A perturbation density functional theory for the competition between inter and intramolecular association

Using the framework of Wertheim's thermodynamic perturbation theory we develop the first density functional theory which accounts for intramolecular association in chain molecules. To test the theory new Monte Carlo simulations are performed at a fluid solid interface for a 4 segment chain which can both intra and intermolecularly associate. The theory and simulation results are found to be in excellent agreement. It is shown that the inclusion of intramolecular association can have profound effects on interfacial properties such as interfacial tension and the partition coefficient

Stringent neutron-star limits on large extra dimensions

Supernovae (SNe) are copious sources for Kaluza-Klein gravitons which are generic for theories with large extra dimensions. These massive particles are produced with average velocities ~0.5 c so that many of them are gravitationally retained by the SN core. Every neutron star thus has a halo of KK gravitons which decay into nu bar-nu, e^+e^- and gamma gamma on time scales \~10^9 years. The EGRET gamma-flux limits (E_gamma ~ 100 MeV) for nearby neutron stars constrain the fundamental scale for n=2 extra dimensions to M >500 TeV, and M>30 TeV for n=3. The upcoming GLAST satellite is a factor ~30 more sensitive and thus may detect KK decays, for example at the nearby neutron star RX J185635--3754. The requirement that neutron stars are not excessively heated by KK decays implies M>1700 TeV for n=2, and M>60 TeV for n=3.Comment: Minor changes, matches version to appear in PR

Dynamics of a trapped Brownian particle in shear flows

The Brownian motion of a particle in a harmonic potential, which is simultaneously exposed either to a linear shear flow or to a plane Poiseuille flow is investigated. In the shear plane of both flows the probability distribution of the particle becomes anisotropic and the dynamics is changed in a characteristic manner compared to a trapped particle in a quiescent fluid. The particle distribution takes either an elliptical or a parachute shape or a superposition of both depending on the mean particle position in the shear plane. Simultaneously, shear-induced cross-correlations between particle fluctuations along orthogonal directions in the shear plane are found. They are asymmetric in time. In Poiseuille flow thermal particle fluctuations perpendicular to the flow direction in the shear plane induce a shift of the particle's mean position away from the potential minimum. Two complementary methods are suggested to measure shear-induced cross-correlations between particle fluctuations along orthogonal directions.Comment: 14 pages, 7 figure

The spectroscopic evolution of the γ\gamma-ray emitting classical nova Nova Mon 2012. I. Implications for the ONe subclass of classical novae

Nova Mon 2012 was the first classical nova to be detected as a high energy $\gamma$-ray transient, by Fermi-LAT, before its optical discovery. We study a time sequence of high resolution optical echelle spectra (Nordic Optical Telescope) and contemporaneous NOT, STIS UV, and CHIRON echelle spectra (Nov 20/21/22). We use [O III] and H$\beta$ line fluxs to constrain the properties of the ejecta. We derive the structure from the optical and UV line profiles and compare our measured line fluxes for with predictions using Cloudy with abundances from other ONe novae. Mon 2012 is confirmed as an ONe nova. We find E(B-V)=0.85$\pm$0.05 and hydrogen column density $\approx 5\times 10^{21}$ cm$^{-2}$. The corrected continuum luminosity is nearly the same in the entire observed energy range as V1974 Cyg, V382 Mon, and Nova LMC 2000 at the same epoch after outburst. The distance, about 3.6 kpc, is quite similar to V1974 Cyg. The line profiles can be modeled using an axisymmetric bipolar geometry for the ejecta with various inclinations of the axis to the line of sight, 60 \le i \le 80 degrees, an opening angle of \approx$70 deg, inner radius$\Delta R/R(t)\approx 0.4$for permitted lines and less filled for forbidden lines. The filling factor$f\approx 0.1-0.3$implying M(ejecta)$\leq 6\times 10^{-5}$M$_\odot$. The ONe novae appear to comprise a single physical class with bipolar high mass ejecta, similarly enhanced abundances, and a common spectroscopic evolution within a narrow range of luminosities. The detected$\gamma$-ray emission may be a generic phenomenon, common to all ONe novae, possibly to all classical novae, and connected with acceleration and emission processes within the ejecta (abstract severely truncated).Comment: Submitted to A&A 9/1/2013; Accepted 27/2/2013 (in press

The spectroscopic evolution of the recurrent nova T Pyxidis during its 2011 outburst. II.The optically thin phase and the structure of the ejecta in recurrent novae

We continue our study of the physical properties of the recurrent nova T Pyx, focussing on the structure of the ejecta in the nebular stage of expansion during the 2011 outburst. The nova was observed contemporaneously with the Nordic Optical Telescope (NOT), at high resolution spectroscopic resolution (R ~ 65000) on 2011 Oct. 11 and 2012 Apr. 8 (without absolute flux calibration), and with the Space Telescope Imaging Spectrograph (STIS) aboard the Hubble Space Telescope, at high resolution (R ~ 30000) on 2011 Oct. 10 and 2012 Mar. 28 (absolute fluxes). We use standard plasma diagnostics (e.g. [O III] and [N II] line ratios and the H$\beta$ line fluxes) to constrain electron densities and temperatures. Using Monte Carlo modeling of the ejecta, we derive the structure and filling factor from comparisons to the optical and ultraviolet line profiles. The ejecta can be modeled using an axisymmetric conical -- bipolar -- geometry with a low inclination of the axis to the line of sight, i=15+/-5 degrees, compatible with published results from high angular resolution optical spectro-interferometry. The structure is similar to that observed in the other short orbital period recurrent novae during their nebular stages. We show that the electron density scales as $t^{-3}$ as expected from a ballistically ejected constant mass shell; there is no need to invoke a continuing mass outflow following the eruption. The derived mass for the ejecta with filling factor f ~ 3%, M_ej ~ 2E-6$M_sun is similar to that obtained for other recurrent nova ejecta but inconsistent with the previously reported extended optically thick epoch of the explosion. We suggest that the system underwent a common envelope phase following the explosion that produced the recombination event. Implications for the dynamics of the recurrent novae are discussed. (truncated)Comment: accepted for publication in A&A (10 Nov. 2012), 10 pgs, 16 fig

Resonant Absorption in the AGN spectra emerging from photoionized gas: differences between steep and flat ionizing continua

We present photoionization models accounting for both photoelectric and resonant absorption. Resonance absorption lines from C, O, Ne, Mg, Si S and Fe between 0.1 and 10 keV are treated. In particular we consider the complex of almost 60 strong Fe L absorption lines around 1 keV. We calculate profiles, intensities and equivalent widths of each line, considering both Doppler and natural broadening mechanisms. Doppler broadening includes a term accounting for turbulence of the gas along the line of sight. We computed spectra transmitted by gas illuminated by drastically different ionizing continua and compared them to spectra observed in flat X-ray spectrum, broad optical emission line type 1 AGN, and steep X-ray spectrum, narrow optical emission line type 1 AGN. We show that the $\sim 1$ keV absorption feature observed in moderate resolution X-ray spectra of several Narrow Line Seyfert 1 galaxies can be explained by photoionization models, taking into account for resonance absorption, without requiring relativistic outflowing velocities of the gas, if the physical properties of these absorbers are close to those found in flat X-ray spectrum Seyfert 1 galaxies.Comment: 22 pages, 10 figures. Accepted for publication on Ap

Complex X-ray Absorption and the Fe Kalpha Profile in NGC 3516

We present data from simultaneous Chandra, XMM-Newton and BeppoSAX observations of the Seyfert 1 galaxy NGC 3516, taken during 2001 April and Nov. We have investigated the nature of the very flat observed X-ray spectrum. Chandra grating data show the presence of X-ray absorption lines, revealing two distinct components of the absorbing gas, one which is consistent with our previous model of the UV/X-ray absorber while the other, which is outflowing at a velocity of ~1100 km/s has a larger column density and is much more highly ionized. The broad-band spectral characteristics of the X-ray continuum observed with XMM during 2001 April, reveal the presence of a third layer of absorption consisting of a very large column (~2.5 x 10E23 cm^-2) of highly ionized gas with a covering fraction ~50%. This low covering fraction suggests that the absorber lies within a few lt-days of the X-ray source and/or is filamentary in structure. Interestingly, these absorbers are not in thermal equilibrium with one another. The two new components are too highly ionized to be radiatively accelerated, which we suggest is evidence for a hydromagnetic origin for the outflow. Applying our model to the Nov dataset, we can account for the spectral variability primarily by a drop in the ionization states of the absorbers, as expected by the change in the continuum flux. When this complex absorption is accounted for we find the underlying continuum to be typical of Seyfert 1 galaxies. The spectral curvature attributed to the high column absorber, in turn, reduces estimates of the flux and extent of any broad Fe emission line from the accretion disk.Comment: 33 pages, 9 figures, accepted for publication in Ap

The Casimir Effect for Parallel Plates Revisited

The Casimir effect for a massless scalar field with Dirichlet and periodic boundary conditions (b.c.) on infinite parallel plates is revisited in the local quantum field theory (lqft) framework introduced by B.Kay. The model displays a number of more realistic features than the ones he treated. In addition to local observables, as the energy density, we propose to consider intensive variables, such as the energy per unit area $\epsilon$, as fundamental observables. Adopting this view, lqft rejects Dirichlet (the same result may be proved for Neumann or mixed) b.c., and accepts periodic b.c.: in the former case $\epsilon$ diverges, in the latter it is finite, as is shown by an expression for the local energy density obtained from lqft through the use of the Poisson summation formula. Another way to see this uses methods from the Euler summation formula: in the proof of regularization independence of the energy per unit area, a regularization-dependent surface term arises upon use of Dirichlet b.c. but not periodic b.c.. For the conformally invariant scalar quantum field, this surface term is absent, due to the condition of zero trace of the energy momentum tensor, as remarked by B.De Witt. The latter property does not hold in tha application to the dark energy problem in Cosmology, in which we argue that periodic b.c. might play a distinguished role.Comment: 25 pages, no figures, late