Fabrication and characterization of smart fabric using energy storage fibres

Fibre supercapacitors were designed and manufactured using a dip-coating method. Their electrochemical properties were characterized using a VersaSTAT 3 workstation. Chinese ink with a fine dispersion of carbon and binder was coated as the electrode material. The specific capacitance per unit length of a copper fibre supercapacitor with the length of 41 cm reached 34.5 mF/cm. When this fibre supercapacitor was bent on rods with a diameter of 10.5 cm, the specific capacitance per length was 93% of the original value (without bending). It showed that these fibre supercapacitors have good flexibility and energy storage capacity. Furthermore, the fibre supercapacitor in the fabric showed the same capacitance before and after weaving.The European Union Seventh Framework Programme (FP7/2007–2013) under grant agreement no. [281063]

Multifunctional Structural Supercapacitor Composites Based on Carbon Aerogel Modified High Performance Carbon Fiber Fabric

It is well documented that bedrest has adverse outcomes for hospitalized patients. This is especially true for critically ill patients due to life support measures, invasive catheters, and mechanical ventilation. Consequences associated with bedrest in critical care patients include venous thromboembolism, ventilator associated pneumonia, pressure ulcer development, and muscle weakness. Respiratory muscle weakness is associated with prolonged ventilator support and delayed extubation. The Awakening and Breathing Coordination, Delirium Monitoring and Management, and Early Mobility (ABCDE) bundle uses evidence based practice to prevent and treat ICU acquired delirium and weakness. The bundle aims to do this by standardizing care processes in collaboration with the ICU team to promote early mobility in ventilated patients. The purpose of this research study was to determine if the implementation of an early mobility protocol decreased the number of ventilator days for patients who receive mechanical ventilation. A retrospective chart review was conducted at a 16 bed ICU. Group A included 30 subjects (n=30) who were treated pre implementation of the ABCDE bundle and Group B included 39 (n=39) subjects who were treated post implementation of the ABCDE bundle. There were less average ventilator days found in Group A in comparison to Group B. Additionally, there was a significant difference found in the ICU length of stay pre implementation (M=9.4, SD=4.4) and post implementation (M=5.7, SD=2.6) of the ABCDE bundle for early mobility, t (65) =4.3, p = 0.00005. The APRN can use the evidence in the ABCDE bundle to guide care to critically ill patients that are mechanically ventilated. Utilizing the ABCDE bundle additionally allows the APRN to be instrumental in improving patient outcomes through interdisciplinary collaboration

Cellulosic materials as biopolymers and supercritical CO2as a green process: chemistry and applications

In this review, we describe the use of supercritical CO2 (scCO2) in several cellulose applications. The focus is on different technologies that either exist or are expected to emerge in the near future. The applications are wide from the extraction of hazardous wastes to the cleaning and reuse of paper or production of glucose. To put this topic in context, cellulose chemistry and its interactions with scCO2 are described. The aim of this study was to discuss the new emerging technologies and trends concerning cellulosic materials processed in scCO2 such as cellulose drying to obtain aerogels, foams and other microporous materials, impregnation of cellulose, extraction of highly valuable compounds from plants and metallic residues from treated wood. Especially, in the bio-fuel production field, we address the pre-treatment of cellulose in scCO2 to improve fermentation to ethanol by cellulase enzymes. Other reactions of cellulosic materials such as organic inorganic composites fabrication and de-polymerisation have been considered. Cellulose treatment by scCO2 has been discussed as well. Finally, other applications like deacidification of paper and cellulosic membranes fabrication in scCO2 have been reviewed. Examples of the discussed technologies are included as well

Polyaniline membranes for use in organic solvent nanofiltration

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Nanocellulose as building block for novel materials

This thesis describes the fabrication of novel green materials using nanocellulose as the building block. Bacterial cellulose (BC) was used as the nanocellulose predominantly in this work. BC is highly crystalline pure cellulose with an inherent fibre diameter in the nano-scale. A single BC nanofibre was found to possess a Young’s modulus of 114 GPa. All these properties are highly favourable for using BC as a nanofiller/reinforcement in green nanocomposite materials. In this work, the surface of BC was rendered hydrophobic by grafting organic acids with various aliphatic chain lengths. These surface-modified BC was used as nanofiller for poly(L-lactide) (PLLA). Direct wetting measurements showed that the BC nanofibre-PLLA interface was improved due to the hydrophobisation of BC with organic acids. This led to the production of BC reinforced PLLA nanocomposites with improved tensile properties. Nanocellulose can also be obtained by grinding of wood pulp, producing nanofibrillated cellulose (NFC). The surface and bulk properties of one type of NFC and BC were compared in this work. Furthermore, the reinforcing ability of NFC and BC was also studied and it was observed that there is no significant difference in the mechanical performance of NFC or BC reinforced nanocomposites. A novel method based on slurry dipping to coat sisal fibres with BC was developed to modify the surface of natural fibres. This method can produce either (i) a densely BC coating layer or (ii) “hairy” BC coated sisal fibres. Randomly oriented short BC coated sisal fibre reinforced hierarchical composites were manufactured. It was found that hierarchical (nano)composites containing BC coated sisal fibres and BC dispersed in the matrix were required to produce composites with improved mechanical properties. This slurry dipping method was also extended to produce robust short sisal fibre preforms. By infusing this preform with a bio-based thermosetting resin followed by curing, green composites with significantly improved mechanical properties were produced. BC was also used as stabiliser and nano-filler for the production of macroporous polymers made by frothing of acrylated epoxidised soybean oil followed by microwave curing

Growth of Carbon Nanotubes on Electrospun Cellulose Fibres for High Performance Supercapacitors and Carbon Fibre Composites

The production of cellulose derived hybrid carbon nanofibre (CNF)/carbon nanotubes (CNTs) electrodes for the fabrication of supercapacitors and carbon fibre composites was investigated. The CNTs were grown via a floating catalyst chemical vapor deposition (CVD) method on the top surface of electrospun cellulose derived CNFs. These CNF and CNF/CNTs samples were then used as electrodes to produce liquid electrolyte-based supercapacitors. The growth of CNTs leads to an improvement of electrochemical performance compared to the plain CNFs. This improvement is due to the grown CNTs enlarging the reactive sites through enhanced surface area and porosity, and thereby increasing the conductivity of the system. CNTs have been also grown onto CNFs containing ferrocene and SiC particles. Composites were fabricated by combining the fibres and CNTs grown fibres with model polymers. The stress transfer properties of these materials have been estimated using an in situ Raman spectroscopic method by observing the shift of the Raman band during the tensile deformation of model polymer composites. Using this method, the elastic modulus of CNF/SiC/CNTs fibres has been estimated to be 208 ± 26 GPa. No shifts in the peak positions of bands relating to the carbon structure were obtained for in situ Raman spectroscopic studies of the CNF/CNTs fibres made from the ferrocene embedded fibres. This was thought to be due to the low yield of CNTs on the surface of the fibres. Furthermore, CNF/CNTs electrode-based structural supercapacitors, combining a solid electrolyte with the carbonized fibres, have been produced. These CNF/CNTs electrodes have a better capacitive performance than the plain CNF electrodes. There was a decrease in this performance with increased curing time of the resin, from 2 to 24 h, due to a lack of charge carrier mobility in the latter samples. A Raman spectroscopic study of the deformation of the carbon structures showed that the G-band shift towards a lower wavenumber position for the CNF and CNF/CNTs samples processed at a carbonization temperature of 2000 °C. Moduli of these fibres were estimated to be ~145 GPa and ~271 GPa, respectively, suggesting the growth of CNTs not only enhances the capacitive performance but also the mechanical properties of the structural supercapacitors. No Raman bend shift was found for the CNFs and CNF/CNTs samples processed below a carbonization temperature of 2000 °C, e.g. 900 °C and 1500 °C. This is because the graphitic structures are not well developed at carbonization temperatures below 1500 °C