Modelling of a post-combustion CO₂ capture process using neural networks

This paper presents a study of modelling post-combustion CO₂ capture process using bootstrap aggregated neural networks. The neural network models predict CO₂ capture rate and CO₂ capture level using the following variables as model inputs: inlet flue gas flow rate, CO₂ concentration in inlet flue gas, pressure of flue gas, temperature of flue gas, lean solvent flow rate, MEA concentration and temperature of lean solvent. In order to enhance model accuracy and reliability, multiple feedforward neural network models are developed from bootstrap re-sampling replications of the original training data and are combined. Bootstrap aggregated model can offer more accurate predictions than a single neural network, as well as provide model prediction confidence bounds. Simulated CO₂ capture process operation data from gPROMS simulation are used to build and verify neural network models. Both neural network static and dynamic models are developed and they offer accurate predictions on unseen validation data. The developed neural network models can then be used in the optimisation of the CO₂ capture process

Hybrid Electronic Tongue based on Multisensor Data Fusion for Discrimination of Beers

This paper reports the use of a hybrid Electronic Tongue based on data fusion of two different sensor families, applied in the recognition of beer types. Six modifiedgraphite- epoxy voltammetric sensors plus 15 potentiometric sensors formed the sensor array. The different samples were analyzed using cyclic voltammetry and direct potentiometry without any sample pretreatment in both cases. The sensor array coupled with feature extraction and pattern recognition methods, namely Principal Component Analysis (PCA) and Linear Discriminant Analysis (LDA), was trained to classify the data clusters related to different beer varieties. PCA was used to visualize the different categories of taste profiles and LDA with leave-one-out cross-validation approach permitted the qualitative classification. The aim of this work is to improve performance of existing electronic tongue systems by exploiting the new approach of data fusion of different sensor types

Convolutional Neural Network on Three Orthogonal Planes for Dynamic Texture Classification

Dynamic Textures (DTs) are sequences of images of moving scenes that exhibit certain stationarity properties in time such as smoke, vegetation and fire. The analysis of DT is important for recognition, segmentation, synthesis or retrieval for a range of applications including surveillance, medical imaging and remote sensing. Deep learning methods have shown impressive results and are now the new state of the art for a wide range of computer vision tasks including image and video recognition and segmentation. In particular, Convolutional Neural Networks (CNNs) have recently proven to be well suited for texture analysis with a design similar to a filter bank approach. In this paper, we develop a new approach to DT analysis based on a CNN method applied on three orthogonal planes x y , xt and y t . We train CNNs on spatial frames and temporal slices extracted from the DT sequences and combine their outputs to obtain a competitive DT classifier. Our results on a wide range of commonly used DT classification benchmark datasets prove the robustness of our approach. Significant improvement of the state of the art is shown on the larger datasets.Comment: 19 pages, 10 figure

Modelling and optimisation of post-combustion carbon capture process integrated with coal-fired power plant using computational intelligence techniques

PhD ThesisCoal-fired power plants are the major source of CO2 emission which contributes significantly to global climate change. An effective way to reduce CO2 emission in coal-fired power plants is post-combustion carbon dioxide (CO2) capture (PCC) with chemical absorption. The aim of this project is to carry out some research in model development, process analysis, controller design and process optimization for reliable, optimal design and control of coal-fired supercritical power plant integrated with post-combustion carbon capture plant. In this thesis, three different advanced neural network models are developed: bootstrap aggregated neural networks (BANNs) model, bootstrap aggregated extreme learning machine (BAELM) model and deep belief networks (DBN) model. The bootstrap aggregated model can offer more accurate predictions than a single neural network, as well as provide model prediction confidence bounds. However, both BANNs and BAELM have a shallow architecture, which is limited to represent complex, highly-varying relationship and easy to converge to local optima. To resolve the problem, the DBN model is proposed. The unsupervised training procedure is helpful to get the optimal solution of supervised training. The purpose of developing neural network models is to find a best model which can be used in the optimization of the CO2 capture process precisely. This thesis also presents a comparison of centralized and decentralized control structures for post-combustion CO2 capture plant with chemical absorption. As for centralized configuration, a dynamic multivariate model predictive control (MPC) technique is used to control the post-combustion CO2 capture plant attached to a coal-fired power plant. When consider the decentralized control structures based on multi-loop proportional-integral-derivative (PID) controllers, two different control schemes are designed using relative disturbance gain (RDG) analysis and dynamic relative gain array (DRGA) analysis, respectively. By comparing the two control structures, the MPC structure performs better in terms of closed-loop settling time, integral squared error, and disturbance injection

Data-driven modelling and monitoring of industrial processes with applications in nuclear waste vitrification

PhD ThesisProcess models are critical for process monitoring, control, and optimisation. With the increasing amount of process data and advancements in computational hardware, data-driven models are a good alternative to mechanistic models, which often have inaccuracies or are too costly to develop. One problem with data-driven models is the difficulty in ensuring that the models perform well on new data and produce accurate predictions in complex situations, which are frequently encountered in the process industry. Within this context, part of this thesis explores developing better data-driven models through using a latent variable technique, known as slow feature analysis, as a pre-processing step to regression. Slow feature analysis extracts slow varying features that contain underlying trends in the data, which can improve model performance through providing more meaningful information to regression, reducing noise, and reducing dimensionality. Firstly, the effectiveness of combining linear slow feature analysis with a neural network is demonstrated on two industrial case studies of soft sensor development and is compared with conventional techniques, such as neural networks and integration of principal component analysis with a neural network. It is shown that integration of slow feature analysis with neural networks can significantly improve model performance. However, linear slow feature analysis can fail to extract the driving forces behind data in nonlinear situations such as batch processes. Therefore, using kernel slow feature analysis with a neural network is proposed to further enhance process model performance. A numerical example was used to demonstrate the effective extraction of driving forces in a nonlinear case where linear slow feature analysis cannot. Model generalisation performance was improved using the proposed method on both this numerical example, and an industrial penicillin process case study. Dealing with radioactive nuclear waste is an important obstacle in nuclear energy. Sellafield Ltd have a nuclear waste vitrification plant which converts high-level nuclear waste into a more stable, lower volume glass form, which is more appropriate for long term storage in sealed containers. This thesis presents three applications of data-driven modelling to this nuclear waste vitrification process. A predictive model of the pour rate of processed nuclear waste into containers, an early detection system for blockages in the dust scrubber, and a model of the long-term chemical durability of the stored glass waste. These applications use the previously developed slow feature analysis methods, as well as other data-driven techniques such as extreme learning machine and bootstrap aggregation, for enhancing the model performance.Engineering and Physical Sciences Research Council (EPSRC) and Sellafield Lt

Modelling of Fine Chemical Manufacturing Effluent and Emissions: Implementation of Mathematical and Physical Models for Wastewater Management

Eng. D. Thesis.This thesis consists of a portfolio of four projects that investigates, and addresses challenges faced by fine chemical and pharmaceutical manufacturers based in the UK to achieve greater control of effluent and air emissions in an environment of tightening legislation. In part one of this research, a mathematical model based on modified continually stirred tank reactor (CSTR) in series equations was created using MATLAB and deployed as a standalone tool with graphical user interface (GUI) to allow non-experts to predict the concentration of substances through a complex plant effluent system and activated sludge wastewater treatment plant (WWTP). The model showed an average prediction accuracy to within 9% of the true value on-site when validated against a tracer compound. In Part two of the thesis, a 100 litre small-scale activated sludge wastewater treatment plant was designed and built to enable extended testing of treatment efficiency for potential new wastewater streams for a large-scale (2400 m3 reactor) plant, to reduce the risk of breaching site effluent consent limits or large scale microorganism poisoning. Plant variables and conditions required to maintain equivalent wastewater treatment performance from the large-scale to the small-scale plant were researched and found to include temperature, pH, dissolved oxygen (DO) concentration, hydraulic retention time (HRT) and solids retention time (SRT). The resulting pilot plant matched performance of the large-scale plant to within 12.8% of effluent chemical oxygen demand (COD) concentration. Long term treatment efficiency testing of a methylene-blue dye containing wastewater was conducted and shown to be satisfactory after a period of microorganism acclimation, where equivalent short-term lab respirometry testing had previously shown no digestion of the blue wastewater. In part three of this thesis, mathematical models were researched and developed in MATLAB to study prediction of the effluent chemical oxygen demand concentration of an activated sludge wastewater treatment plant. Existing methods of non-linear modelling using partial least squares (PLS) and artificial neural network (ANN) structures were investigated and compared against a newly proposed structure that replaces the linear inner regressor of the PLS algorithm with a combination of multiple neural networks (mNNPLS). The mNNPLS model showed an improved correlation coefficient (R2) of 0.855 between observed variables and predicted effluent chemical oxygen demand. In the final section of the thesis, a methodology was created for conducting consequence and risk modelling using DNV’s PHAST software to compliment the studies in parts one and two by allowing estimation of substance input concentrations to the effluent system from potential major accidents to aid emergency response planning and test the robustness of the effluent system. Sources for input data including individual and societal risk criteria are researched and presented along with techniques of scenario identification, results presentation and overall report format