Collaboratory for Multi-scale Chemical Science DOE grant FG02-01ER25444

Motivation for the Project Progress on the many multi-scale problems in the chemical sciences is significantly hindered by the difficulties researchers working at each scale have in accessing and translating the best available information and methods from the other scales. Very often there are "gaps" between scales which cannot be bridged at present, often because there is an unresolved technical or mathematical issue in addition to the pervasive lack of translation software and problems with connecting the mismatched data models used at each scale. Problems are particularly severe for complex systems involving combustion and pyrolysis chemistry. For example, simulations used to design high-efficiency, low-emission homogeneous-charge compression-ignition (HCCI) engines typically contain thousands of different chemical species and reactions. The engine designer running the macroscopic simulation is typically not an expert in chemistry -the macroscopic engine scale is quite complicated enough -so he or she needs all the important microscopic chemical details to be handled more or less automatically by software, and in a way that the chemistry models can be easily updated as additional information becomes available. All these microscopic chemistry details must be documented electronically in a way that is easy visible to the chemistry community, and these chemistry databases must be extensible, to make it practical to capture the benefits of the very large, but also very thinly spread (i.e. each chemist is expert in only a few types of molecules and reactions, under a limited range of conditions), expertise in the chemistry community. The numerical methods used by the engine designer were not designed to handle all this chemical detail, so intermediate preprocessing model-reduction software is needed to reduce the size of the chemical model. It is crucial that the approximation errors introduced in this step be properly controlled, so we do not lose significant accuracy in the final simulation results. Again, all the assumptions and calculations involved in this model-reduction process need to be documented, to facilitate future progress and to allow the engine model to be updated as more information on the combustion chemistry becomes available

Prospects of distributed electricity generation and services based on small scale biomass systems in Ghana

Access to energy is crucial to human welfare; no residential, commercial or industrial activity can be conceived without energy supply. At the same time, current dependence on fossil fuels and their negative effects on global climate claim for urgent alternatives. The situation in Sub-Saharan Africa is poignant: over half of the population, mainly in rural areas, live without access to electricity services. Crop residues from farming communities in those areas are unused; while technology for electricity production from agricultural biomass is progressing, managing decentralised rural electricity projects is still a challenge, especially in developing countries like Ghana, given the variety and complexity of the factors conditioning biomass to energy supply chains. Such complexity has been previously formulated in academic exercises, but with limited practical applicability for energy planners, practitioners and investors. This research has deployed a holistic approach to biomass-to-energy planning, yet flexible to adapt to different regulatory scenarios and energy supply configurations. A qualitative framework has been developed, taking into consideration four critical components: social development, organisational/institutional, technical, and financial, with their respective metrics. Then, the framework has been applied to three real case study configurations in Ghana, involving primary data collection, sustainability modelling and discussion of the techno-economic feasibility results with policy makers and practitioners. The first configuration consists in decentralised power generation using crop residues from clustered smallholder farms in 14 districts in Ghana; the number of clustered farms, reference residue yields, and residue densities are determined to assess the distances within which it would be feasible to supply feedstock to biomass power plants. The findings show that a minimum of 22 to 54 larger (10 ha) farms would need to be clustered to enable an economically viable biomass supply to a 1000 kWe plant. Financial analyses indicate that such investment would not be viable under the current renewable feed-in-tariff rates in Ghana; increased tariff by 25% or subsidies from a minimum 30% of investment cost are needed to ensure viability using internal rate of return as an indicator. Carbon finance options are also discussed. The second configuration focuses on co- and tri-generation from clustered crop residues. Techno-economic results show that 600 kW and 1 MW biomass fuelled plants to generate power, heating (for cassava or maize drying) and cooling (to refrigerate tomatoes) are feasible, considering a minimum 20% yearly profit for investors’ equity. Additional income between 29 and 64 US $/tonne of crop residue would be possible for farmers if a minimum of 60% of the heat produced can be traded. The consideration of carbon financing under the most common traded prices has little impact on the project results; if more favourable schemes (like the Swedish carbon tax) are considered, the viability of co- and tri-generation plants run on agro residue can be possible even with a low level of residual heat sales. The third configuration analyses minigrid electricity generation and services based on biomass gasification in five Ghanaian communities. Results show that the projected electricity demand compares favourably with the potential supply from available crop residues. Project financing via 100% private funding would not be viable under current national uniform tariffs; however, by applying an end-user tariff equal to the current expenditure on electricity-equivalent uses in the communities, a subsidy of about 35% on initial investment would enable a private entrepreneur an internal rate of return of 15%, whereas a 60% subsidy could enable internal rate of return of 25%. The outcomes of this research have triggered the interest of Ghanaian and international policy makers, developers and private investors.L'accés a l'energia és crucial per al benestar humà, no es pot concebre cap activitat residencial, comercial o industrial sense subministrament d'energia. Alhora, la dependència actual dels combustibles fòssils i els seus efectes negatius sobre el clima global reclamen alternatives urgents. La situació a l'Àfrica Subsahariana és punyent: més de la meitat de la població, principalment rural, viu sense accés a serveis elèctrics. Tanmateix, en aquestes zones abunden les restes agrícoles. Tot i que la tecnologia per a la producció d'electricitat a partir de biomassa agrícola avança, la promoció de l’electrificació rural descentralitzada continua sent un repte, especialment en països en desenvolupament com Ghana, atesa la varietat i la complexitat de factors que condicionen l’aprofitament energètic de la biomassa. Aquesta complexitat s'ha tractat en exercicis acadèmics, però amb poca aplicabilitat pràctica per a planificadors d'energia, promotors i inversors. A fi de contribuir a una millor planificació i presa de decisions, aquesta Tesi desplega un marc integral d’anàlisi tenint en compte quatre components (desenvolupament social, organitzatiu/institucional, tècnic, i financer), flexible per adaptar-se a diferents configuracions de subministrament d'energia i escenaris reguladors. Aquest marc s'ha aplicat a tres casos reals a Ghana, recollint dades de camp, modelitzant la viabilitat tecno-econòmica i debatent els resultats amb promotors públics i privats. La primera configuració consisteix en la generació elèctrica a partir de restes agrícoles de petites plantacions rurals, en 14 districtes a Ghana, on s?ha determinat la biomassa disponible i la seva localització per calcular les distàncies màximes que permetrien la rendibilitat de petites centrals elèctriques. Els resultats indiquen que un mínim de 22 a 54 plantacions (de 10 ha. cadascuna) haurien d'agrupar-se per permetre un subministrament de biomassa econòmicament viable a una planta de 1000 kWe. Financerament aquesta inversió no seria viable amb les tarifes actuals d’injecció a xarxa; un increment d’aquesta tarifa en un 25%, o bé una subvenció mínima del 30% del cost d'inversió són necessàries per garantir la viabilitat. La segona configuració se centra en la co- i la tri-generació a partir de restes agrícoles. Els resultats de l’anàlisi tècnic-econòmica mostren que centrals de 600 kW i 1 MW per autogenerar electricitat, calor (per assecar mandioca o de blat de moro) i fred (per refrigerar tomàquets) són factibles, fins i tot aportant un retorn anual mínim del 20% per a inversors externs. A més de l’electricitat, en cas de poder vendre com a mínim un 60% de la calor produïda, es podria pagar entre 29 i 64 USD per tona de biomassa. La consideració de bons de carboni a preus habituals de mercat internacional té poc impacte en els resultats del projecte; si es consideren esquemes més favorables (com els bons de carboni a Suècia), la viabilitat de les plantes de co-i tri-generació a partir de restes agrícoles seria possible fins i tot amb un baix nivell de vendes de calor residual. La tercera configuració tracta el servei elèctric amb microxarxes basades en la gasificació de restes agrícoles de comunitats rurals. Els resultats de l’anàlisi en 5 comunitats mostren que el potencial de generació elèctrica a partir de la biomassa disponible supera la demanda elèctrica projectada. El finançament només a partir d’aportacions privades no seria viable amb les tarifes nacionals de consum elèctric actuals; en canvi, si s’aplica una tarifa de consum igual a la despesa actual en usos equivalents a l’electricitat (p.ex. llanternes i piles, bateries de cotxe), una subvenció del 35% sobre la inversió inicial permetria una taxa interna de retorn del 15% a inversors privats, mentre que un 60% la subvenció permetria una taxa interna de retorn del 25%.Els resultats d'aquesta investigació han estat considerats pels grups d'interès de Ghana dins de la formulació de polítiques i regulacions d'electrificació rural, i perspectives de trigeneració i els minigresos de biomassa també han desencadenat l'interès dels inversors privats internacionals i ghanesosPostprint (published version

Prospects of distributed electricity generation and services based on small scale biomass systems in Ghana

Access to energy is crucial to human welfare; no residential, commercial or industrial activity can be conceived without energy supply. At the same time, current dependence on fossil fuels and their negative effects on global climate claim for urgent alternatives. The situation in Sub-Saharan Africa is poignant: over half of the population, mainly in rural areas, live without access to electricity services. Crop residues from farming communities in those areas are unused; while technology for electricity production from agricultural biomass is progressing, managing decentralised rural electricity projects is still a challenge, especially in developing countries like Ghana, given the variety and complexity of the factors conditioning biomass to energy supply chains. Such complexity has been previously formulated in academic exercises, but with limited practical applicability for energy planners, practitioners and investors. This research has deployed a holistic approach to biomass-to-energy planning, yet flexible to adapt to different regulatory scenarios and energy supply configurations. A qualitative framework has been developed, taking into consideration four critical components: social development, organisational/institutional, technical, and financial, with their respective metrics. Then, the framework has been applied to three real case study configurations in Ghana, involving primary data collection, sustainability modelling and discussion of the techno-economic feasibility results with policy makers and practitioners. The first configuration consists in decentralised power generation using crop residues from clustered smallholder farms in 14 districts in Ghana; the number of clustered farms, reference residue yields, and residue densities are determined to assess the distances within which it would be feasible to supply feedstock to biomass power plants. The findings show that a minimum of 22 to 54 larger (10 ha) farms would need to be clustered to enable an economically viable biomass supply to a 1000 kWe plant. Financial analyses indicate that such investment would not be viable under the current renewable feed-in-tariff rates in Ghana; increased tariff by 25% or subsidies from a minimum 30% of investment cost are needed to ensure viability using internal rate of return as an indicator. Carbon finance options are also discussed. The second configuration focuses on co- and tri-generation from clustered crop residues. Techno-economic results show that 600 kW and 1 MW biomass fuelled plants to generate power, heating (for cassava or maize drying) and cooling (to refrigerate tomatoes) are feasible, considering a minimum 20% yearly profit for investors’ equity. Additional income between 29 and 64 US $/tonne of crop residue would be possible for farmers if a minimum of 60% of the heat produced can be traded. The consideration of carbon financing under the most common traded prices has little impact on the project results; if more favourable schemes (like the Swedish carbon tax) are considered, the viability of co- and tri-generation plants run on agro residue can be possible even with a low level of residual heat sales. The third configuration analyses minigrid electricity generation and services based on biomass gasification in five Ghanaian communities. Results show that the projected electricity demand compares favourably with the potential supply from available crop residues. Project financing via 100% private funding would not be viable under current national uniform tariffs; however, by applying an end-user tariff equal to the current expenditure on electricity-equivalent uses in the communities, a subsidy of about 35% on initial investment would enable a private entrepreneur an internal rate of return of 15%, whereas a 60% subsidy could enable internal rate of return of 25%. The outcomes of this research have triggered the interest of Ghanaian and international policy makers, developers and private investors.L'accés a l'energia és crucial per al benestar humà, no es pot concebre cap activitat residencial, comercial o industrial sense subministrament d'energia. Alhora, la dependència actual dels combustibles fòssils i els seus efectes negatius sobre el clima global reclamen alternatives urgents. La situació a l'Àfrica Subsahariana és punyent: més de la meitat de la població, principalment rural, viu sense accés a serveis elèctrics. Tanmateix, en aquestes zones abunden les restes agrícoles. Tot i que la tecnologia per a la producció d'electricitat a partir de biomassa agrícola avança, la promoció de l’electrificació rural descentralitzada continua sent un repte, especialment en països en desenvolupament com Ghana, atesa la varietat i la complexitat de factors que condicionen l’aprofitament energètic de la biomassa. Aquesta complexitat s'ha tractat en exercicis acadèmics, però amb poca aplicabilitat pràctica per a planificadors d'energia, promotors i inversors. A fi de contribuir a una millor planificació i presa de decisions, aquesta Tesi desplega un marc integral d’anàlisi tenint en compte quatre components (desenvolupament social, organitzatiu/institucional, tècnic, i financer), flexible per adaptar-se a diferents configuracions de subministrament d'energia i escenaris reguladors. Aquest marc s'ha aplicat a tres casos reals a Ghana, recollint dades de camp, modelitzant la viabilitat tecno-econòmica i debatent els resultats amb promotors públics i privats. La primera configuració consisteix en la generació elèctrica a partir de restes agrícoles de petites plantacions rurals, en 14 districtes a Ghana, on s?ha determinat la biomassa disponible i la seva localització per calcular les distàncies màximes que permetrien la rendibilitat de petites centrals elèctriques. Els resultats indiquen que un mínim de 22 a 54 plantacions (de 10 ha. cadascuna) haurien d'agrupar-se per permetre un subministrament de biomassa econòmicament viable a una planta de 1000 kWe. Financerament aquesta inversió no seria viable amb les tarifes actuals d’injecció a xarxa; un increment d’aquesta tarifa en un 25%, o bé una subvenció mínima del 30% del cost d'inversió són necessàries per garantir la viabilitat. La segona configuració se centra en la co- i la tri-generació a partir de restes agrícoles. Els resultats de l’anàlisi tècnic-econòmica mostren que centrals de 600 kW i 1 MW per autogenerar electricitat, calor (per assecar mandioca o de blat de moro) i fred (per refrigerar tomàquets) són factibles, fins i tot aportant un retorn anual mínim del 20% per a inversors externs. A més de l’electricitat, en cas de poder vendre com a mínim un 60% de la calor produïda, es podria pagar entre 29 i 64 USD per tona de biomassa. La consideració de bons de carboni a preus habituals de mercat internacional té poc impacte en els resultats del projecte; si es consideren esquemes més favorables (com els bons de carboni a Suècia), la viabilitat de les plantes de co-i tri-generació a partir de restes agrícoles seria possible fins i tot amb un baix nivell de vendes de calor residual. La tercera configuració tracta el servei elèctric amb microxarxes basades en la gasificació de restes agrícoles de comunitats rurals. Els resultats de l’anàlisi en 5 comunitats mostren que el potencial de generació elèctrica a partir de la biomassa disponible supera la demanda elèctrica projectada. El finançament només a partir d’aportacions privades no seria viable amb les tarifes nacionals de consum elèctric actuals; en canvi, si s’aplica una tarifa de consum igual a la despesa actual en usos equivalents a l’electricitat (p.ex. llanternes i piles, bateries de cotxe), una subvenció del 35% sobre la inversió inicial permetria una taxa interna de retorn del 15% a inversors privats, mentre que un 60% la subvenció permetria una taxa interna de retorn del 25%.Els resultats d'aquesta investigació han estat considerats pels grups d'interès de Ghana dins de la formulació de polítiques i regulacions d'electrificació rural, i perspectives de trigeneració i els minigresos de biomassa també han desencadenat l'interès dels inversors privats internacionals i ghaneso

The State of the Art of Thermo-Chemical Heat Storage

The heat storage based on thermochemical technology is associated with higher amounts of energy stored with respect to systems based on sensible heat. This interesting feature is stimulating the interest of the scientific community, among energy providers and grid managers, since it can effectively support the operation and integration of renewable high-efficiency systems and local smart grids. Research in this field is achieving unprecedented goals thanks to the profitable exploitation of results obtained in the field of heat pumps and thermally driven systems. The present issue offers the reader a sensational window to this rapidly evolving world

SMART GRIDS LABORATORIES INVENTORY 2015

A smart electricity grid opens the door to a myriad of new applications aimed at enhancing security of supply, sustainability and market competitiveness. Gathering detailed information about smart grid laboratories activities represents a primary need. In order to obtain a better picture of the ongoing Smart Grid developments, after the successful smart grid project survey initiated in 2011, we recently launched a focused on-line survey addressed to organisations owning or running Smart Grid laboratory facilities. The main objective is to publish aggregated information on a regular basis in order to provide an overview of the current facilities, to highlight trends in research and investments and to identify existing gaps.JRC.F.3-Energy Security, Systems and Marke