DEVELOPMENT OF FUNCTIONAL NANOCOMPOSITE MATERIALS TOWARDS BIODEGRADABLE SOFT ROBOTICS AND FLEXIBLE ELECTRONICS

World population is continuously growing, as well as the influence we have on the ecosystem\u2019s natural equilibrium. Moreover, such growth is not homogeneous and it results in an overall increase of older people. Humanity\u2019s activity, growth and aging leads to many challenging issues to address: among them, there are the spread of suddenly and/or chronic diseases, malnutrition, resource pressure and environmental pollution. Research in the novel field of biodegradable soft robotics and electronics can help dealing with these issues. In fact, to face the aging of the population, it is necessary an improvement in rehabilitation technologies, physiological and continuous monitoring, as well as personalized care and therapy. Also in the agricultural sector, an accurate and efficient direct measure of the plants health conditions would be of help especially in the less-developed countries. But since living beings, such as humans and plants, are constituted by soft tissues that continuously change their size and shapes, today\u2019s traditional technologies, based on rigid materials, may not be able to provide an efficient interaction necessary to satisfy these needs: the mechanical mismatch is too prohibitive. Instead, soft robotic systems and devices can be designed to combine active functionalities with soft mechanical properties that can allow them to efficiently and safely interact with soft living tissues. Soft implantable biomedical devices, smart rehabilitation devices and compliant sensors for plants are all applications that can be achieved with soft technologies. The development of sophisticated autonomous soft systems needs the integration on a unique soft body or platform of many functionalities (such as mechanical actuation, energy harvesting, storage and delivery, sensing capabilities). A great research interest is recently arising on this topic, but yet not so many groups are focusing their efforts in the use of natural-derived and biodegradable raw materials. In fact, resource pressure and environmental pollution are becoming more and more critical problems. It should be completely avoided the use of in exhaustion, pollutant, toxic and non-degradable resources, such as lithium, petroleum derivatives, halogenated compounds and organic solvents. So-obtained biodegradable soft systems and devices could then be manufactured in high number and deployed in the environment to fulfil their duties without the need to recover them, since they can safely degrade in the environment. The aim of the current Ph.D. project is the use of natural-derived and biodegradable polymers and substances as building blocks for the development of smart composite materials that could operate as functional elements in a soft robotic system or device. Soft mechanical properties and electronic/ionic conductive properties are here combined together within smart nanocomposite materials. The use of supersonic cluster beam deposition (SCBD) technique enabled the fabrication of cluster-assembled Au electrodes that can partially penetrate into the surface of soft materials, providing an efficient solution to the challenge of coupling conductive metallic layers and soft deformable polymeric substrates. In this work, cellulose derivatives and poly(3-hydroxybutyrate) bioplastic are used as building blocks for the development of both underwater and in-air soft electromechanical actuators that are characterized and tested. A cellulosic matrix is blended with natural-derived ionic liquids to design and manufacture completely biodegradable supercapacitors, extremely interesting energy storage devices. Lastly, ultrathin Au electrodes are here deposited on biodegradable cellulose acetate sheets, in order to develop transparent flexible electronics as well as bidirectional resistive-type strain sensors. The results obtained in this work can be regarded as a preliminary study towards the realization of full natural-derived and biodegradable soft robotic and electronic systems and devices

Micro/Nano Structures and Systems

Micro/Nano Structures and Systems: Analysis, Design, Manufacturing, and Reliability is a comprehensive guide that explores the various aspects of micro- and nanostructures and systems. From analysis and design to manufacturing and reliability, this reprint provides a thorough understanding of the latest methods and techniques used in the field. With an emphasis on modern computational and analytical methods and their integration with experimental techniques, this reprint is an invaluable resource for researchers and engineers working in the field of micro- and nanosystems, including micromachines, additive manufacturing at the microscale, micro/nano-electromechanical systems, and more. Written by leading experts in the field, this reprint offers a complete understanding of the physical and mechanical behavior of micro- and nanostructures, making it an essential reference for professionals in this field

SUSTAINABLE ENERGY HARVESTING TECHNOLOGIES – PAST, PRESENT AND FUTURE

Chapter 8: Energy Harvesting Technologies: Thick-Film Piezoelectric Microgenerato

Electromechanical Performance of HASEL Actuators: Fundamentals and Applications

Soft robotic systems are well-suited to unstructured, dynamic tasks and environments, but are currently limited by the soft actuators that power them. Most current soft actuators are based on pneumatics or shape-memory alloys, which have issues with efficiency, response speed, and portability. More recently, dielectric elastomer actuators (DEAs) have shown promise, but they have limited material selection, fabrication methods, and modes of actuation. As such, there remains a need for new types of high performance and well-rounded soft actuators. This dissertation focuses on the development and exploration of a new class of soft electrohydraulic actuators called hydraulically amplified self-healing electrostatic (HASEL) actuators. The first part of this dissertation (Chapter 2) presents of a subclass of HASEL actuators called Peano-HASELs that simultaneously introduce a breakthrough materials system based on thermoplastic films as well as a novel contractile mode of actuation. This approach enables industrially-amenable fabrication techniques, vastly expands the usable materials for actuator construction, and results in high performance actuators with fast linear contraction on activation. The second part of this dissertation (Chapter 3) elucidates the fundamentals of the electromechanical coupling that drives HASEL actuators. An analytical model is developed that accurately describes the quasi-static actuation behavior of Peano-HASEL actuators without relying on fitting parameters. Using this model, we identify a theory-driven approach to actuator design, including a roadmap for actuators with drastically improved specific energies. The final section of this dissertation (Chapter 4 and 5) looks towards more integrated and applied designs of HASEL actuators. First, a new type of articulating actuator is presented that integrates both compliant and rigid components. These spider-inspired electrohydraulic soft-actuated (SES) joints demonstrate high torque and high-speed actuation in an independently-addressable multi-joint limb, a bidirectional actuator, and a versatile gripper. Second, a biodegradable materials system is presented for high performance Peano-HASEL actuators that reduce environmental impact. Finally, a new method of capacitive self-sensing is presented that enables inexpensive and compact circuits that use only off-the-shelf and low voltage components. The results presented in this dissertation provide a framework for the development of high-performance actuators that may one day power the next generation of capable soft robots.</p

Research and technology operating plan summary: Fiscal year 1975 research and technology program

Summaries are presented of Research and Technology Operating Plans currently in progress throughout NASA. Citations and abstracts of the operating plans are presented along with a subject index, technical monitor index, and responsible NASA organization index. Research programs presented include those carried out in the Office of Aeronautics and Space Technology, Office of Energy Programs, Office of Applications, Office of Space Sciences, Office of Tracking and Data Acquisition, and the Office of Manned Space Flight