Tides in northern Adriatic Sea - the Gulf of Trieste

The effects of tides in the northern Adriatic Sea were examined using the 2D finite-difference model. The Eulerian residual velocity field of the calibrated model was checked for the mixing efficiency of tides in the northern Adriatic Sea. It is shown through the simulation of tides for the period of one half year that tides are too weak to mix the whole water column (at any time within this period), even in front of the promontories (e.g. the Po river outlet). The model resolution (556 m) allowed analysis of the tidal dynamics in smaller regions. In the Gulf of Trieste the model results are in satisfactory agreement with the current-meter observations for winter 1984-85 and spring 1985. It is shown that in the middle of the entrance to the gulf the sense of rotation of the tidal ellipse vector changes from a clockwise rotation at the southern part of the entrance to an anticlockwise rotation at the northern part of entrance. Tidal currents in the interior of the gulf rotate counterclockwise, while in small bays, and in front of them, the rotation is clockwise

Simulating biomass assimilation in a Mediterranean ecosystem model using SOFA: setup and identical twin experiments

Assessing the potential improvement of basin scale ecosystem forecasting for the Mediterranean Sea requires biochemical data assimilation techniques. To this aim, a feasibility study of surface biomass assimilation is performed following an identical twin experiment approach. NPZD ecosystem data generator, embedded in one eighth degree general circulation model, is integrated with the reduced-order optimal interpolation System for Ocean Forecasting and Analysis. <P> The synthetic &quot;sea-truth&quot; data are winter daily averages obtained from the control run (CR). The twin experiments consist in performing two runs: the free run (FR) with summer-depleted phytoplankton initial conditions and the assimilated run (AR), in which, starting from the same FR phytoplankton concentrations, weekly surface biomasses averaged from the CR data are assimilated. The FR and AR initial conditions modify the winter bloom state of the phytoplankton all over the basin and reduce the total nitrogen, i.e.&nbsp;the energy of the biochemical ecosystem. <P> The results of this feasibility study shows good performance of the system in the case of phytoplankton, zooplankton, detritus and surface inorganic nitrogen. The weak results in the case of basin inorganic nitrogen and total nitrogen, the latter nonperformant at surface, are discussed

Reduced-order optimal interpolation for biomass assimilation

International audienceThe analysis of the evolution of the chemical and biological characteristics of the Mediterranean marine ecosystem requires an integrated approach. Consistently, an ecosystem description, embedded in the MFSTEP one eighth degree three-dimensional general circulation model, is tested and used following a twin experiment approach. The ecosystem model is based on the NPZD trophic chain: inorganic nitrogen, N, phytoplankton, P, zooplankton, Z and detritus, D. Assimilation of synthetic biomass data is performed by means of the reduced-order optimal interpolation system SOFA. The synthetic "sea-truth" data are daily averages obtained from a sixty-nine days reference run (RR). The twin experiments consist in performing two runs: a free run (FR) with wrong summer-depleted phytoplankton initial conditions and an assimilated run (AR), in which, starting from the same FR wrong phytoplankton concentrations, weekly averaged surface biomasses extracted from the RR results are assimilated. The comparison of the FR results with the AR ones shows a good convergence, on a basin Mediterranean scale, confirming improvements of the forecasting in each of the four ecological compartments. Regional trophic regimes are analysed and interpreted in the western and eastern Mediterranean subbasins, for explaining the deteriorating behaviour of the total nitrogen

Circular dichroism and 1H NMR studies of Co2+- and Ni2+-substituted concanavalin A and the lentil and pea lectins.

Visible absorption, circular dichroism (CD) and magnetic circular dichroism spectra have been recorded for the Ca2+-Co2+ derivatives of the lentil (CCoLcH) and pea (CCoPSA) lectins (Co2+ at the S1 sites and Ca2+ at the S2 sites) and shown to be very similar for both proteins. The visible absorption and magnetic circular dichroism spectra indicate similar octahedral geometries for high spin Co2+ at S1 in both proteins, as found in the Ca2+-Co2+ complex of concanavalin A (CCoPL) (Richardson, C. E., and Behnke, W. D. (1976) J. Mol. Biol. 102, 441-451). The visible CD data, however, indicate differences in the environment around S1 of CCoLcH and CCoPSA compared to CCoPL. 1H NMR spectra at 90 MHz of the Co2+ and Ni2+ derivatives of the lectins show a number of isotropically shifted signals which arise from protons in the immediate vicinity of the S1 sites. Analysis of the spectra of the Co2+ derivatives in H2O and D2O has permitted resonance assignments of the side chain ring protons of the coordinated histidine at S1 in the lectins. Differences are observed in the H-D exchange rate of the histidine NH proton at S1 in concanavalin A compared to the lentil and pea lectins. NMR data of the Ni2+-substituted proteins, together with spectra of the Co2+ derivatives, also indicate that the side chains of a carboxylate ligand and of the histidine residue at S1 are positioned differently in concanavalin A than in the other two lectins. These results appear to account, in part, for the differences observed in the visible CD spectra of the Co2+-substituted proteins. In addition, binding of monosaccharides does not significantly perturb the spectra of the lectins. An unusual feature in the 1H NMR spectra of all three Co2+-substituted lectins is the presence of two exchangeable downfield shifted resonances which appear to be associated with the two protons of a slowly exchanging water molecule coordinated to the Ca2+ ion at S2. T1 measurements of CCoLcH have provided an estimation of the distances from the Co2+ ion to these two protons of 3.7 and 4.0 A

Water column monitoring at CO2 leaking sites near Panarea Island

The fate and transport of geologically produced CO2 that leaks from the sea floor into the overlying water column has numerous important implications related to large scale carbon cycling and potential impact on marine organisms, and is of interest for the development of improved monitoring techniques and strategies for offshore Carbon Capture and Storage (CCS) sites. The CO2 leakage areas off the east coast of Panarea Island, Italy provides an excellent environment to study these processes given the wide range of different flux rates in relatively shallow water. The water column at this site was monitored using two completely different but complementary approaches, continuous monitoring along short 2D transects using GasPro pCO2 sensors and discrete seasonal sampling along a 700 m transect crossing multiple leakage areas. Results are discussed in terms of the movement of CO2, and associated tracers, in the water column

Recent AEM Case Study Examples of a Full Waveform Time-Domain System for Near-Surface and Groundwater Applications

Early time or high frequency airborne electromagnetic data (AEM) are desirable for shallow sounding or mapping of resistive areas but this poses difficulties due to a variety of issues, such as system bandwidth, system calibration and parasitic loop capacitance. In an effort to address this issue, a continued system design strategy, aimed at improving its early-channel VTEM data, has achieved fully calibrated, quantitative measurements closer to the transmitter current turn-off, while maintaining reasonably optimal deep penetration characteristics. The new design implementation, known as “Full Waveform” VTEM was previously described by Legault et al. (2012). This paper presents some case-study examples of a Full Waveform helicopter time-domain EM system for near-surface application