PET and PVC separation with hyperspectral Imagery

Traditional plants for plastic separation in homogeneous products employ material physical properties (for instance density). Due to the small intervals of variability of different polymer properties, the output quality may not be adequate. Sensing technologies based on hyperspectral imaging have been introduced in order to classify materials and to increase the quality of recycled products, which have to comply with specific standards determined by industrial applications. This paper presents the results of the characterization of two different plastic polymers—polyethylene terephthalate (PET) and polyvinyl chloride (PVC)—in different phases of their life cycle (primary raw materials, urban and urban-assimilated waste and secondary raw materials) to show the contribution of hyperspectral sensors in the field of material recycling. This is accomplished via near-infrared (900–1700 nm) reflectance spectra extracted from hyperspectral images acquired with a two-linear-spectrometer apparatus. Results have shown that a rapid and reliable identification of PET and PVC can be achieved by using a simple two near-infrared wavelength operator coupled to an analysis of reflectance spectra. This resulted in 100% classification accuracy. A sensor based on this identification method appears suitable and inexpensive to build and provides the necessary speed and performance required by the recycling industry

Comparison of latent variable-based and artificial intelligence methods for impurity detection in PET recycling from NIR hyperspectral images

[EN] In polyethylene terephthalate's (PET)'s recycling processes, separation from polyvinyl chloride (PVC) is of prior relevance due to its toxicity, which degrades the final quality of recycled PET. Moreover, the potential presence of some polymers in mixed plastics (such as PVC in PET) is a key aspect for the use of recycled plastic in products such as medical equipment, toys, or food packaging. Many works have dealt with plastic classification by hyperspectral imaging, although only some of them have been directly focused on PET sorting and very few on its separation from PVC. These works use different classification models and preprocessing techniques and show their performance for the problem at hand. However, still, there is a lack of methodology to address the goal of comparing and finding the best model and preprocessing technique. Thus, this paper presents a design of experiments-based methodology for comparing and selecting, for the problem at hand, the best preprocessing technique, and the best latent variable-based and/or artificial intelligence classification method, when using NIR hyperspectral images. There is a lack of methodology to address the goal of comparing and finding the best model and preprocessing technique. Thus, this paper presents a design of experiments-based methodology for comparing and selecting, for the problem at hand, the best preprocessing technique, and the best latent variable-based and/or artificial intelligence classification method when using near-infrared hyperspectral images.Universitat Politecnica de Valencia, Grant/Award Number: UPV-FE-16-B18This research was partially supported by the Universitat Politècnica de València under the project UPV‐FE‐16‐B18.Galdón-Navarro, B.; Prats-Montalbán, JM.; Cubero-García, S.; Blasco Ivars, J.; Ferrer, A. (2018). Comparison of latent variable-based and artificial intelligence methods for impurity detection in PET recycling from NIR hyperspectral images. Journal of Chemometrics. 32(1):1-14. https://doi.org/10.1002/cem.2980S11432

Quantifying marine plastic debris in a beach environment using spectral analysis

Marine plastic debris (MPD) is a globally relevant environmental challenge, with an estimated 8 million tons of synthetic debris entering the marine environment each year. Plastic has been found in all parts of the marine environment, including the surface layers of the ocean, within the water column, in coastal waters, on the benthic layer and on beaches. While research on detecting MPD using remote sensing is increasing, most of it focuses on detecting floating debris in open waters, rather than detecting MPD on beaches. However, beaches present challenges that are unique from other parts of the marine environment. In order to better understand the spectral properties of beached MPD, we present the SWIR reflectance of weathered MPD and virgin plastics over a sandy substrate. We conducted spectral feature analysis on the different plastic groups to better understand the impact that polymers have on our ability to detect synthetic debris at sub-pixel surface covers that occur on beaches. Our results show that the minimum surface cover required to detect MPD on a sandy surface varies between 2–8% for different polymer types. Furthermore, plastic composition affects the magnitude of spectral absorption. This suggests that variation in both surface cover and polymer type will inform the efficacy of beach litter detection methods

A Review of Sorting and Separating Technologies Suitable for Compostable and Biodegradable Plastic Packaging

As a result of public pressure and government legislation to reduce plastic waste there has been a sharp rise in the manufacture and use of alternatives to conventional plastics including compostable and biodegradable plastics. If these plastics are not collected separately, they can contaminate plastic recycling, organic waste streams, and the environment. To deal with this contamination requires effective identification and sorting of these different polymer types to ensure they are separated and composted at end of life. This review provides the comprehensive overview of the identification and sorting technologies that can be applied to sort compostable and biodegradable plastics including gravity-based sorting, flotation sorting, triboelectrostatic sorting, image-based sorting, spectral based sorting, hyperspectral imaging and tracer-based sorting. The advantages and limitations of each sorting approach are discussed within a circular economy framework

Automatic identification and classification of compostable and biodegradable plastics using hyperspectral imaging

In the UK waste management systems biodegradable and compostable packaging are not automatically detected and separated. As a result, their fate is generally landfill or incineration, neither of which is an environmentally good outcome. Thus, effective sorting technologies for compostable plastics are needed to help improve composting rates of these materials and reduce the contamination of recycling waste streams. Hyperspectral imaging (HSI) was applied in this study to develop classification models for automatically identifying and classifying compostable plastics with the analysis focused on the spectral region 950–1,730 nm. The experimental design includes a hyperspectral imaging camera, allowing different chemometric techniques to be applied including principal component analysis (PCA) and partial least square discriminant analysis (PLS-DA) to develop a classification model for the compostable materials plastics. Materials used in this experimental analysis included compostable materials (sugarcane-derived and palm leaf derived), compostable plastics (PLA, PBAT) and conventional plastics (PP, PET, and LDPE). Our strategy was to develop a classification model to identify and categorize various fragments over the size range of 50 x 50 mm to 5 x 5 mm. Results indicated that both PCA and PLS-DA achieved classification scores of 100% when the size of material was larger than 10 mm x 10 mm. However, the misclassification rate increased to 20% for sugarcane-derived and 40% for palm leaf-based materials at sizes of 10 x 10 mm or below. In addition, for sizes of 5 x 5 mm, the misclassification rate for LDPE and PBAT increased to 20%, and for sugarcane and palm-leaf based materials to 60 and 80% respectively while the misclassification rate for PLA, PP, and PET was still 0%. The system is capable of accurately sorting compostable plastics (compostable spoons, forks, coffee lids) and differentiating them from identical looking conventional plastic items with high accuracy

Hyperspectral imaging based detection of PVC during Sellafield repackaging procedures.

Traditionally, Special Nuclear Material (SNM) at Sellafield has been stored in multi-layered packages, consisting of metallic cans and an over-layer of plasticized Polyvinyl Chloride (PVC) as an intermediate layer when transitioning between areas of different radiological classification. However, it has been found that plasticized PVC can break down in the presence of both radiation and heat, releasing hydrochloric acid which can corrode these metallic containers. Therefore, internal repackaging procedures at Sellafield have focused recently on the removal of these PVC films from containers, where as much degraded and often adhered PVC as possible is manually removed based on visual inspection. This manual operation is time-consuming and it is possible that residual fragments of PVC could remain, leading to corrosion-related issues in future. In this work, Hyperspectral Imaging (HSI) was evaluated as a new tool for detecting PVC on metallic surfaces. Samples of stainless steel type 1.4404 – also known as 316L, the same as is used to construct SNM cans – and PVC were imaged in our experiments, and Support Vector Machine (SVM) classification models were used to generate detection maps. In these maps, pixels were classified into either PVC or 316L based on their spectral responses in the range 954-1700nm of the electromagnetic spectrum. Results suggest that HSI could be used for an effective automated detection and quantification of PVC during repackaging procedures, detection and quantification that could be extended to other similar applications

Portable multispectral imaging system based on Raspberry Pi

Purpose In this work, the authors aim to present a compact low-cost and portable spectral imaging system for general purposes. The developed system provides information that can be used for a fast in situ identification and classification of samples based on the analysis of captured images. The connectivity of the instrument allows a deeper analysis of the images in an external computer. Design/methodology/approach The wavelength selection of the system is carried out by light multiplexing through a light-emitting diode panel where eight wavelengths covering the spectrum from ultraviolet (UV) to near-infrared region (NIR) have been included. The image sensor used is a red green blue – infrared (RGB-IR) micro-camera controlled by a Raspberry Pi board where a basic image processing algorithm has been programmed. It allows the visualization in an integrated display of the reflectance and the histogram of the images at each wavelength, including UV and NIRs. Findings The prototype has been tested by analyzing several samples in a variety of applications such as detection of damaged, over-ripe and sprayed fruit, classification of different type of plastic materials and determination of properties of water. Originality/value The designed system presents some advantages as being non-expensive and portable in comparison to other multispectral imaging systems. The low-cost and size of the camera module connected to the Raspberry Pi provides a compact instrument for general purposes.Project CTQ2013-44545-R from the Ministry of Economy and Competitiveness (Spain)Junta de Andalucía (Proyecto de Excelencia P10-FQM-5974)European Regional Development Funds (ERDF

Spectral Analysis of Marine Debris in Simulated and Observed Sentinel-2/MSI Images using Unsupervised Classification

Marine litter poses significant threats to marine and coastal environments, with its impacts ever-growing. Remote sensing provides an advantageous supplement to traditional mitigation techniques, such as local cleaning operations and trawl net surveys, due to its capabilities for extensive coverage and frequent observation. In this study, we used Radiative Transfer Model (RTM) simulated data and data from the Multispectral Instrument (MSI) of the Sentinel-2 mission in combination with machine learning algorithms. Our aim was to study the spectral behavior of marine plastic pollution and evaluate the applicability of RTMs within this research area. The results from the exploratory analysis and unsupervised classification using the KMeans algorithm indicate that the spectral behavior of pollutants is influenced by factors such as the type of polymer and pixel coverage percentage. The findings also reveal spectral characteristics and trends of association and differentiation among elements. The applied methodology is strongly dependent on the data, and if reapplied in new, more diverse, and detailed datasets, it can potentially generate even better results. These insights can guide future research in remote sensing applications for detecting marine plastic pollution.Comment: Manuscript submitted to Ocean and Coastal Research journa