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100th Anniversary of Macromolecular Science Viewpoint: Opportunities in the Physics of Sequence-Defined Polymers
Polymer science has been driven by ever-increasing molecular complexity, as polymer synthesis expands an already-vast palette of chemical and architectural parameter space. Copolymers represent a key example, where simple homopolymers have given rise to random, alternating, gradient, and block copolymers. Polymer physics has provided the insight needed to explore this monomer sequence parameter space. The future of polymer science, however, must contend with further increases in monomer precision, as this class of macromolecules moves ever closer to the sequence-monodisperse polymers that are the workhorses of biology. The advent of sequence-defined polymers gives rise to opportunities for material design, with increasing levels of chemical information being incorporated into long-chain molecules; however, this also raises questions that polymer physics must address. What properties uniquely emerge from sequence-definition? Is this circumstance-dependent? How do we define and think about sequence dispersity? How do we think about a hierarchy of sequence effects? Are more sophisticated characterization methods, as well as theoretical and computational tools, needed to understand this class of macromolecules? The answers to these questions touch on many difficult scientific challenges, setting the stage for a rich future for sequence-defined polymers in polymer physics
Generalized Langevin Equation Formulation for Anomalous Polymer Dynamics
For reproducing the anomalous -- i.e., sub- or super-diffusive -- behavior in
some stochastic dynamical systems, the Generalized Langevin Equation (GLE) has
gained considerable popularity in recent years. Motivated by the question
whether or not a system with anomalous dynamics can have the GLE formulation,
here I consider polymer physics, where sub-diffusive behavior is commonplace. I
provide an exact derivation of the GLE for phantom Rouse polymers, andby
identifying polymeric response to local strains, I argue the case for the GLE
formulation for self-avoiding polymers and polymer translocation through a
narrow pore in a membrane. The number of instances in polymer physics, where
the anomalous dynamics corresponds to the GLE, thus seems to be fairly common.Comment: 8 pages, no figures, minimal changes, to appear in JSTAT as a Lette
Multifractal dimension spectra in polymer physics
We study the multifractal properties of diffusion in the presence of an
absorbing polymer and report the numerical values of the multifractal dimension
spectra for the case of an absorbing self avoiding walk or random walk.Comment: 9 pages, latex, 3 latex picture
Microgravity Polymers
A one-day, interactive workshop considering the effects of gravity on polymer materials science was held in Cleveland, Ohio, on May 9, 1985. Selected programmatic and technical issues were reviewed to introduce the field to workshop participants. Parallel discussions were conducted in three disciplinary working groups: polymer chemistry, polymer physics, and polymer engineering. This proceedings presents summaries of the workshop discussions and conclusions
Statics and dynamics of single DNA molecules confined in nanochannels
The successful design of nanofluidic devices for the manipulation of biopolymers requires an understanding of how the predictions of soft condensed matter physics scale with device dimensions. Here we present measurements of DNA extended in nanochannels and show that below a critical width roughly twice the persistence length there is a crossover in the polymer physics
Structural Arrangements of Polymers Adsorbed at Nanostrings
We study ground states of a hybrid system consisting of a polymer and an
attractive nanowire by means of computer simulations. Depending on structural
and energetic properties of the substrate, we find different adsorbed polymer
conformations, amongst which are spherical droplets attached to the wire and
monolayer tubes surrounding it. We construct the complete conformational phase
diagram and analyze in more detail particularly interesting polymer-tube
conformations.Comment: Proceedings of the 23nd Workshop on Recent Developments in Computer
Simulation Studies in Condensed Matter Physics, Feb 22-26, 2010, Athens,
Georgia, US
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