On the modelling of highly elastic flows of amorphous thermoplastics

Two approaches to the kinematic structuring of constitutive models for highly elastic flows of polymer melts have been examined systematically, assuming either: (1) additivity of elastic and viscous velocity gradients or (2) multiplicability of elastic and viscous deformation gradients. A series of constitutive models were compared, with differing kinematic structure but the same linear responses in elastic and viscous limits. They were solved numerically and their predictions compared, and they were also compared to those of the Giesekus model. Several variants, previously proposed as separate models, are shown to be equivalent and qualitatively in agreement with experiment, and therefore a sound basis for construction of models. But the assignment of viscous spin is critical: if it is assumed equal to the total spin with approach (1), or equal to zero with approach (2), then unphysical viscoelastic behaviour is predicted. © 2008 Elsevier Ltd. All rights reserved

Wall Adhesion and Constitutive Modelling of Strong Colloidal Gels

Wall adhesion effects during batch sedimentation of strongly flocculated colloidal gels are commonly assumed to be negligible. In this study in-situ measurements of colloidal gel rheology and solids volume fraction distribution suggest the contrary, where significant wall adhesion effects are observed in a 110mm diameter settling column. We develop and validate a mathematical model for the equilibrium stress state in the presence of wall adhesion under both viscoplastic and viscoelastic constitutive models. These formulations highlight fundamental issues regarding the constitutive modeling of colloidal gels, specifically the relative utility and validity of viscoplastic and viscoelastic rheological models under arbitrary tensorial loadings. The developed model is validated against experimental data, which points toward a novel method to estimate the shear and compressive yield strength of strongly flocculated colloidal gels from a series of equilibrium solids volume fraction profiles over various column widths.Comment: 37 pages, 12 figures, submitted to Journal of Rheolog

Pattern Formation and Elastocapillary Instabilities in Soft Gels

Hydrogels are complex materials that are typically utilized as bioinks in the emerging 3D bioprinting technology. Gels are distinguished by an elasticity that introduces complexity into the pinch-off process. The distinguishing feature of soft gels is that capillarity (surface tension) and elasticity are comparable which can induce an abundance of new phenomena in the elastocapillary regime. Unfortunately, elastocapillary instabilities are not fully understood because classical theories of fluid mechanics and solid mechanics can not capture the crossover between capillary-dominated and elasticity-dominated dynamics. Herein, elastocapillary surface phenomena on hydrogels are experimentally characterized and new theoretical models are proposed to interpret the discrepancies between classical theories and new experimental observations. Many first observations of dynamic elastocapillary phenomena are reported including the experimental observations of i) gel drop oscillations in ultrasonic levitation and ii) Faraday waves on mechanically-vibrated gels. The mechanism of pattern formation is investigated and the role of elasticity is revealed. By relating theory to experiment, a new diagnostic technique to measure the surface tension and rheology of soft gels is developed, which can directly support many emerging 3D bioprinting technologies

Frame Indifferent Formulation of Maxwell's Elastic Fluid and the Rational Continuum Mechanics of the Electromagnetic Field

We show that the linearized equations of the incompressible elastic medium admit a `Maxwell form' in which the shear component of the stress vector plays the role of the electric field, and the vorticity plays the role of the magnetic field. Conversely, the set of dynamic Maxwell equations are strict mathematical corollaries from the governing equations of the incompressible elastic medium. This suggests that the nature of `electromagnetic field' may actually be related to an elastic continuous medium. The analogy is complete if the medium is assumed to behave as fluid in shear motions, while it may still behave as elastic solid under compressional motions. Then the governing equations of the elastic fluid are re-derived in the Eulerian frame by replacing the partial time derivatives by the properly invariant (frame indifferent) time rates. The `Maxwell from' of the frame indifferent formulation gives the frame indifferent system that is to replace the Maxwell system. This new system comprises terms already present in the classical Maxwell equations, alongside terms that are the progenitors of the Biot--Savart, Oersted--Ampere's, and Lorentz--force laws. Thus a frame indifferent (truly covariant) formulation of electromagnetism is achieved from a single postulate that the electromagnetic field is a kind of elastic (partly liquid partly solid) continuum.Comment: accepte

Influence of supramolecular forces on the linear viscoelasticity of gluten

Stress relaxation behavior of hydrated gluten networks was investigated by means of rheometry combined with μ-computed tomography (μ-CT) imaging. Stress relaxation behavior was followed over a wide temperature range (0–70 °C). Modulation of intermolecular bonds was achieved with urea or ascorbic acid in an effort to elucidate the presiding intermolecular interactions over gluten network relaxation. Master curves of viscoelasticity were constructed, and relaxation spectra were computed revealing three relaxation regimes for all samples. Relaxation commences with a well-defined short-time regime where Rouse-like modes dominate, followed by a power law region displaying continuous relaxation concluding in a terminal zone. In the latter zone, poroelastic relaxation due to water migration in the nanoporous structure of the network also contributes to the stress relief in the material. Hydrogen bonding between adjacent protein chains was identified as the determinant force that influences the relaxation of the networks. Changes in intermolecular interactions also resulted in changes in microstructure of the material that was also linked to the relaxation behavior of the networks

Polymeric jets throw light on the origin and nature of the forest of solar spicules

Spicules are plasma jets, observed in the dynamic interface region between the visible solar surface and the hot corona. At any given time, it is estimated that about 3 million spicules are present on the Sun. We find an intriguing parallel between the simulated spicular forest in a solar-like atmosphere and the numerous jets of polymeric fluids when both are subjected to harmonic forcing. In a radiative magnetohydrodynamic numerical simulation with sub-surface convection, solar global surface oscillations are excited similarly to those harmonic vibrations. The jets thus produced match remarkably well with the forests of spicules detected in observations of the Sun. Taken together, the numerical simulations of the Sun and the laboratory fluid dynamics experiments provide insights into the mechanism underlying the ubiquity of jets: the nonlinear focusing of quasi-periodic waves in anisotropic media of magnetized plasma as well as polymeric fluids under gravity is sufficient to generate a forest of spicules on the Sun.Comment: Published in Nature Physics. Video files are available at https://rdcu.be/cZdl

Shear-induced transitions and instabilities in surfactant wormlike micelles

In this review, we report recent developments on the shear-induced transitions and instabilities found in surfactant wormlike micelles. The survey focuses on the non-linear shear rheology and covers a broad range of surfactant concentrations, from the dilute to the liquid-crystalline states and including the semi-dilute and concentrated regimes. Based on a systematic analysis of many surfactant systems, the present approach aims to identify the essential features of the transitions. It is suggested that these features define classes of behaviors. The review describes three types of transitions and/or instabilities : the shear-thickening found in the dilute regime, the shear-banding which is linked in some systems to the isotropic-to-nematic transition, and the flow-aligning and tumbling instabilities characteristic of nematic structures. In these three classes of behaviors, the shear-induced transitions are the result of a coupling between the internal structure of the fluid and the flow, resulting in a new mesoscopic organization under shear. This survey finally highlights the potential use of wormlike micelles as model systems for complex fluids and for applications.Comment: 64 pages, 31 figures, 2 table