About the limits of microfiltration for the purification of wastewaters

In the past, microfiltration was widely used as a pretreatment step for wastewater stream purification purposes. Experiences performed during the last years shows that microfiltration fails to maintain its performances for longer period of times. Many case studies demonstrate that the adoption of microfiltration leads to the failure of the overall process; the severe fouling of the microfiltration membranes leads to high operating costs with the consequence to make the treatment of the wastewater economically unfeasible. The boundary flux concept is a profitable tool to analyze fouling issues in membrane processes. The boundary flux value separates an operating region characterized by reversible fouling formation from irreversible one. Boundary flux values are not content, but function of time, as calculated by the subboundary fouling rate value. The knowledge of both parameters may fully describe the membrane performances in sub-boundary operating regimes. Many times, for wastewater purification purposes, ultrafiltration membranes appear to be suits better to the needs, even they exhibit lower permeate fluxes compared to microfiltration. Key to this choice is that ultrafiltration appears to resist better to fouling issues, with a limited reduction of the performances as a function of time. In other words, it appears that ultrafiltration exhibit higher boundary flux values and lower sub-boundary fouling rates. In this work, after a brief introduction to the boundary flux concept, for many different wastewater streams (more than 20, produced by the most relevant industries in food, agriculture, manufacture, pharmaceutics), the boundary flux and sub-boundary fouling rate values of different microfiltration and ultrafiltration membranes will be discussed and compared. The possibility to successfully use microfiltration as a pretreatment step strongly depends on the feedstock characteristics and, in detail, on the particle size of the suspended matter. In most cases, microfiltration demonstrates to be technically unsuitable for pretreatment purposes of many wastewater streams; as a consequence, the adoption of microfiltration pushes operators to exceed boundary flux conditions, therefore triggering severe fouling, that leads to economic unfeasibility of the process in long terms

Dead-end filtration of yeast suspensions: correlating specific resistance and flux data using artificial neural networks

The specific cake resistance in dead-end filtration is a complex function of suspension properties and operating conditions. In this study, the specific resistance of resuspended dried bakers yeast suspensions was measured in a series of 150 experiments covering a range of pressures, cell concentrations, pHs, ionic strengths and membrane resistances. The specific resistance was found to increase linearly with pressure and exhibited a complex dependence on pH and ionic strength. The specific resistance data were correlated using an artificial neural network containing a single hidden layer with nine neurons employing the sigmoidal activation function. The network was trained with 104 training points, 13 validation points and 33 test points. Excellent agreement was obtained between the neural network and the test data with average errors of less than 10%. In addition, a network was trained for prediction of the filtrate flux directly from the system inputs and this approach is easily extended to crossflow filtration by adding inputs such as the crossflow velocity and channel height. An attempt was made to interpret the network weights for both the specific resistance and flux networks. The effective contribution of each input to the system output was computed in each case and showed trends that were as expected. Although network weights, and consequently the computed effect of each parameter, is different each time a network is changed (depending on the initial weights used in the training process), the variation was low enough for information contained in the network to be interpreted in a meaningful way

Modelling the microfiltration of lactic acid fermentation broths and comparison of operating modes

clarification of fermentation broths by cross-flow microfiltration. Microfiltration experiments conducted under constant transmembrane pressure and under constant permeate fluxes (higher and lower than the critical flux) were represented by the resistance in series model in which the membrane resistance, the adsorption resistance, the bacteria cake resistance and the soluble compounds concentration polarisation resistance were taken into account. The different operating modes were compared in terms of two industrial interest criteria: the productivity and fouling rates. Higher productivities were obtained during constant transmembrane pressure runs whereas the lowest fouling rate was observed during the run conducted with a constant permeate flux lower than the critical flux. However, this fouling was mainly due to adsorption and solute components concentration polarisation. Key words

Optimal design of batch plants under economic and ecological considerations: Application to a biochemical batch plant

This work deals with the multicriteria cost-environment design of multiproduct batch plants, where the design variables are the equipment item sizes as well as the operating conditions. The case study is a multiproduct batch plant for the production of four recombinant proteins. Given the important combinatorial aspect of the problem, the approach used consists in coupling a stochastic algorithm, indeed a Genetic Algorithm (GA) with a Discrete Event Simulator (DES). To take into account the conflicting situations that may be encountered at the earliest stage of batch plant design, i.e. compromise situations between cost and environmental considerations, a Multicriteria Genetic Algorithm (MUGA) was developed with a Pareto optimal ranking method. The results show how the methodology can be used to find a range of trade-off solutions for optimizing batch plant design

Impact of the physico-chemistry of the wine on membrane filtration performance

During the process of wine making, operation of cross-flow microfiltration allows a one-step clarification and sterilization of wine, with lower waste compared to the conventional processes of clarification and sterilization. Indeed, these processes are sources of voluminous waste (earth, Kieselguhr, additives), when discharges are becoming more and more restricted by environmental and health rules. Nevertheless, cross-flow microfiltration of wine presents a major drawback: membrane fouling causes a significant decrease in the flow rates, due to excessive retention of some wine components which could lead ultimately to the alteration of the quality of wine. The aim of this work was to study the impact of some specific wine components (phenolic compounds and yeast extract), as well as some physico-chemical parameters (pH) in regard to membrane fouling. Studies were performed using one red wine and synthetic wines, using cellulose acetate membranes (0.2 μm) operated in the dead-end mode under 2 bar pressure. The simultaneous presence of the both species of phenolic compounds (anthocyanins and tannins) in the synthetic wine was shown to be the main cause of fouling, whereas the presence of one specie leads only to standard blocking type behavior. An important decrease in the flow rates was also observed when yeast extract was added to the liquid. This yeast extract was shown to contain 300 mg/g of proteins and to be free of mannoproteins. The influence of these proteins on fouling was demonstrated while pre-treating the synthetic wine with bentonite, which was able to adsorb proteins, and in this case, no fouling was observed. It was also shown that, when decreasing the pH, the flow rate was enhanced. For all experiments, a fouling index or cake specific resistance, according to the type of fouling, was calculated in order to be used as a reference to estimate the filterability of a given wine, according to its composition in some targeted molecules. Finally, the experiments of the actual red wine exhibited complete rapid fouling of the membrane, probably due to the presence of high concentration of phenolic compounds

Ultrasound enhancement of microfiltration performance for natural organic matter removal

Sonication of water at 1500 W power prior to microfiltration showed that short sonication times (60 s) gave a reduced flux decline. It is suggested that a less potent, smaller molecular form of the natural organic matter (NOM) was produced by sonication. Longer sonication times diminished this beneficial effect. This may be due to the formation of aggregates or compounds that are more readily adsorbed on the membrane. Where the sonication was preceded by an alum treatment, the flux loss showed a regular decrease with longer sonication times. It is suggested that the effects of sonication on the alum flocs and on the flocs; NOM interactions may play a critical role in regulating the flux. Where sand was present on sonication at 800 and 1400 W, the cavitational energy was focussed on adsorbed organic material, resulting in more efficient destruction and the formation of compounds that counteracted the flux enhancement

Behaviours of natural organic matter in membrane filtration for surface water treatment : a review

Membrane application in surface water treatment provides many advantages over conventional treatment. However, this effort is hampered by the fouling issue, which restricts its widespread application due to increases in hydraulic resistances, operational and maintenance costs, deterioration of productivity and frequency of membrane regeneration problems. This paper discusses natural organic matter (NOM) and its components as the major membrane foulants that occur during the water filtration process, possible fouling mechanisms relating to reversible and irreversible of NOM fouling, current techniques used to characterize fouling mechanisms and methods to control fouling. Feed properties, membrane characteristics, operational conditions and solution chemistry were also found to strongly influence the nature and extent of NOM fouling. Findings of such studies are highlighted. The understanding of the combined roles of controlling factors and the methods used is very important in order to choose and optimize the best technique and conditions during surface water treatment. The future potential of membrane application for NOM removal is also discussed

The effect of NOM characteristics and membrane type on microfiltration performance

Efforts to understand and predict the role of different organic fractions in the fouling of low-pressure membranes are presented. Preliminary experiments with an experimental apparatus that incorporates automatic backwashing and filtration over several days has shown that microfiltration of the hydrophilic fractions leads to rapid flux decline and the formation of a cake or gel layer, while the hydrophobic fractions show a steady flux decline and no obvious formation of a gel or cake layer. The addition of calcium to the weakly hydrophobic acid (WHA) fraction led to the formation of a gel layer from associations between components of the WHA. The dominant foulants were found to be the neutral and charged hydrophilic compounds, with hydrophobic and small pore size membranes being the most readily fouled. The findings suggest that surface analyses such as FTIR will preferentially identify hydrophilic compounds as the main foulants, as these components form a gel layer on the surface while the hydrophobic compounds adsorb within the membrane pores. Furthermore, coagulation pre-treatment is also likely to reduce fouling by reducing pore constriction rather than the formation of a gel layer, as coagulants remove the hydrophobic compounds to a large extent and very little of the hydrophilic neutral components

Characterization of new membrane materials by means of fouling experiments Adsorption of bsa on polyetherimide-polyvinylpyrrolidone membranes

The hydrophilicity of polyetherimide-polyvinylpyrrolidone (PEI-PVP) microfiltration membranes can be adjusted by means of a suitable post-treatment. The influence of the nature of the membrane surface on fouling properties was studied using permeation experiments before and after exposure to a protein (BSA) solution and adsorption experiments with 14C labelled BSA. A correlation between the permeation experiments and the radiolabelled BSA adsorption experiments was found. The PVP in the membrane matrix prevents BSA adsorption taking place to a large extent and it appeared that heat-treated PEI-PVP membranes showed the same nonfouling behaviour as, for example, cellulose acetate membranes

Morphological characterization of a polymeric microfiltration membrane by synchrotron radiation computed microtomography

Most commercial polymeric membranes are prepared by phase inversion. The performance of the membranes depends greatly on the morphology of the porous structure formed during the different steps of this process. Researchers in this field have found it extremely difficult to foresee how a change in the composition of the polymer solution will affect pore formation without a set of methods designed to yield detailed knowledge of the morphological structure. This paper reports the new potential associated with X-Ray synchrotron microtomography to characterize the 3D structure of a PvDF hollow fibre microfiltration membrane prepared by phase inversion. 3D morphological data obtained from the ID19 line at the ESRF are presented. The membrane actually appears as a complex three-dimensional bi-continuum of interconnected pores. Within the hollow fibre structure, different regions with various thicknesses and pore size distributions have been identified and well characterized. Transversal views show the anisotropic finger-like structure of pores, while longitudinal sections reveal a honeycomb structure which resembles the structure of highly concentrated water in oil emulsion or dispersion. This typical structure might be obtained during the phase inversion process. How the phase inversion process may result in these morphologies is finally discussed