SINTESIS GARAM TIMAH KLORIDA (SnCl2) BERBAHAN DASAR LIMBAH ELEKTRONIK

Timah (Sn) merupakan mineral logam yang mempunyai nilai ekonomis tinggi yang dapat dimanfaatkan sebagai bahan baku dalam proses kimia. Limbah elektronik Cathode Ray Tubes (CRTs) tabung TV berwarna mempunyai kandungan timah (Sn). Timah (Sn) dari limbah elektronik Cathode Ray Tubes (CRTs) tabung TV berwarna dapat digunakan sebagai bahan baku dalam proses sintesis garam SnCl2. Cathode Ray Tubes  yang telah dipreparasi selanjutnya didestruksi menggunakan asam nitrat (HNO3) dan dikarakterisasi dengan X-Ray Fluoresence (XRF). Sintesis SnCl2 dilakukan dengan reaksi redoks dan dilanjutkan dengan tahap kristalisasi. Garam SnCl2 yang dihasilkan berwarna putih keabu-abuan. Randemen yang diperoleh 62,89 %. Karakterisasi produk dilakukan dengan menentukan titik leleh produk dan uji daya reduksi Sn2+. Hasil penelitian menunjukkan bahwa kemurnian garam SnCl2 dari limbah elektronik tabung TV berwarna masih belum murni berdasarkan dari uji titik lelehnya 227-232o C sedangkan daerah titik leleh standar SnCl2 231,8o C. Dilihat dari uji daya reduksi Sn2+ yang dilakukan dengan cara titrasi potensiometri, nilai potensial yang diperoleh yaitu 0,13002, nilai ini tidak jauh berbeda dengan nilai standar potensial sel Sn2+ yaitu 0,13. Hasil ini menunjukkan bahwa nilai potensial untuk reduksi Sn2+ yang dihasilkan baik. Kata kunci: SnCl2, Cathode Ray Tubes (CRTs), timah, potensiometr

Advanced Transport Operating System (ATOPS) color displays software description: MicroVAX system

This document describes the software created for the Display MicroVAX computer used for the Advanced Transport Operating Systems (ATOPS) project on the Transport Systems Research Vehicle (TSRV). The software delivery of February 27, 1991, known as the 'baseline display system', is the one described in this document. Throughout this publication, module descriptions are presented in a standardized format which contains module purpose, calling sequence, detailed description, and global references. The global references section includes subroutines, functions, and common variables referenced by a particular module. The system described supports the Research Flight Deck (RFD) of the TSRV. The RFD contains eight Cathode Ray Tubes (CRTs) which depict a Primary Flight Display, Navigation Display, System Warning Display, Takeoff Performance Monitoring System Display, and Engine Display

Advanced Transport Operating System (ATOPS) color displays software description microprocessor system

This document describes the software created for the Sperry Microprocessor Color Display System used for the Advanced Transport Operating Systems (ATOPS) project on the Transport Systems Research Vehicle (TSRV). The software delivery known as the 'baseline display system', is the one described in this document. Throughout this publication, module descriptions are presented in a standardized format which contains module purpose, calling sequence, detailed description, and global references. The global reference section includes procedures and common variables referenced by a particular module. The system described supports the Research Flight Deck (RFD) of the TSRV. The RFD contains eight cathode ray tubes (CRTs) which depict a Primary Flight Display, Navigation Display, System Warning Display, Takeoff Performance Monitoring System Display, and Engine Display

WEEE Recycling and Circular Economy Assisted by Collaborative Robots

Considering the amount of waste of electrical and electronic equipment (WEEE) generated each year at an increasing rate, it is of crucial importance to develop circular economy solutions that prioritize reuse and recycling, as well as reducing the amount of waste that is disposed of at landfills. This paper analyses the evolution of the amount of WEEE collection and its recycling rate at the national and European levels. It also describes the regulatory framework and possible future government policy measures to foster a circular economy. Furthermore, it identifies the different parts and materials that can be recovered from the recycling process with a special emphasis on plastics. Finally, it describes a recycling line that has been designed for the dismantling of computer cathodic ray tubes (CRT)s that combines an innovative participation of people and collaborative robots which has led to an effective and efficient material recovery solution. The key issue of this human–robot collaboration relies on only assigning tasks that require human skills to operators and sending all other tasks to robots. The first results from the model show a better economic performance than current manual processes, mainly regarding the higher degree of separation of recovered materials and plastic in particular, thus reaching higher revenues. This collaboration also brings considerable additional benefits for the environment, through a higher recovery rate in weight and for workers, who can make intelligent decisions in the factory and enjoy a safer working environment by avoiding the most dangerous tasks

Modeling the Costs and Environmental Benefits of Disposal Options for End-of-Life Electronic Equipment: The Case of Used Computer Monitors

Managing the growing quantity of used electronic equipment poses challenges for waste management officials. In this paper, we focus on a large component of the electronic waste stream—computer monitors—and the disposal concerns associated with the lead embodied in cathode ray tubes (CRTs) used in most monitors. We develop a policy simulation model of consumers’ disposal options based on the costs of these options and their associated environmental impacts. For the stock of monitors disposed of in the United States in 1998, our preliminary findings suggest that bans on some disposal options would increase disposal costs from about $1 per monitor to between$3 and $20 per monitor. Policies to promote a modest amount of recycling of monitor parts, including lead, can be less expensive. In both cases, the costs of the policies exceed the value of the avoided health effects of CRT disposal.end-of-life electronics, waste stream, cost-benefit analysis

Shielding parameters of leaded cement mortar

The Cathode ray tubes (CRTs) represent more than 70% of global e-waste sets. The glass of the CRT is doped with lead to prevent emission of radiations especially electrons. The glass at the panel and neck of the CRT along with the cement mortar, a mixture of 70% neck glass and 30% cement (mix70), are investigated mathematically as shielding materials from photons having energies in the range 0.06-3 (MeV). Experimentally the material mix70 is tested at energies 0.238 and 0.583 (MeV). Good agreement was recognized between the calculated shielding parameters and that obtained experimentally while complete equality between the calculated parameters carried out using the online XCom software or Phy-X software except at low energies for concrete material. Glass from panel, neck and mix70 have acceptable shielding characteristics at and below the energy 0.238 (MeV) or generally at the X-ray region. Neck glass has good shielding parameters at the chosen energy region and it is nominated as a shielding material for many nuclear applications. To enhance the shielding characteristics of the material mix70 it should be compacted during preparation to get higher density. The present work tested the shielding properties of leaded glass composites to find out its integrity for practical shielding applications and radiological safety

Analysis of products from the pyrolysis of plastics recovered from the commercial scale recycling of waste electrical and electronic equipment

Three plastic fractions from a commercial waste electrical and electronic equipment (WEEE) processing plant were collected and investigated for the possibility of recycling them by batch pyrolysis. The first plastic was from equipment containing cathode ray tubes (CRTs), the second plastic was from refrigeration equipment, and the third plastic was from mixed WEEE. Initially, the decomposition of each of the plastics was investigated using a TGA linked to a FT-ir spectrometer which showed that the CRT plastic decomposed to form aliphatic and aromatic compounds, the refrigerator plastic decomposed to form aldehydes, CO2, aromatic, and aliphatic compounds, and the mixed WEEE plastic decomposed to form aromatic and aliphatic compounds, CO2, and CO. Each plastic mixture was also pyrolysed in a batch reactor to determine the halogen and metal content of the pyrolysis products, additionally, characterisation of the pyrolysis oils was carried out by GC-MS and the pyrolysis gases by GC-FID and GC-TCD. It was found that the halogen content of the oils was relatively low but the halogen and metal content of the chars was high. The pyrolysis oils were found to contain valuable chemical products and the pyrolysis gases were mainly halogen free, making them suitable as a fuel

Research on Strength, Alkali-Silica Reaction and Abrasion Resistance of Concrete with Cathode Ray Tube Glass Sand

In this study, the effects on the mechanical and durability properties of concrete with cathode ray tube glass sand (CRTS) obtained by recycling the screens of cathode ray tubes (CRTs) were investigated. CRTS was used by the ratios of 5, 10, 15, and 20% in the concrete. The unit weight, workability, water absorption, compressive strength, flexural strength, ultrasonic pulse velocity, static and dynamic elastic moduli, abrasion resistance, and alkali-silica reaction (ASR) expansion tests on the concrete were examined. The use of CRTS improved specific properties of concrete according to the fraction of glass aggregate used between 0 and 20%. Plain concrete (P) and CRTS of 5% in concrete gave better results in terms of mechanical properties. Use of CRTS above 5% in concrete declined the mechanical properties but on the 90th day, CRTS concrete reduced the difference. CRTS up to 20% in concrete especially improved abrasion resistance in comparison to P without CRTS; furthermore, this addition did not increase ASR expansion to a deleterious level

Waste Cathode Rays Tube: An Assessment of Global Demand for Processing

AbstractThe management of used Cathode rays tube (CRT) devices is a major problem worldwide due to rapid uptake of the technology and early obsolescence of CRT devices, which is considered an environment hazard if disposed improperly. Previously, their production has grown in step with computer and television demand but later on with rapid technological change; TVs and computer screens has been replaced by new products such as Liquid Crystal Displays (LCDs) and Plasma Display Panel (PDPs). This change creates a large volume of waste stream of obsolete CRTs waste in developed countries and developing countries will become major CRTs waste producers in the forthcoming decades. This article provides a concise overview of world's current CRTs waste scenario, namely magnitude of the demand and processing, current disposal and recycling operations