Understanding Cross-Conjugation for Organic Electronics

Comunicación a congresopi-Conjugated organic molecules have been the focus of interest since they have been probed as potential semiconducting materials,[1] suitable for replacing the widely used silicon technologies. Their structural, optical and conductive properties are now under study to improve their application in organic electronics and to make possible their ad hoc synthesis. In this sense, the knowledge of the pi-electron delocalization is crucial to stablish the relation between the properties and the function, enabling the development of a synthesis guide based on the specific application. The most acknowledged conjugated organic materials are those which present extended, linearlyconjugated pi-systems. [1,2] However, this is not the only way of pi-electron delocalization: homoconjugation, cross-conjugation, curved-conjugation, etc. constitute different electronic designs to achieve new organic materials. There is a relative high abundance in the organic world of cross-conjugated but limited comprehension. [1,2,3] Thus, the understanding of how cross-conjugation works in -electronic systems is of importance. Following this idea, in this project we show 4 different structures which present two perpendicular pi-conjugated paths and how the cross-conjugated property is revealed. On the one hand, two molecules based on thieno[3,4-c]pyrrole-4,6-dione quaterthiophenes[2,3] allow us toaccomplish the subject from the aromatic/quinoidal outlook, and, on the other hand, two molecules with an anthanthrone core make possible the study from the perspective of the substituent groups. [4]Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Bias-induced insulator-metal transition in organic electronics

We investigate the bias-induced insulator-metal transition in organic electronics devices, on the basis of the Su-Schrieffer-Heeger model combined with the non-equilibrium Green's function formalism. The insulator-metal transition is explained with the energy levels crossover that eliminates the Peierls phase and delocalizes the electron states near the threshold voltage. This may account for the experimental observations on the devices that exhibit intrinsic bistable conductance switching with large on-off ratio.Comment: 6 pages, 3 figures. To appear in Applied Physics Letter

Transient Absorption and Raman Spectroscopies in Organic Electronics

Raman spectroscopy has proved to be a very valuable tool for characterization in a large number of research fields, both biological, chemical and material sciences.[1] In the last decades, organic electronics has broken out as a real alternative to conventional electronics, based on inorganic materials. However, in order to advance significantly in this field of research is paramount the full characterization of electronic devices, going from the individual molecule to the system as a whole. Moreover, the study of photophysical and photochemical processes crosses the interest of many fields of research in physics, chemistry and biology. Among the experimental approaches developed for this purpose, the advent of ultrafast transient absorption spectroscopy has become a powerful and widely used method.[2,3] This pump-probe technique is a popular means of studying photophysics, because of its versatile time resolution and its ease of comparison with ground-state absorption spectra. In this communication, I will present the basic principles of transient absorption spectroscopy, along with some examples where its combination with Raman spectroscopy allows the great characterization of organic molecules with potential applications in organic electronics.[4,5] References [1] H. Schulz, M. Baranska, R. Baranski. Biopolymers 2005, 77, 212 - 221. [2] U. Megerle, I. Pugliesi, C. Schriever, C.F. Sailer, E. Riedle. Appl. Phys. B, 2009, 96, 215 - 231. [3] R. Berera, R. van Grondelle, J.T.M. Kennis. Photosynth. Res. 2009, 101, 105 - 118. [4] E. Anaya-Plaza, M. Moreno Oliva, A. Kunzmann, C. Romero-Nieto, R.D. Costa, A. de la Escosura, D.M. Guldi, T. Torres. Adv. Funct. Mater. 2015, 25, 7418 - 7427. [5] F. Liu, G.L. Espejo, S. Qiu, M. Moreno Oliva, J. Pina, J.S. Seixas de Melo, J. Casado, X. Zhu. J. Am. Chem. Soc. 2015, 137, 10357 - 10366.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Donor-acceptor polymers for applications in organic electronics and photovoltaics

We have synthesized a new series of high-mobility polymeric semiconductors with good processability and excellent environmental stability for organic electronics and photovoltaics. Using these materials, solar cells were fabricated with power conversion efficiencies of up to 8.7% and remarkable fill factors of 76-80%.MINECO, Junta de Andalucí

Conjugated Polymers for Organic Electronics: Structural and Electronic Characteristics

The use of organic materials to design electronic devices has actually presented a broad interest for because they constitute an ecological and suitable resource for our current "electronic world". These materials provide several advantages (low cost, light weight, good flexibility and solubility to be easily printed) that cannot be afforded with silicium. They can also potentially interact with biological systems, something impossible with inorganic devices. Between these materials we can include small molecules, polymers, fullerenes, nanotubes, graphene, other carbon-based molecular structures and hybrid materials. Actually these materials are being used to build electronic structures into electronic devices, like organic light-emitting diodes (OLEDs), organic solar cells (OSCs), and organic field-effect transistors (OFETs), constituting and already commercial reality. Some of them are used on a widespread basis1, and are the focus of some recent researches in molecules2,3 and polymers4-6 suitable for these purposes. In this study we analyze the electronic and molecular characteristics of some different π-conjugated structures in order to evaluate their potential as semiconducting materials for organic electronics. For this purpose we focus on the study of conjugated polymers with different backbones configurations: (i) donor-acceptor configuration, (ii) 1D lineal or 2D branched conjugated backbones, and (iii) encapsulated polymers. To achieve this goal, we use a combined experimental and theoretical approach that includes electronic spectroscopies (i.e., absorption, emission and microsecond transient absorption), vibrational Raman spectroscopy and DFT calculations. These structural modifications are found to provoke a strong impact on the HOMO and LUMO levels and the molecular morphology, and, consequently, on their suitability as semiconductors in organic electronic applications.References 1. S. R. Forrest, M. E. Thompson. Chem. Rev., 2007, 107, 923 2. R. C. González-Cano, G. Saini, J. Jacob, J. T. López Navarrete, J. Casado and M. C. Ruiz Delgado. Chem. Eur. J. 2013, 19, 17165 3. J. L. Zafra, R. C. González-Cano, M. C. Ruiz Delgado, Z. Sun, Y. Li, J. T. López Navarrete, J. Wu and J. Casado. J. Chem. Phys. , 2014, 140, 054706 4. M. Goll, A. Ruff, E. Muks, F. Goerigk, B. Omiecienski, I. Ruff, R. C. González-Cano, J. T. López Navarrete, M. C. Ruiz Delgado, S. Ludwigs. Beilstein J. Org. Chem., 2015, 11, 335. 5. D. Herrero-Carvajal, A. de la Peña, R. C. González-Cano, C. Seoane, J. T. López Navarrete, J. L. Segura, J. Casado, M. C. Ruiz Delgado, J. Phys. Chem. C, 2014, 118, 9899. 6. M. Scheuble, Y. M. Gross, D. Trefz, M. Brinkmann, J. T. López Navarrete, M. C. Ruiz Delgado, and S. Ludwigs, Macromolecules, 2015, 48, 7049.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Organic electronics for biosensors

V úvodní části se pojednává o organických tenkovrstvých tranzistorech a jejich možném využití jako chemických a biologických senzorů. Střední část pojednává o elektrických vlastnostech zařízení OECT v přechodném ději a ustáleném stavu a potenciálním využití OECT zařízení pro sledování buněk. Závěrečná experimentální část se zabývá vlivem teploty, stárnutí, prostředí elektrolytu a geometrie na funkci OECT zařízení.In the first part are discussed the organic thin-film transistors and their possible use for chemical and biological sensors. Middle section discusses the electrical properties of OECT device in steady-state and transient behaviour and potential use of OECT for cell monitoring. The final experimental part deals with influence of temperature, aging, electrolyte environment and geometry on the function of OECT device.

Polyconjugation for Organic Electronics

Since the discovery of the semiconducting properties of π-conjugated organic oligomers and polymers, many efforts have been devoted to generating structural features that bring about new and outstanding properties for optoelectronics, spintronics and magnetic devices, non-linear optics, or singlet fission processes. In this sense, the play between the resonance and π-electron delocalization phenomena in π-conjugated organic materials is the origin of their semiconducting behavior. For this reason, establishing not only the electron delocalization mechanism and its extension, but also which factors disturb the π-electron density is of utmost importance to enhance the proper performance of the electronic devices and develop ad hoc synthesis for desired application.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech