Use of X-ray radiography and tomography to evaluate self-healing concrete

info:eu-repo/semantics/publishe

Self-healing concrete in aggressive enironments

Although certain crack widths are allowed in reinforced concrete structures, without having immediate effects on the structural stability, they may impair the durability and service life of the structure in the long term. Cracks wider than 10 μm will result, for instance, in a faster penetration of chlorides into the crack and from there onwards into the concrete matrix. Fortunately, the autogenous healing ability of concrete may close cracks of up to 100 μm completely. The further hydration of binder particles, will be supplemented by the deposition of calcium carbonate crystals in case of wet/dry cycles. In case of marine infrastructures in tidal zones, the presence of magnesium sulfates may enhance the crack sealing by means of brucite precipitation. These processes will result in reduced chloride penetration rates. If the cracks are larger than 100 μm or the conditions are not favourable for autogenous healing, autonomous healing mechanisms can be incorporated. In this case, healing is obtained through encapsulated polymeric healing agents, superabsorbent polymers, microbial agents, expansive additives, etc. With encapsulated polyurethane based healing agents, a reduction of the chloride concentration by 75% or more was obtained in a zone with a 300 μm wide crack after chloride diffusion tests, relative to the case in which cracks were not healed. As a result, the service life of reinforced concrete elements in marine environments could be increased with a factor of about 10. Neutron radiography images obtained during a capillary sorption test indicated that release of encapsulated polyurethane in wet conditions was favourable for the polyurethane reaction. As an alternative to the autonomous healing with encapsulated polyurethane, also the incorporation of encapsulated water repellent agents and corrosion inhibitors, has proven to effectively delay reinforcement corrosion during electrochemical measurement campaigns. Accelerated corrosion tests on cracked, manually treated mortar samples, allowed to rapidly screen different agents for their efficiency

Service life estimation of cracked and healed concrete in marine environment

In the aggressive seawater environment, the durability of concrete is strongly influenced by the presence of chlorides and sulfates. Marine structures mostly have an important social function with a high economic impact, which makes durability a key issue. In addition, early-age cracks are a common problem, specifically for massive structural components. Repair of cracks is expensive and often impossible due to inaccessibility. Self-healing concrete is a promising solution to make marine structures more durable. In this study, capsules containing Polyurethane (PU) prepolymers were embedded in the concrete to release their contents when cracks appear. In cracked mortar, the chloride diffusion coefficients in the zone immediately around the crack significantly increased compared to uncracked mortar. The crack width dependency could be introduced into the service life model using a crack effect function. For crack widths in the range of 100 mu m to 300 mu m a service life decrease of around 80% was calculated. Autonomous crack healing had a beneficial influence on the resistance against chloride diffusion. However, for about one third of the cracks the healing mechanism failed, probably due to shifting of the tubes, tubes not rupturing properly, too high capillary forces in the tubes, etc. Nevertheless, on average, the service life of autonomously healed structures by means of encapsulated polyurethane increased with around 100% compared to cracked, unhealed structures. Moreover, in the most beneficial situation of proper healing, a service life increase of 150-550% was obtained, reaching values similar as for sound structures

Sustainability effects of including concrete cracking and healing in service life prediction for marine environments

With today’s focus on sustainable design, it is necessary to adequately predict and prolong service life of concrete in marine environments. By introducing self-healing properties, service life extension can be achieved. However, in prediction models, the required concrete mix specific input is usually not available. Moreover, little attention goes to the unavoidable presence of cracks. Finally, autonomous crack healing has almost never been taken into account. In this paper, the relevant model input was estimated from experimental chloride profiles. It enabled an adequate prediction of the chloride-induced steel depassivation period for cracked and uncracked 15% fly ash concrete (8–104 years, respectively). Comparison with self-healing by means of encapsulated polyurethane indicated a 48–76% self-healing efficiency. It could extend the corrosion initiation period to 36–68 years. Being much less subject to time-dependent repair, PU based self-healing concrete has a 77–88% lower environmental impact than traditional (cracked) concrete

Real-scale testing of the efficiency of self-healing concrete

After several years of research in the Magnel Laboratory (Belgium) to obtain concrete with self-healing properties, the most promising mechanisms were tested on a larger scale. Instead of small mortar samples with self-healing properties, real-scale self-healing concrete beams (150 mm × 250 mm × 3000 mm) were made and the efficiency of autonomous crack repair was evaluated over time after loading the beams in four-point bending. In addition to a reference beam without self-healing properties, a beam with encapsulated polyurethane and a beam containing superabsorbent polymers were investigated. While for the beam with polyurethane, crack repair is obtained as the healing agent is released as soon as cracks damage the embedded capsules, the superabsorbent polymers absorb water which intrudes into the cracks, immediately blocking the crack through swelling and later on by continued hydration and precipitation of calcite. The efficiency of both self-healing approaches was compared by measuring the reduction in water ingress into the cracks and by measuring the crack width reduction over time

Resistance to chloride penetration of self-healing concrete with encapsulated polyuretyhane

Reinforcement corrosion induced by diffusion of chlorides is one of the most important damage mechanisms that leads to the deterioration of reinforced concrete structures. Cracking of reinforced concrete structures during their service life is almost inevitable. Cracks form preferential pathways for the ingress of chlorides and will accelerate the onset of corrosion and its propagation. In this paper, autonomous self-healing of cracks by encapsulated polyurethane is investigated as a possible method to heal cracks and reduce chloride ingress through cracks without human intervention. Cracks in concrete specimens were created in two ways: by means of thin metal plates to create standardized artificial cracks and by means of splitting tests to create realistic cracks. A crack width of 0.3 mm was chosen since most design codes limit the crack width to that value. The resistance to chloride penetration of autonomously healed concrete was evaluated by the diffusion test as described in NT Build 443. Uncracked, cracked and healed specimens were subjected to a 165 g/l NaCl solution for 7 weeks. After that period chloride profiles in the crack region and in an area further away from the crack were obtained by potentiometric titrations. From the resulting chloride profiles it was concluded that the polyurethane was very well able to seal both artificial and realistic cracks and reduce the chloride content in the crack zone significantly. At depths below the surface larger than 14 mm, healing was able to reduce the total chloride content in the crack zone by more than 70%

Application of a self-healing mechanism in concrete to reduce chloride ingress through cracks

Chloride induced corrosion of reinforcing steel is one of the most important damage mechanisms of reinforced concrete structures. The appearance of cracks in reinforced concrete structures will accelerate the ingress of chlorides and therefore cause a higher risk for corrosion and its propagation. In this research, autonomous healing of cracks by encapsulated polyurethane was investigated as a possible method to reduce chloride ingress through cracks. Therefore, uncracked, cracked, and healed concrete specimens were subjected to a high concentration NaCl solution for exposure periods of 7, 19, and 52 weeks. Chloride profiles were determined in the crack region after each exposure period. The resulting chloride profiles showed that the autonomous crack healing mechanism formed a partial barrier which prevented the immediate ingress of chlorides through cracks. At depths below the surface larger than 12 mm, a self-healing efficiency of at least 70% was found for all exposure periods. Due to this big reduction in chloride concentration, a much lower amount of chlorides will reach the steel reinforcement through the cracks. This will postpone the time to corrosion initiation and reduce the corrosion rate of the steel reinforcement. Consequently, the use of self-healing concrete will have important benefits for the durability of reinforced concrete structures in marine environments

Experimental investigation on the ability of macro-encapsulated polyurethane to resist cyclic damaging actions in self-repaired cement-based elements

The use of polymer precursors as repairing agents in capsule-based self-healing systems has been extensively studied in recent years. In particular, the effectiveness of macro-encapsulated polyurethane in restoring both watertightness and mechanical properties has been demonstrated at the laboratory level, and the experimental methods to test the effectiveness have been validated following pre-standard procedures. However, the use of macro-capsules containing polyurethane precursors for field applications has not been sufficiently implemented yet. For these systems to become appealing to the construction industry, it is essential to further characterize the self-healing effect in terms of stability in time, namely, to investigate the behavior of the self-healing system when subjected to recurring actions that can affect structures in time, after cracking and subsequent self-repairing. The goal of this study was to characterize the ability of commercial polyurethane foams to withstand cyclic flexural actions and repeated temperature variations after release from cementitious macro-capsules embedded in mortar specimens. The specimens were tested immediately after pre-cracking and self-repairing to characterize the initial sealing efficiency through a water-flow test. The same test was repeated at prescribed time intervals to analyze the evolution of the sealing efficiency with the applied mechanical and thermal stresses. The results showed that the proposed system has good stability against the selected damaging actions and confirmed the potential of encapsulated polyurethane for self-healing applications

Development of an improved cracking method to reduce the variability in testing the healing efficiency of self-healing mortar containing encapsulated polymers

Concrete cracking can result in a significant reduction of the durability and the service life due to the ingress of aggressive agents Self-healing concrete is able to heal cracks without external intervention, thereby mitigating the need for manual repair. In the assessment of the healing efficiency of self-healing concrete the to-be-healed crack width is an important parameter and different researchers have emphasised that the variability of the crack width significantly hampers an accurate assessment of the healing efficiency. With two new crack control techniques the variability of the crack width was reduced in order to decrease the variability on the calculated healing efficiency. This paper reports on the application of these techniques for the assessment of self-healing mortar containing encapsulated polyurethane. The healing potential was investigated by looking at the degree of sealing using a water flow test setup. It was observed that by using a crack control technique the variability on the crack width can indeed be reduced. Nonetheless, this does not translate in an equivalent reduction on the variability of the healing efficiency. This indicates that other factors contribute to the variability of the healing efficiency