In-situ monitoring of photocatalytic reactions in optofluidic microreactors

To advance the state-of-the-art technology in photocatalysis, there is a growing need to develop optically efficient microreactors that allow rapid changes in reaction conditions for catalyst screening. In addition, such microreactors should offer strong light-matter interactions for the in-situ spectroscopic detection of chemical species. Motivated by these challenges, this thesis marries the fields of fibre-based optofluidics and photocatalysis to generate scientific insights into how promising new photocatalysts behave. Novel types of optical fibre were optimised and characterised for liquid phase spectroscopy on sub-microlitre samples; these fibres included kagomé-style and single-ring hollow-core photonic crystal fibres (HC-PCFs). New kinetic insights were obtained into the photoactivity of carbon nanodots (CDs) through systematic screening of a wide range of reaction conditions within kagomé-style HC-PCF microreactors. Spectrokinetic insights across twenty-nine reaction conditions were studied with a cumulative sample volume of < 1.5 mL, using viologen species as indicators of electron transfer from CDs. First, amorphous and graphitic CDs were benchmarked against the well-known photocatalyst [Ru(bpy)3]2+. This study was then extended to replace the viologen indicator with hydrogen-evolving cobaloxime electrocatalysts, to probe catalytic intermediate states. To give further insight into the electron transfer from carbon nanodots to viologens, transient absorption spectroscopy was then performed to probe changes on timescales of 1 nanosecond to 1 millisecond. Finally, a new ultralow volume fibre-based fluorescence spectroscopy method was realised. As a proof of principle, the photoredox catalyst 4CzIPN was combined with the fluorescence quenchers tetrabutylammonium azide and cyclohexylamine. The extracted bimolecular Stern-Volmer quenching coefficients were compared with conventional fluorimeter-based approaches, which were taken on much larger sample volumes. This thesis provides a foundation for developing continuous-flow photocatalytic screening systems based on HC-PCFs, which minimise the consumption of precious reagents

Hybrid photonic-crystal fiber

This article offers an extensive survey of results obtained using hybrid photonic-crystal fibers (PCFs) which constitute one of the most active research fields in contemporary fiber optics. The ability to integrate novel and functional materials in solid-and hollow-core PCFs through various postprocessing methods has enabled new directions toward understanding fundamental linear and nonlinear phenomena as well as novel application aspects, within the fields of optoelectronics, material and laser science, remote sensing, and spectroscopy. Here the recent progress in the field of hybrid PCFs is reviewed from scientific and technological perspectives, focusing on how different fluids, solids, and gases can significantly extend the functionality of PCFs. The first part of this review discusses the efforts to develop tunable linear and nonlinear fiber-optic devices using PCFs infiltrated with various liquids, glasses, semiconductors, and metals. The second part concentrates on recent and state-of-the-art advances in the field of gas-filled hollow-core PCFs. Extreme ultrafast gas-based nonlinear optics toward light generation in the extreme wavelength regions of vacuum ultraviolet, pulse propagation, and compression dynamics in both atomic and molecular gases, and novel soliton-plasma interactions are reviewed. A discussion of future prospects and directions is also included

Investigation into Smart Multifunctional Optical System-On-A-Chip Sensor Platform and Its Applications in Optical Wireless Sensor Networks

Wireless sensor networks (WSNs) have been widely used in various applications to acquire distributed information through cooperative efforts of sensor nodes. Most of the sensor nodes used in WSNs are based on mechanical or electrical sensing mechanisms, which are susceptible to electromagnetic interference (EMI) and can hardly be used in harsh environments. Although these disadvantages of conventional sensor nodes can be overcome by employing optical sensing methods, traditional optical systems are usually bulky and expensive, which can hardly be implemented in WSNs. Recently, the emerging technologies of silicon photonics and photonic crystal promise a solution of integrating a complete optical system through a complementary metal-oxide-semiconductor (CMOS) process. However, such an integration still remains a challenge. The overall objective of this dissertation work is to develop a smart multifunctional optical system-on-a-chip (SOC) sensor platform capable of both phase modulation and wavelength tuningfor heterogeneous sensing, and implement this platform in a sensor node to achieve an optical WSN for various applications, including those in harsh environments. The contributions of this dissertation work are summarized as follows. i)A smart multifunctional optical SOC sensor platform for heterogeneous sensing has beendeveloped for the first time. This platform can be used to perform phase modulation and demodulation in a low coherence interferometric configuration or wavelength tuning in a spectrum sensing configuration.The multifunctional optical sensor platform is developed through hybrid integration of a light source, an optical modulator, and multiple photodetectors. As the key component of the SOC platform, two types of modulators, namely, the opto-mechanical and electro-optical modulators, are investigated. For the first time, interrogating different types of heterogeneous sensors, including various Fabry-Perot (FP) sensors and fiber Bragg grating (FBG) sensors, with a single SOC sensor platform, is demonstrated. ii)Enhanced understanding of the principles of the multifunctional optical platform withanopto-mechanical modulator has been achieved.As a representative of opto-mechanical modulators, a microelectromechanical systems (MEMS) based FP tunable filter is thoroughly investigated through mechanical and optical modeling. The FP tunable filter is studied for both phase modulation and wavelength tuning, and design guidelines are developed based on the modeling and parametric studies. It is found that the MEMS tunable filter can achieve a large modulation depth, but it suffers from a trade-off between modulation depth and speed. iii) A novel silicon electro-optical modulator based on microring structures for optical phase modulation and wavelength tuning has been designed. To overcome the limitations of the opto-mechanical modulators including low modulation speed and mechanical instability, a CMOS compatible high speed electro-optical silicon modulator is designed, which combines microring and photonic crystal structures for phase modulation in interferometric sensors and makes use of two cascaded microrings for wavelength tuning in sensors that require spectrum domain signal processing. iv)A novel optical SOC WSN node has been developed. The optical SOC sensor platform and the associated electric circuit are integrated with a conventional WSN module to achieve an optical WSN node, enabling optical WSNs for various applications. v) A novel cross-axial dual-cavity FP sensor has been developed for simultaneous pressure and temperature sensing.Across-axial sensor is useful in measuring static pressures without picking up dynamic pressures in the presence of surface flows. The dual-cavity sensing structure is used for both temperature and pressure measurements without the need for another temperature sensor for temperature drift compensation. This sensor can be used in moderate to high temperature environments, which demonstrates the potential of using the optical WSN sensor node in a harsh environment

Smart Textiles Production

The research field of smart textiles is currently witnessing a rapidly growing number of applications integrating intelligent functions in textile substrates. With an increasing amount of new developed product prototypes, the number of materials used and that of specially designed production technologies are also growing. This book is intended to provide an overview of materials, production technologies, and product concepts to different groups concerned with smart textiles. It will help designers to understand the possibilities of smart textile production, so that they are enabled to design this type of products. It will also help textile and electronics manufacturers to understand which production technologies are suitable to meet certain product requirements