Phenomenological Study of Decoherence in Solid-State Spin Qubits due to Nuclear Spin Diffusion

We present a study of the prospects for coherence preservation in solid-state spin qubits using dynamical decoupling protocols. Recent experiments have provided the first demonstrations of multipulse dynamical decoupling sequences in this qubit system, but quantitative analyses of potential coherence improvements have been hampered by a lack of concrete knowledge of the relevant noise processes. We present simulations of qubit coherence under the application of arbitrary dynamical decoupling pulse sequences based on an experimentally validated semiclassical model. This phenomenological approach bundles the details of underlying noise processes into a single experimentally relevant noise power spectral density. Our results show that the dominant features of experimental measurements in a two-electron singlet-triplet spin qubit can be replicated using a $1/\omega^{2}$ noise power spectrum associated with nuclear-spin-flips in the host material. Beginning with this validation we address the effects of nuclear programming, high-frequency nuclear-spin dynamics, and other high-frequency classical noise sources, with conjectures supported by physical arguments and microscopic calculations where relevant. Our results provide expected performance bounds and identify diagnostic metrics that can be measured experimentally in order to better elucidate the underlying nuclear spin dynamics.Comment: Updated References. Related articles at: http://www.physics.usyd.edu.au/~mbiercuk/Publications.htm

Speech coding at medium bit rates using analysis by synthesis techniques

Speech coding at medium bit rates using analysis by synthesis technique

Novel Pitch Detection Algorithm With Application to Speech Coding

This thesis introduces a novel method for accurate pitch detection and speech segmentation, named Multi-feature, Autocorrelation (ACR) and Wavelet Technique (MAWT). MAWT uses feature extraction, and ACR applied on Linear Predictive Coding (LPC) residuals, with a wavelet-based refinement step. MAWT opens the way for a unique approach to modeling: although speech is divided into segments, the success of voicing decisions is not crucial. Experiments demonstrate the superiority of MAWT in pitch period detection accuracy over existing methods, and illustrate its advantages for speech segmentation. These advantages are more pronounced for gain-varying and transitional speech, and under noisy conditions

Probing molecular dynamics at the nanoscale via an individual paramagnetic center

Understanding the dynamics of molecules adsorbed to surfaces or confined to small volumes is a matter of increasing scientific and technological importance. Here, we demonstrate a pulse protocol using individual paramagnetic nitrogen vacancy (NV) centers in diamond to observe the time evolution of 1H spins from organic molecules located a few nanometers from the diamond surface. The protocol records temporal correlations among the interacting 1H spins, and thus is sensitive to the local system dynamics via its impact on the nuclear spin relaxation and interaction with the NV. We are able to gather information on the nanoscale rotational and translational diffusion dynamics by carefully analyzing the time dependence of the NMR signal. Applying this technique to various liquid and solid samples, we find evidence that liquid samples form a semi-solid layer of 1.5 nm thickness on the surface of diamond, where translational diffusion is suppressed while rotational diffusion remains present. Extensions of the present technique could be adapted to highlight the chemical composition of molecules tethered to the diamond surface or to investigate thermally or chemically activated dynamical processes such as molecular folding

Sparsity in Linear Predictive Coding of Speech

nrpages: 197status: publishe

Interference estimation with applications to blind multiple-access communication over fading channels

Includes bibliographical references.We consider the detection of nonorthogonal multipulse signals on multiple-access fading channels. The generalized maximum-likelihood rule is employed to decode users whose complex fading gains are unknown. We develop geometrical interpretations for the resulting detectors and their corresponding asymptotic efficiencies. The generalized maximum-likelihood detection rule is then applied to find a matched subspace detector for the frequency-selective fading channel, under the assumption of a short coherence time (or long coherence time without the computational power to track the fading parameters). We propose blind implementations of these detectors for nonorthogonal multipulse signaling on both frequency-nonselective and frequency-selective multiple-access fading channels. These blind detectors extend the results of Wang and Poor to multipulse modulation and fast frequency selective fading. For comparison, the minimum mean-squared error decision rules for these channels are derived and blind implementations of their corresponding detectors are developed.This work was supported by the National Science Foundation under Contract ECS 9979400 and by the Office of Naval Research under Contracts N00014-89-J-1070 and N0014-00-1-0033

Frequency-warped autoregressive modeling and filtering

This thesis consists of an introduction and nine articles. The articles are related to the application of frequency-warping techniques to audio signal processing, and in particular, predictive coding of wideband audio signals. The introduction reviews the literature and summarizes the results of the articles. Frequency-warping, or simply warping techniques are based on a modification of a conventional signal processing system so that the inherent frequency representation in the system is changed. It is demonstrated that this may be done for basically all traditional signal processing algorithms. In audio applications it is beneficial to modify the system so that the new frequency representation is close to that of human hearing. One of the articles is a tutorial paper on the use of warping techniques in audio applications. Majority of the articles studies warped linear prediction, WLP, and its use in wideband audio coding. It is proposed that warped linear prediction would be particularly attractive method for low-delay wideband audio coding. Warping techniques are also applied to various modifications of classical linear predictive coding techniques. This was made possible partly by the introduction of a class of new implementation techniques for recursive filters in one of the articles. The proposed implementation algorithm for recursive filters having delay-free loops is a generic technique. This inspired to write an article which introduces a generalized warped linear predictive coding scheme. One example of the generalized approach is a linear predictive algorithm using almost logarithmic frequency representation.reviewe

Global and target analysis of time-resolved spectra

AbstractIn biological/bioenergetics research the response of a complex system to an externally applied perturbation is often studied. Spectroscopic measurements at multiple wavelengths are used to monitor the kinetics. These time-resolved spectra are considered as an example of multiway data. In this paper, the methodology for global and target analysis of time-resolved spectra is reviewed. To fully extract the information from the overwhelming amount of data, a model-based analysis is mandatory. This analysis is based upon assumptions regarding the measurement process and upon a physicochemical model for the complex system. This model is composed of building blocks representing scientific knowledge and assumptions. Building blocks are the instrument response function (IRF), the components of the system connected in a kinetic scheme, and anisotropy properties of the components. The combination of a model for the kinetics and for the spectra of the components results in a more powerful spectrotemporal model. The model parameters, like rate constants and spectra, can be estimated from the data, thus providing a concise description of the complex system dynamics. This spectrotemporal modeling approach is illustrated with an elaborate case study of the ultrafast dynamics of the photoactive yellow protein