Chemical modification of TiO2 surfaces with methylsilanes and characterization by infrared absorption spectroscopy

Infrared absorption spectra of methylsilanes bonded to a TiO2 powder were obtained. The reacting silanes include Me sub (4-n)SiX sub n (n=1-4; X=Cl, OMe) and hexamethyldisilazane (HMDS). Reactions were performed on hydroxylated-but-anhydrous TiO2 surfaces in the gas phase. IR spectra confirm the presence of a bonded silane layer. Terminal surface OH groups are found to react more readily than bridging OH groups. By-products of the modification adsorp tenaciously to the surface. The various silanes show only small differences in their ability to sequester surface OH groups. Following hydrolysis in moist air, Si-OH groups are observed only for the tetrafunctional silanes

The Importance of Teaching Techniques to Improve Cognitive Processes in Interpreting Courses

Oral translation or interpreting has always been understood as a task involvedwith high proficiency in two languages or a superior form of bilingualism practiced.This study aims at identifying the importance of studying human cognitive processesoperational in language interpreting, especially in the process of training interpreters.During the study, it has been identified that many of the interpreting courses, theirtrainers and amateur interpreters have overlooked the role of cognitive processesnamely, attention, memory, speech perception, comprehension and speech productionduring the course of interpreting. The main objective of the study is to challenge thecurrent point of view of the interpreters and trainers that the language proficiency is theutmost need of a good interpreter. The study puts forward the question whether efficientbilinguals / translators can still go wrong in their interpretations and what are theunderlying causes for the errors and omissions made by them. In carrying out this study,a sample of 15 undergraduates who had offered translation methods as a core subject fortheir B.A. degree at the University of Kelaniya were tested for the errors and omissionsthey made during interpreting tasks. By comparing the results of two interpretingattempts and a translation, the relationship between the cognitive factors andinterpreting is emphasized given the fact that for most of the errors and omissions, thecognitive intrusions could have influenced. Several techniques are suggested to be usedin future interpreting-training in order to enhance the quality of interpreting. Thefindings of this study aim at delivering ideas for future research in this line by applyingthese methods introduced.Key words: Interpretin, Cognitive processes, Attention, Memory, Interpreters

Globular cluster population of the HST frontier fields galaxy J07173724+3744224

We present the first measurement of the globular cluster population surrounding the elliptical galaxy J07173724+3744224 (z=0.1546). This galaxy is located in the foreground in the field-of-view of the Hubble Space Telescope (HST) Frontier Fields observations of galaxy cluster MACS J0717.5+3745 (z=0.5458). Based on deep HST ACS F435W, F606W, and F814W images, we find a total globular cluster population of N_tot = 3441 +/- 1416. Applying the appropriate extinction correction and filter transformation from ACS F814W to the Johnson V-band, we determine that the host galaxy has an absolute magnitude of M_V = -22.2. The specific frequency was found to be S_N = 4.5 +/- 1.8. The radial profile of the globular cluster system was best fit using a powerlaw of the form $\sigma\sim R^{-0.6}$, with the globular cluster population found to be more extended than the halo light of the host galaxy ($\sigma_{halo}\sim R^{-1.7}$). The F435W-F814W colour distribution suggests a bimodal population, with red globular clusters 1-3x more abundant than blue clusters. These results are consistent with the host elliptical galaxy J07173724+3744224 having formed its red metal-rich GCs in situ, with the blue metal-poor globular clusters accreted from low-mass galaxies.Comment: 21 pages, 14 figures, 2 tables, revised following peer-review, accepted for publication in MNRA

Microbiological quality of raw milk attributable to prolonged refrigeration conditions

Refrigerated storage of raw milk is a prerequisite in dairy industry. However, temperature abused conditions in the farming and processing environments can significantly affect the microbiological quality of raw milk. Thus, the present study investigated the effect of different refrigeration conditions such as 2, 4, 6, 8, 10 and 12 °C on microbiological quality of raw milk from three different dairy farms with significantly different initial microbial counts. The bacterial counts (BC), protease activity (PA), proteolysis (PL) and microbial diversity in raw milk were determined during storage. The effect of combined heating (75 ± 0·5 °C for 15 s) and refrigeration on controlling those contaminating microorganisms was also investigated. Results of the present study indicated that all of the samples showed increasing BC, PA and PL as a function of temperature, time and initial BC with a significant increase in those criteria ≥6 °C. Similar trends in BC, PA and PL were observed during the extended storage of raw milk at 4 °C. Both PA and PL showed strong correlation with the psychrotrophic proteolytic count (PPrBC: at ≥4 °C) and thermoduric psychrotrophic count (TDPC: at ≥8 °C) compared to total plate count (TPC) and psychrotrophic bacterial count (PBC), that are often used as the industry standard. Significant increases in PA and PL were observed when PPrBC and TDPC reached 5 × 104cfu/ml and 1 × 104cfu/ml, and were defined as storage life for quality (SLQ), and storage life for safety (SLS) aspects, respectively. The storage conditions also significantly affected the microbial diversity, wherePseudomonas fluorescensandBacillus cereuswere found to be the most predominant isolates. However, deep cooling (2 °C) and combination of heating and refrigeration (≤4 °C) significantly extended theSLQandSLsof raw milk.</jats:p

The use of transient electro-magnetism method to localize saline water intrusion in Sri Lanka

On the east coast of Sri Lanka, groundwater resources mainly consist in coastal aquifers, which are exploited for both irrigation and domestic purposes. In case of an intensive exploitation, saline water intrusions can occur, which make the water in wells improper for consumption. Considering the future resettlements of internally displaced families in coastal areas, and in order to evaluate the potential of these coastal aquifers (before launching a well implementation program), one need to locate the extent of this saline water intrusion. This information can be obtained by intrusive means such as piezometers monitoring, or non-intrusive means with geophysical methods. Transient Electro Magnetism (TEM) method has been used on different coastal sites on the east coast of Sri Lanka and has given good results for estimating the aquifers geometrical parameters. This first study will be followed by a more complete geophysical survey involving other methods

Submerged turbulence detection with optical satellites

During fall periods in 2002, 2003 and 2004 three major oceanographic expeditions were carried out in Mamala Bay, Hawaii. These were part of the RASP Remote Anthropogenic Sensing Program. Ikonos and Quickbird optical satellite images of sea surface glint revealed ~100 m spectral anomalies in km^2 averaging patches in regions leading from the Honolulu Sand Island Municipal Outfall diffuser to distances up to 20 km. To determine the mechanisms behind this phenomenon, the RASP expeditions monitored the waters adjacent to the outfall with an array of hydrographic, optical and turbulence microstructure sensors in anomaly and ambient background regions. Drogue tracks and mean turbulence parameters for 2x10^4 microstructure patches were analyzed to understand complex turbulence, fossil turbulence and zombie turbulence near-vertical internal wave transport processes. The dominant mechanism appears to be generic to stratified natural fluids including planet and star atmospheres and is termed beamed zombie turbulence maser action (BZTMA). Most of the bottom turbulent kinetic energy is converted to ~100 m fossil turbulence waves. These activate secondary (zombie) turbulence in outfall fossil turbulence patches that transmit heat, mass, chemical species, momentum and information vertically to the sea surface for detection in an efficient maser action. The transport is beamed in intermittent mixing chimneys.Comment: 8 pages, 7 figures, SPIE Optics+Photonics 2007 Coastal Ocean Remote Sensing Aug. 27, San Diego, CA, see http://sdcc3.ucsd.edu/~ir11

Star formation in low-redshift cluster dwarf galaxies

Evolution of galaxies in dense environments can be affected by close encounters with neighbouring galaxies and interactions with the intracluster medium. Dwarf galaxies (dGs) are important as their low mass makes them more susceptible to these effects than giant systems. Combined luminosity functions (LFs) in the r and u band of 15 galaxy clusters were constructed using archival data from the Canada–France–Hawaii Telescope. LFs were measured as a function of clustercentric radius from stacked cluster data. Marginal evidence was found for an increase in the faint-end slope of the u-band LF relative to the r-band with increasing clustercentric radius. The dwarf-to-giant ratio (DGR) was found to increase toward the cluster outskirts, with the u-band DGR increasing faster with clustercentric radius compared to the r-band. The dG blue fraction was found to be ∼2 times larger than the giant galaxy blue fraction over all clustercentric distance (∼5σ level). The central concentration (C) was used as a proxy to distinguish nucleated versus non-nucleated dGs. The ratio of high-C to low-C dGs was found to be ∼2 times greater in the inner cluster region compared to the outskirts (2.8σ level). The faint-end slope of the r-band LF for the cluster outskirts (0.6 ≤ r/r200 \u3c 1.0) is steeper than the Sloan Digital Sky Survey field LF, while the u-band LF is marginally steeper at the 2.5σ level. Decrease in the faint-end slope of the r- and u-band cluster LFs towards the cluster centre is consistent with quenching of star formation via ram pressure stripping and galaxy–galaxy interactions

Using Coded Excitation to maintain Signal to Noise for FMC+TFM on Attenuating Materials

Ultrasonic Non-Destructive Evaluation using Full Matrix Capture (FMC) and Total Focusing Method (TFM) is used for high resolution imaging as every pixel is in optimal focus. FMC excites one element in turn, so operates with lower transmitted energy compared to phased array beamforming. The energy at a reflector is further reduced by the broad directivity pattern of the single element. The large number of Tx/Rx A-scans that contribute to each pixel recover the Signal-to-Noise Ratio (SNR) in the final TFM image. Maintaining this in the presence of attenuating materials is a challenge because relevant information in each A-scan signal is buried in the thermal noise, and the TFM process assumes no quantization effects in the Analogue-to-Digital Converters (ADCs) in each receiver. In-process inspection during Additive Manufacturing (AM) requires ultrasonic array sensors that can tolerate high temperatures, scan over rough surfaces and leave no residue. Dry-coupled wheel probes are a solution, but the tire rubbers are often highly attenuating, causing a problem for FMC+TFM needed to adapt the focus through the rough surface. Common approaches to maintain the SNR are to drop the frequency or to average over multiple transmissions, but these compromise resolution and acquisition rate respectively. In this paper, the application of coded excitation to maintain the SNR in the presence of high signal attenuation is explored

MIMO Visible Light Communications Using a Wide Field-of-View Fluorescent Concentrator

This letter reports a demonstration of a 2 x 2 multiple-input multiple-output (MIMO) indoor visible-light communication (VLC) system using a novel fluorescent optical concentrator-based receiver. This potentially allows a high degree of spatial multiplexing to be achieved using a simple receiver structure that can have a wide field-of-view. Details of a two-channel MIMO VLC system that operates at 32 Mb/s with a receiver acceptance angle of ±22.5° are given, and future directions are discussed.PostprintPeer reviewe