Mechanical rolling formation of interpenetrated lithium metal/lithium tin alloy foil for ultrahigh-rate battery anode

To achieve good rate capability of lithium metal anodes for high-energy-density batteries, one fundamental challenge is the slow lithium diffusion at the interface. Here we report an interpenetrated, three-dimensional lithium metal/lithium tin alloy nanocomposite foil realized by a simple calendering and folding process of lithium and tin foils, and spontaneous alloying reactions. The strong affinity between the metallic lithium and lithium tin alloy as mixed electronic and ionic conducting networks, and their abundant interfaces enable ultrafast charger diffusion across the entire electrode. We demonstrate that a lithium/lithium tin alloy foil electrode sustains stable lithium stripping/plating under 30mAcm(-2) and 5mAhcm(-2) with a very low overpotential of 20mV for 200 cycles in a commercial carbonate electrolyte. Cycled under 6C (6.6mAcm(-2)), a 1.0mAhcm(-2) LiNi0.6Co0.2Mn0.2O2 electrode maintains a substantial 74% of its capacity by pairing with such anode

Lithium counterdoped silicon solar cell

The resistance to radiation damage of an n(+)p boron doped silicon solar cell is improved by lithium counterdoping. Even though lithium is an n-dopant in silicon, the lithium is introduced in small enough quantities so that the cell base remains p-type. The lithium is introduced into the solar cell wafer by implantation of lithium ions whose energy is about 50 keV. After this lithium implantation, the wafer is annealed in a nitrogen atmosphere at 375 C for two hours

7Li NMR of Normal Human Erythrocytes

Lithium has been known to be an effective medication for people with bipolar disorder. The mechanisms of action of lithium in the brain is not very well understood. NMR spectroscopy and imaging are effective both in determining lithium levels in tissue and brain. We have monitored lithium levels in red blood cells. We have been able to separate intra- and extracellular compartments of lithium using shift reagents, thereby obtaining T^1 \u27s of both the compartments. Lithium uptake as a function of hematocrit was monitored weekly over a 3 week period. The time constant of 50 mM lithium uptake at 25°C and 85% hematocrit was found to be 16.5 hrs. The time constant of 1.8 mM lithium uptake at 37 °C and 45% hematocrit was found to be 11.6 hrs. Experiments on the visibility of the quadrupolar nuclei indicate that it is only 74-90% visible and the visibility decreased with decreasing concentrations

Lithium treatment reduces the renal kallikrein excretion rate

Lithium treatment reduces the renal kallikrein excretion rate. Lithium salts are widely used agents for the prophylactic treatment of affective disorders. Lithium salts may be associated with distal nephron dysfunction. Kallikrein is a protease which is generated by the distal nephron. We used an amidolytic assay of chromatographically purified enzyme to determine the urinary excretion rate of active kallikrein in relation to lithium treatment. All plasma lithium concentrations were within the therapeutic range (0.4 to 0.9 mmol/liter). In 15 patients the urinary excretion rate of active kallikrein was 267.4 65.6 mU/24 hrs before lithium treatment, and fell to 117.8 39.6 mU/24 hrs (P < 0.05) on day 14 of lithium treatment. This reduction was associated with a decrease of immunoreactive kallikrein in the same urines by 66%. In another 15 patients who had undergone lithium therapy for an average period of 5.6 years, the urinary excretion rate of active kallikrein was 86.1 14.5 mU/24 hrs, while 21 age-matched healthy controls had an excretion rate of 364.1 58.4 mU/24 hrs (P < 0.05). Measurements of immunoreactive kallikrein in the same urine samples demonstrated a reduction of kallikrein after long-term lithium treatment by 78%. These observations could not be attributed to changes in creatinine clearance, renal sodium or potassium excretion rates or plasma concentrations of aldosterone and vasopressin. Addition of lithium to the urine in vitro had no demonstrable effect on kallikrein measurement by amidolytic assay. We conclude that lithium in therapeutic plasma concentrations may directly suppress the secretion of kallikrein by renal connecting tubule cells

On the possible existence of a self-regulating hydrodynamical process in slowly rotating stars II. Lithium Plateau in Halo Stars and Primordial Abundance

The lithium plateau observed in halo stars has long appeared as a paradox in the general context of the lithium abundance behavior in stellar outer layers. First, the plateau is flat, second, the lithium abundance dispersion is extremely small. This seems in contradiction with the large lithium variations observed in younger stars. It is also difficult to understand theoretically as lithium nuclei are easily destroyed by nuclear reactions, and subject to microscopic diffusion which, in the case of halo stars, should also lead to depletion. Several ideas have been proposed to account for the lithium behavior in halo stars. The most promising possibilities were rotational-induced mixing, which could reduce lithium in the same way for all the stars, and mass-loss, which could oppose the lithium settling. In both cases however, the parameters should be tightly adjusted to prevent any dispersion in the final results. Vauclair 1999 (paper I) pointed out that the mu-gradient terms which appear in the computations of the meridional circulation velocity were not introduced in previous computations of rotationally-induced mixing. This can lead to a self-regulating process which reduces the efficiency of the meridional circulation as well as the microscopic diffusion. Here we present numerical computations of this process and its influence on the lithium abundance variations in halo stars. We show that in slowly rotating stars, under some conditions, lithium can be depleted by a factor of up to two with a dispersion smaller than 0.1 dex in the middle part of the lithium plateau. We derive a primordial lithium abundance of 2.5 +/- 0.1, consistent with the recent determinations of D/H and 4He/H.Comment: 15 pages, 10 figures. to be published in A&

Thermodynamics of Lithium Intercalation into Graphites and Disordered Carbons

The temperature dependence of the open-circuit potential of lithium half-cells was measured for electrodes of carbon materials having different amounts of structural disorder. The entropy of lithium intercalation, DeltaS, and enthalpy of intercalation, DeltaH, were determined over a broad range of lithium concentrations. For the disordered carbons, DeltaS is small. For graphite, an initially large DeltaS decreases with lithium concentration, becomes negative, and then shows two plateaus associated with the formation of intercalation compounds. For all carbons DeltaH is negative, and decreases in magnitude with increased lithium concentration. For lithium concentrations less than x = 0.5 in LixC6, for the disordered carbons the magnitude of DeltaH is significantly more negative than for graphite (i.e., intercalation is more exothermic). The measurements of DeltaH provide an energy spectrum of chemical environments for lithium. This spectrum can be used to understand some of the concentration dependence of configurational entropy, but the negative values of DeltaS require another contribution to entropy, perhaps vibrational in origin

Nanobead-reinforced outmost shell of solid-electrolyte interphase layers for suppressing dendritic growth of lithium metal

Department of Energy EngineeringDesign of catalyst support for high durability of oxygen electrocatalystPlating-stripping reversibility of lithium metal was improved by reinforcing the solid-electrolyte interphase (SEI) layer by inorganic nanobeads during formation of the SEI layer. The outmost SEI shell (OSS) was clearly identified, which is the SEI layer formed on current collectors (or lithium metal) before the first lithium metal deposition. The OSS was intrinsically brittle and fragile so that the OSS was easily broken by lithium metal dendrites growing along the progress of plating. Lithium metal deposit was not completely stripped back to lithium ions. On the other hand, lithium metal cells containing inorganic nanobeads in electrolyte showed high reversibility between plating and stripping. The nanobeads were incorporated into the OSS during the OSS formation. The nanobead-reinforced OSS having mechanically durable toughness suppressed dendritic growth of lithium metal, not allowing the dendrites to penetrate the OSS. In addition to the mechanical effect of nanobeads, the LiF-rich SEI layer formation was triggered by HF generated by the reaction of the moisture adsorbed on oxide nanobeads with PF6-. The LiF-rich composition was responsible for facile lithium ion transfer through the SEI layer and the OSS in the presence of nanobeads.clos

Impact of rotation and disc lifetime on pre-main sequence lithium depletion of solar-type stars

Aims: We study the influence of rotation and disc lifetime on lithium depletion of pre-main sequence (PMS) solar-type stars. Methods: The impact of rotational mixing and of the hydrostatic effects of rotation on lithium abundances are investigated by computing non-rotating and rotating PMS models that include a comprehensive treatment of shellular rotation. The influence of the disc lifetime is then studied by comparing the lithium content of PMS rotating models experiencing different durations of the disc-locking phase between 3 and 9 Myr. Results: The surface lithium abundance at the end of the PMS is decreased when rotational effects are included. During the beginning of the lithium depletion phase, only hydrostatic effects of rotation are at work. This results in a decrease in the lithium depletion rate for rotating models compared to non-rotating ones. When the convective envelope recedes from the stellar centre, rotational mixing begins to play an important role due to differential rotation near the bottom of the convective envelope. This mixing results in a decrease in the surface lithium abundance with a limited contribution from hydrostatic effects of rotation, which favours lithium depletion during the second part of the PMS evolution. The impact of rotation on PMS lithium depletion is also found to be sensitive to the duration of the disc-locking phase. When the disc lifetime increases, the PMS lithium abundance of a solar-type star decreases owing to the higher efficiency of rotational mixing in the radiative zone. A relationship between the surface rotation and lithium abundance at the end of the PMS is then obtained: slow rotators on the zero-age main sequence are predicted to be more lithium-depleted than fast rotators due to the increase in the disc lifetime.Comment: 8 pages, 11 figures, A&