Mechanochemical bottom-up synthesis of phosphorus-linked, heptazine-based carbon nitrides using sodium phosphide

Herein, we present the bottom-up, mechanochemical synthesis of phosphorus-bridged heptazine-based carbon nitrides (g-h-PCN). The structure of these materials was determined through a combination of powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), 31P magic angle spinning nuclear magnetic resonance (MAS NMR), density functional theory (DFT) and electron energy loss spectroscopy (EELS). Compared to traditional furnace-based techniques, the presented method utilizes milder conditions, as well as shorter reaction times. Both samples of g-h-PCN directly after milling and aging and after an hour of annealing at 300 °C (g-h-PCN300) show a reduction in photoluminescent recombination, as well as a nearly two-time increase in photocurrent under broad spectrum irradiation, which are appealing properties for photocatalysis

HIV-Associated TB in An Giang Province, Vietnam, 2001–2004: Epidemiology and TB Treatment Outcomes

BACKGROUND: Mortality is high in HIV-infected TB patients, but few studies from Southeast Asia have documented the benefits of interventions, such as co-trimoxazole (CTX), in reducing mortality during TB treatment. To help guide policy in Vietnam, we studied the epidemiology of HIV-associated TB in one province and examined factors associated with outcomes, including the impact of CTX use. METHODOLOGY/PRINCIPAL FINDINGS: We retrospectively abstracted data for all HIV-infected persons diagnosed with TB from 2001-2004 in An Giang, a province in southern Vietnam in which TB patients receive HIV counseling and testing. We used standard WHO definitions to classify TB treatment outcomes. We conducted multivariate analysis to identify risk factors for the composite outcome of death, default, or treatment failure during TB treatment. From 2001-2004, 637 HIV-infected TB patients were diagnosed in An Giang. Of these, 501 (79%) were male, 321 (50%) were aged 25-34 years, and the most common self-reported HIV risk factor was sex with a commercial sex worker in 221 (35%). TB was classified as smear-positive in 531 (83%). During TB treatment, 167 (26%) patients died, 9 (1%) defaulted, and 6 (1%) failed treatment. Of 454 patients who took CTX, 116 (26%) had an unsuccessful outcome compared with 33 (70%) of 47 patients who did not take CTX (relative risk, 0.4; 95% confidence interval [CI], 0.3-0.5). Adjusting for male sex, rural residence, TB smear status and disease location, and the occurrence of adverse events during TB treatment in multivariate analysis, the benefit of CTX persisted (adjusted odds ratio for unsuccessful outcome 0.1; CI, 0.1-0.3). CONCLUSIONS/SIGNIFICANCE: In An Giang, Vietnam, HIV-associated TB was associated with poor TB treatment outcomes. Outcomes were significantly better in those taking CTX. This finding suggests that Vietnam should consider applying WHO recommendations to prescribe CTX to all HIV-infected TB patients

Influence de la preparation sur la segregation metallique dans les catalyseurs bimetalliques de reformage a base de platine et rhenium supportes par silice, oxyde de titane et alumine

SIGLECNRS T Bordereau / INIST-CNRS - Institut de l'Information Scientifique et TechniqueFRFranc

Editorial: Special Issue on “Emerging Trends in TiO2 Photocatalysis and Applications”

It is not an exaggerated fact that the semiconductor titanium dioxide (TiO2) has been evolved as a prototypical material to understand the photocatalytic process and has been demonstrated for various photocatalytic applications such as pollutants degradation, water splitting, heavy metal reduction, CO2 conversion, N2 fixation, bacterial disinfection, etc [...

Comprehensive Review for an Efficient Charge Transfer in Single Atomic Site Catalyst/Organic Polymers toward Photocatalytic CO2 Reduction

Abstract Single atomic site catalyst/organic polymers hybrid photocatalyst has been demonstrated as a potential material for photocatalytic CO2 reduction that can solve both environmental and energy issues simultaneously. The charge migration and transfer between organic polymers and single atomic site catalysts are attributed to the high performance of the hybrid material. In this review, two typical charge transfers between the single atomic site catalyst and organic polymer‐based semiconductor, namely intermolecular electron transfer and intramolecular electron transfer, are discussed. Typical single‐atomic site catalysts, organic polymers, and methods are first reviewed for the fabrication of hybrid systems. Why intramolecular electron transfer between the single atomic site catalyst and organic polymers exhibits higher photocatalytic activity than intermolecular electron transfer is also discussed. Finally, the critical challenges in fabricating these hybrid photocatalysts toward an efficient photocatalytic CO2 reduction are highlighted, and propose solutions to these challenges

Emerging Hybrid Nanocomposite Photocatalysts for the Degradation of Antibiotics: Insights into Their Designs and Mechanisms

The raising occurrence of antibiotics in the global water bodies has received the emerging concern due to their potential threats of generating the antibiotic-resistive and genotoxic effects into humans and aquatic species. In this direction, the solar energy assisted photocatalytic technique offers a promising solution to address such emerging concern and paves ways for the complete degradation of antibiotics with the generation of less or non-toxic by-products. Particularly, the designing of hybrid photocatalyticcomposite materials has been found to show higher antibiotics degradation efficiencies. As the hybrid photocatalysts are found as the systems with ideal characteristic properties such as superior structural, surface and interfacial properties, they offer enhanced photoabsorbance, charge-separation, -transfer, redox properties, photostability and easy recovery. In this context, this review study presents an overview on the recent developments in the designing of various hybrid photocatalytic systems and their efficiency towards the degradation of various emerging antibiotic pharmaceutical contaminants in water environments

Insights into the Recent Progress and Advanced Materials for Photocatalytic Nitrogen Fixation for Ammonia (NH₃) Production

Ammonia (NH3) is one of the key agricultural fertilizers and to date, industries are using the conventional Haber-Bosh process for the synthesis of NH3 which requires high temperature and energy. To overcome such challenges and to find a sustainable alternative process, researchers are focusing on the photocatalytic nitrogen fixation process. Recently, the effective utilization of sunlight has been proposed via photocatalytic water splitting for producing green energy resource, hydrogen. Inspired by this phenomenon, the production of ammonia via nitrogen, water and sunlight has been attracted many efforts. Photocatalytic N2 fixation presents a green and sustainable ammonia synthesis pathway. Currently, the strategies for development of efficient photocatalyst for nitrogen fixation is primarily concentrated on creating active sites or loading transition metal to facilitate the charge separation and weaken the N⁻N triple bond. In this investigation, we review the literature knowledge about the photocatalysis phenomena and the most recent developments on the semiconductor nanocomposites for nitrogen fixation, following by a detailed discussion of each type of mechanism