidic device for rectifying flow. The device is analogous to an electronic diode in function since it allows flow in one direction and stops flow in the opposing direction. The device is planar, in-line and can be replica molded via standard soft lithography techniques. The fabrication process is outlined in detail and follows a simple procedure that requires only photolithography and one replica molding step. Several geometries of devices are presented along with their flow versus pressure characteristics. A brief discussion of the device behavior is presented along with possible uses for the device

Neutral-cluster implantation in polymers by computer experiments

In this work we perform atomistic model potential molecular dynamics simulations by means of state-of-the art force-fields to study the implantation of a single Au nanocluster on a Polydimethylsiloxane substrate. All the simulations have ben performed on realistic substrate models containing up to 4.6 millions of atoms having depths up to 90 nm and lateral dimensions up to 25 nm. We consider both entangled-melt and cross-linked Polydimethylsiloxane amorphous structures. We show that even a single cluster impact on the Polydimethylsiloxane substrate remarkably changes the polymer local temperature and pressure. Moreover we observe the presence of craters created on the polymer surface having lateral dimensions comparable to the cluster radius and depths strongly dependent on the implantation energy. Present simulations suggest that the substrate morphology is largely affected by the cluster impact and that most-likely such modifications favor the the penetration of the next impinging clusters

Polydimethylsiloxane (PDMS)-based microfluidic channel with integrated commercial pressure sensors

The precise characterisation of boiling in microchannels is essential for the optimisation of applications requiring two phase cooling. In this paper polydimethylsiloxane (PDMS) is employed to make microchannels for characterising microboiling. In particular the material properties of PDMS facilitate rapid prototyping and its optical transparency provides the capability to directly view any fluid flow. The production of microchannels is complicated by the need to integrate custom made sensors. This paper presents a PDMS microfluidic device with integrated commercial pressure sensors, which have been used to perform a detailed characterisation of microboiling phenomena. The proposed approach of integrating commercial pressure sensors into the channel also has potential applications in a range of other microsystems

An Evaluation of The Host Response to An Interspinous Process Device Based on A Series of Spine Explants: Device for Intervertebral Assisted Motion (DIAM®)

Background: The objective of this study was to evaluate the host response to an interspinous process device [Device for Intervertebral Assisted Motion (DIAM®)] based on a series of nine spine explants with a mean post-operative explant time of 35 months. Methods: Explanted periprosthetic tissues were processed for histology and stained with H&E, Wright-Giemsa stain, and Oil Red O. Brightfield and polarized light microscopy were used to evaluate the host response to the device and the resultant particulate debris. The host response was graded per ASTM F981-04. Quantitative histomorphometry was used to characterize particle size, shape, and area per ASTM F1877-05. The presence or absence of bone resorption was also evaluated when bony tissue samples were provided. Results: Periprosthetic tissues demonstrated a non-specific foreign body response composed of macrophages and foreign body giant cells to the DIAM® device in most of the accessions. The foreign body reaction was not the stated reason for explantation in any of the accessions. Per ASTM F981-04, a “very slight” to “mild” to “moderate” chronic inflammatory response was observed to the biomaterials and particulate, and this varied by tissue sample and accession. Particle sizes were consistent amongst the explant patients with mean particle size on the order of several microns. Osteolysis, signs of toxicity, necrosis, an immune response, and/or device related infection were not observed. Conclusions: Cyclic loading of the spine can cause wear in dynamic stabilization systems such as DIAM®. The fabric nature of the DIAM® device’s polyethylene terephthalate jacket coupled with the generation of polymeric particulate debris predisposes the device to a foreign body reaction consisting of macrophages and foreign body giant cells. Although not all patients are aware of symptoms associated with a foreign body reaction to a deeply implanted device, surgeons should be aware of the host response to this device

Topography driven spreading

Roughening a hydrophobic surface enhances its nonwetting properties into superhydrophobicity. For liquids other than water, roughness can induce a complete rollup of a droplet. However, topographic effects can also enhance partial wetting by a given liquid into complete wetting to create superwetting. In this work, a model system of spreading droplets of a nonvolatile liquid on surfaces having lithographically produced pillars is used to show that superwetting also modifies the dynamics of spreading. The edge speed-dynamic contact angle relation is shown to obey a simple power law, and such power laws are shown to apply to naturally occurring surfaces