15 research outputs found
NMR saturation transfer and line shape analyses of cyclic tetradepsipeptide AM toxin II Conformational equilibrium with very unequal populations
Get PDFLarge-scale animal model study uncovers altered brain pH and lactate levels as a transdiagnostic endophenotype of neuropsychiatric disorders involving cognitive impairment
Get PDFLiver progenitor cells may construct cysts having heterogeneous gene expression of liver-enriched transcription factors in mice with conditional knockout of the Hhex gene
No full textautho
Ruthenium-Catalyzed Transformation of Aryl and Alkenyl Triflates to Halides
No full textAryl triflates were transformed to aryl bromides/iodides
simply
by treating them with LiBr/NaI and [Cp*RuÂ(MeCN)<sub>3</sub>]ÂOTf. The
ruthenium complex also catalyzed the transformation of alkenyl sulfonates
and phosphates to alkenyl halides under mild conditions. Aryl and
alkenyl triflates undergo oxidative addition to a rutheniumÂ(II) complex
to form η<sup>1</sup>-arylruthenium and 1-ruthenacyclopropene
intermediates, respectively, which are transformed to the corresponding
halides
Quantitative structure-activity studies of insect growth regulators, XVI : substituent effects of dibenzoylhydrazines on the insecticidal activity to Colorado potato beetle Leptinotarsa decemlineata
No full textRuthenium-Catalyzed Transformation of Aryl and Alkenyl Triflates to Halides
No full textAryl triflates were transformed to aryl bromides/iodides
simply
by treating them with LiBr/NaI and [Cp*RuÂ(MeCN)<sub>3</sub>]ÂOTf. The
ruthenium complex also catalyzed the transformation of alkenyl sulfonates
and phosphates to alkenyl halides under mild conditions. Aryl and
alkenyl triflates undergo oxidative addition to a rutheniumÂ(II) complex
to form η<sup>1</sup>-arylruthenium and 1-ruthenacyclopropene
intermediates, respectively, which are transformed to the corresponding
halides
