Small Angle Neutron Scattering of Aerogels: Simulations and Experiments

A numerical simulation of silica aerogels is performed using diffusion-limited cluster-cluster aggregation of spheres inside a cubic box (with periodic boundary conditions). The volume fraction $c$ is taken to be sufficiently large to get a gel structure at the end of the process. In the case of monodisperse spheres, the wavevector dependent scattered intensity $I(q)$ is calculated from the product of the form factor $P(q)$ of a sphere by the structure factor $S(q)$, which is related to the Fourier transform of $g(r)-1$, where $g(r)$ is the pair correlation function between sphere centers. The structure factor $S(q)$ exhibits large-$q$ damped oscillations characteristics of the short range (intra-aggregate) correlations between spheres. These oscillations influence the $I(q)$ curve in the $q$-region between the fractal regime and the Porod regime and quantitative comparisons are made with experiments on colloidal aerogels. Moreover, at small-$q$ values, $S(q)$ goes through a maximum characteristic of large range (inter-aggregate) correlations. Quantitative fits of the maximum in the experimental $I(q)$ curves of base-catalyzed aerogel are presented. In the case of polydisperse spheres, $I(q)$ is calculated directly from a single aggregate simulation. It is shown that increasing polydispersity shifts the location of the cross-over between the fractal and Porod regimes towards low $q$-value.Comment: RevTex, 9 pages + 11 postscript figures, compressed using "uufiles". Proceeding of the 4th International Simposium on Aerogels (To appear in J. of Non-Cryst. Solids

Colloidal systems with competing interactions: from an arrested repulsive cluster phase to a gel

We report an extensive numerical study of a charged colloidal system with competing short-range depletion attraction and long-range electrostatic repulsion. By analizing the cluster properties, we identify two distinct regions in the phase diagram: a state composed of stable finite-size clusters, whose relative interactions are dominated by long-range repulsion, and a percolating network. Both states are found to dynamically arrest at low temperatures, providing evidence of the existence of two distinct non-ergodic states in these systems: a Wigner glass of clusters and a gel.Comment: 10 figures, to be published in Soft Matte

Organization Development Experiences . A Case for Enriching HRD through OD

This article reviews a few definitions of OD and identifies eight characters that are necessary to call an activity or experience as an OD activity or experience. The article then goes on to examine ten case studies (of research, consulting and OD) of what appears like an OD activity in which the author was involved as one of the facilitators for whole system or subsystem and examines each on of them for their appropriateness to be called as OD interventions. The author then goes on to derive some lessons from these experiences. The article outlines also some advantages of using traditional OD approach in various HRD interventions and offers some suggestions for making specific HRD interventions like competency mapping, 360Degree Feedback based leadership Development and Assessment and Development Centers as OD activities. The paper concludes that using an OD approach enriches HRD and yields a good ROI on HRD interventions.

Simulating emergent urban form: desakota in China

We propose that the emergent phenomenon know as ?desakota?, the rapidurbanization of densely populated rural populations in the newlydeveloped world, particularly China, can be simulated using agent-basedmodels which combine both local and global features. We argue thatdeskota represents a surprising and unusual form of urbanization wellmatchedto processes of land development that are driven from the bottomup but moderated by the higher-level macro economy. We develop asimple logic which links local household reform to global urban reform,translating these ideas into a model structure which reflects these twoscales. Our model first determines the rate of growth of different spatialaggregates using linear statistical analysis. It then allocates this growth tothe local level using developer agents who determine the transformation ormutation of rural households to urban pursuits based on local land costs,accessibilities, and growth management practices. The model is applied todesakota development in the Suzhou region between 1990 and 2000. Weshow how the global rates of change predicted at the township level in theWuxian City region surrounding Suzhou are tempered by localtransformations of rural to urban land uses which we predict using cellularautomata rules. The model, which is implemented in the RePast 3software, is validated using a blend of data taken from remote sensing andgovernment statistical sources. It represents an example of generativesocial science that fuses plausible behavior with formalized logics matchedagainst empirical evidence, essential in showing how novel patterns ofurbanization such as desakota emerge

The Coverage and Cost Impacts of Expanding Medicaid

Estimates the drop in the number of uninsured and the rise in government costs from not limiting Medicaid eligibility for adults to the disabled and those with dependent children but basing it on income level, under two scenarios. Discusses implications

ILR Faculty Publications 2008-09

The production of scholarly research continues to be one of the primary missions of the ILR School. During a typical academic year, ILR faculty members published or had accepted for publication over 25 books, edited volumes, and monographs, 170 articles and chapters in edited volumes, numerous book reviews. In addition, a large number of manuscripts were submitted for publication, presented at professional association meetings, or circulated in working paper form. Our faculty's research continues to find its way into the very best industrial relations, social science and statistics journals.Faculty_Publications_2008_09.pdf: 36 downloads, before Oct. 1, 2020