Nanostructured Transition Metal Oxides for Energy Storage and Conversion

The conventional film configuration of electrochemical electrodes hardly fulfills the high energy and efficiency requirements because heavy electroactive material deposition restricts ion diffusion path, and lowers power density and fault tolerance. In this thesis, I demonstrate that novel nanoarchitectured transition metal oxides (TMOs), e.g. MnO2, V2O5, and ZnO, and their relevant nanocomposites were designed, fabricated and assembled into devices to deliver superior electrochemical performances such as high energy and power densities, and rate capacity. These improvements could be attributed to the significant enhancement of surface area, shortened ion diffusion distances and facile penetration of electrolyte solution into open structures of networks. The utilization of Forcespinning® , a newly developed nanofiber processing technology, for large-scale energy storage and conversion applications is emphasized. This process facilitates the contradiction between the micro-batch production and the ease of large-scale manufacturing

Future benefits and applications of intelligent on-board processing to VSAT services

The trends and roles of VSAT services in the year 2010 time frame are examined based on an overall network and service model for that period. An estimate of the VSAT traffic is then made and the service and general network requirements are identified. In order to accommodate these traffic needs, four satellite VSAT architectures based on the use of fixed or scanning multibeam antennas in conjunction with IF switching or onboard regeneration and baseband processing are suggested. The performance of each of these architectures is assessed and the key enabling technologies are identified

GUIDELINES FOR THE DESIGN OF ENHANCED, COST EFFECTIVE NETWORKS IN A MANUFACTURING ENVIRONMENT

Investigations into the transmission of real-time interactive speech over local area networks (LAN) in an industriai/commerciai environment to eventually obviate the need for a private automatic branch exchange and ultimately prepare the way for a single interactive integrated information system (PS) that provides work stations, which are networked via a LAN, with a fully interactive speech and graphics facility commensurate with the future requirements in computer integrated manufacturing (CIM). The reasons for conducting this programme of research were that existing LANs do not offer a real time interactive speech facility. Any verbal communication between workstation users on the LAN has to be carried out over a telephone network (PABX). This necessitates the provision of a second completely separate network with its associated costs. Initial investigations indicate that there is sufGcient capacity on existing LANs to support both data and real-time speech provided certain data packet delay criteria can be met. Earlier research work (in the late 1980s) has been conducted at Bell Labs and MIT. [Ref 25, 27 & 28], University of Strathclyde [Ref 24] and at BTRL [Ref 22 and 37]. In all of these cases the real time implementation issues were not fijlly addressed. In this thesis the research work reported provides the main criteria for the implementation of real-time interactive speech on both existing and newly installed networks. With such enhanced communication facilities, designers and engineers on the shop floor can be projected into their suppliers, providing a much greater integration between manufacturer and supplier which will be beneficial as Concurrent and Simultaneous Engineering Methodologies are further developed. As a result, various LANs have been evaluated as to their suitability for the transmission of real time interactive speech. As LANs, in general, can be separated into those with either deterministic or stochastic access mechanisms, investigations were carried out into the ability of both the: (i) Token Passing Bus LANs supporting the Manufacturing and Automation Protocol (MAP)—Deterministic and (u) Carrier Sense Multiple Access/Collision Detection (CSMA/CD) LANs supporting the Technical Office Protocol (TOP)— Stochastic to support real time interactive speech, as both are used extensively in commerce and manufacturing. The thesis that real time interactive speech can be transmitted over LANs employed in a computer integrated manufacturing environment has to be moderated following the tests carried out in this work, as follows:- The Token Passing LAN presents no serious problems under normal traffic conditions, however, the CSMA/CD LAN can only be used in relatively light traffic conditions i.e. below 30% of its designed maximum capacity, providing special arrangements are made to minimise the access, transmission and processing delays of speech packets. Given that a certain amount of delay is inevitable in packet switched systems (LANs), investigations have been carried out into techniques for reducing the subjective efifect of speech packet loss on real-time interactive systems due to the unacceptable delays caused by the conditions mentioned above

Large-Scale Client/Server Migration Methodology

The purpose of this dissertation is to explain how to migrate a medium-sized or large company to client/server computing. It draws heavily on the recent IBM Boca Raton migration experience. The client/server computing model is introduced and related, by a Business Reengineering Model, to the major trends that are affecting most businesses today, including business process reengineering, empowered teams, and quality management. A recommended information technology strategy is presented. A business case development approach, necessary to justify the large expenditures required for a client/server migration, is discussed. A five-phase migration management methodology is presented to explain how a business can be transformed from mid-range or mainframe-centric computing to client/server computing. Requirements definition, selection methodology, and development alternatives for client/server applications are presented. Applications are broadly categorized for use by individuals (personal applications) or teams. Client systems, server systems, and network infrastructures are described along with discussions of requirements definition, selection, installation, and support. The issues of user communication, education, and support with respect to a large client/server infrastructure are explored. Measurements for evaluation of a client/server computing environment are discussed with actual results achieved at the IBM Boca Raton site during the 1994 migration. The dissertation concludes with critical success factors for client/server computing investments and perspectives regarding future technology in each major area

Computer aided reliability, availability, and safety modeling for fault-tolerant computer systems with commentary on the HARP program

Many of the most challenging reliability problems of our present decade involve complex distributed systems such as interconnected telephone switching computers, air traffic control centers, aircraft and space vehicles, and local area and wide area computer networks. In addition to the challenge of complexity, modern fault-tolerant computer systems require very high levels of reliability, e.g., avionic computers with MTTF goals of one billion hours. Most analysts find that it is too difficult to model such complex systems without computer aided design programs. In response to this need, NASA has developed a suite of computer aided reliability modeling programs beginning with CARE 3 and including a group of new programs such as: HARP, HARP-PC, Reliability Analysts Workbench (Combination of model solvers SURE, STEM, PAWS, and common front-end model ASSIST), and the Fault Tree Compiler. The HARP program is studied and how well the user can model systems using this program is investigated. One of the important objectives will be to study how user friendly this program is, e.g., how easy it is to model the system, provide the input information, and interpret the results. The experiences of the author and his graduate students who used HARP in two graduate courses are described. Some brief comparisons were made with the ARIES program which the students also used. Theoretical studies of the modeling techniques used in HARP are also included. Of course no answer can be any more accurate than the fidelity of the model, thus an Appendix is included which discusses modeling accuracy. A broad viewpoint is taken and all problems which occurred in the use of HARP are discussed. Such problems include: computer system problems, installation manual problems, user manual problems, program inconsistencies, program limitations, confusing notation, long run times, accuracy problems, etc

A novel routing approach for source location privacy in wireless sensor networks

Wireless sensor networks (WSNs) allows the world to use a technology for event supervision for several applications like military and civilian applications. Network privacy remained a prime concern in WSNs. Privacy of Source location is assumed to be one of the main un-tackled issues in privacy ofWSNs. Privacy of the source location is vital and highly jeopardized with the use of wireless communications. For WSNs, privacy of source location is become more complex by the fact that sensor nodes are low cost and energy efficient radio devices. So, use of computation intensive encryption methods and large scale broadcasting based algorithms are found to be unsuitable for WSNs. Several schemes have been proposed to ensure privacy of source location in WSNs. But, most of existing schemes depends on public-key cryptosystems, while others are either energy inefficient or have certain security flaws like leakage of information using directional attacks or traffic analysis attacks. In this thesis, we propose a novel dynamic routing based approach for preserving privacy of source location in WSNs, which injects fake packets in network and switches the real packet information among different routing patterns. It addresses the privacy of source location by considering the limited features of WSNs. Major contributions of this work includes two aspects. Firstly, different from the existing approaches, the proposed approach considers enhancing the security of nodes with minimal transmission delay and consumes power with minimum effect on the lifetime of the network. Secondly, the proposed approach is designed to defend many attacks like hop by hop, directional attacks by choosing a suitable path to send information from node to BS dynamically without affecting network life significantly. Thus, it becomes difficult for the attacker to find the exact path, and hence the original location of node. The proposed approach is implemented and validated by comparing its results with that of the existing approaches in the field of source location privacy in terms of Power consumption, Transmission delay, Safety period, and network lifetime. The analysis of comparative results indicates that the proposed approach is superior to the existing approaches in preserving the source location privacy

Space Shuttle/TDRSS communication and tracking systems analysis

In order to evaluate the technical and operational problem areas and provide a recommendation, the enhancements to the Tracking and Data Delay Satellite System (TDRSS) and Shuttle must be evaluated through simulation and analysis. These enhancement techniques must first be characterized, then modeled mathematically, and finally updated into LinCsim (analytical simulation package). The LinCsim package can then be used as an evaluation tool. Three areas of potential enhancements were identified: shuttle payload accommodations, TDRSS SSA and KSA services, and shuttle tracking system and navigation sensors. Recommendations for each area were discussed

Phenolic resin aerogels: The significance of inserting an oxidative ring-fusion aromatization step at the early stages of pyrolytic carbonization, and the application of these materials in CO₂ storage and separation

Phenolic aerogels, prepared via polycondensation of phenolic monomers and formaldehyde, were converted to carbon aerogels at 800 ⁰C/Ar followed by reactive etching under flowing CO2. Previously, it was found that a lower-temperature air-oxidation of polybenzoxazine aerogels was necessary in order to obtain highly porous, isomorphic carbon aerogels with high carbonization yields. Using those findings as the point of departure, phenolic aerogels were oxidized at 240 ⁰C/air prior to carbonization. During that air-oxidation step, phenolic aerogels based on phloroglucinol (1,3,5- trihydroxybenzene) undergo fusion of their aromatic rings, yielding 6-membered heteroaromatic pyryliums with pendant phenoxide ions. The resulting carbon aerogels have higher surface areas than other carbon aerogels not subjected to aromatization. Subsequently, carbon aerogels were studied for their CO2 adsorption capacity at 273 K up to 1 bar, relevant to post-combustion separation of CO2 from N2. Carbon aerogels from phenolic resins were compared to carbon aerogels from Ishida\u27s polybenzoxazine, and from a random copolymer of polyamide, polyurea, and polyimide. The results show that phenolic resin-derived carbons (containing phenoxide) adsorb more CO2 than the latter, which contain N in addition to oxygen. Interestingly, resorcinol-formaldehyde-derived carbon aerogels uptook 14.8 ± 3.9 mmol g-1 CO2, which is much higher than the values reported in the literature for other microporous materials. Opening of closed micropores and enlargement of micropore size, resulted in a multilayer coverage of micropore walls with CO2. The high capacity for CO2 was attributed to an energy-neutral reaction between surface phenoxides and CO2 --Abstract, page iv