3,531 research outputs found
Optical constants of silicon carbide for astrophysical applications. II. Extending optical functions from IR to UV using single-crystal absorption spectra
Laboratory measurements of unpolarized and polarized absorption spectra of
various samples and crystal stuctures of silicon carbide (SiC) are presented
from 1200--35,000 cm ( 8--0.28 m) and used to improve
the accuracy of optical functions ( and ) from the infrared (IR) to the
ultraviolet (UV). Comparison with previous 6--20 m
thin-film spectra constrains the thickness of the films and verifies that
recent IR reflectivity data provide correct values for in the IR region. We
extract and needed for radiative transfer models using a new
``difference method'', which utilizes transmission spectra measured from two
SiC single-crystals with different thicknesses. This method is ideal for
near-IR to visible regions where absorbance and reflectance are low and can be
applied to any material. Comparing our results with previous UV measurements of
SiC, we distinguish between chemical and structural effects at high frequency.
We find that for all spectral regions, 3C (-SiC) and the polarization of 6H (a type of -SiC) have almost identical
optical functions that can be substituted for each other in modeling
astronomical environments. Optical functions for of 6H SiC
have peaks shifted to lower frequency, permitting identification of this
structure below m. The onset of strong UV absorption for pure
SiC occurs near 0.2 m, but the presence of impurities redshifts the rise
to 0.33 m. Optical functions are similarly impacted. Such large
differences in spectral characteristics due to structural and chemical effects
should be observable and provide a means to distinguish chemical variation of
SiC dust in space.Comment: 46 pages inc. 8 figures and 2 full tables. Also 6 electronic-only
data files. Accepted by Ap
The SiC problem: astronomical and meteoritic evidence
Pre-solar grains of silicon carbide found in meteorites and interpreted as
having had an origin around carbon stars from their isotopic composition, have
all been found to be of the beta-SiC polytype. Yet to date fits to the 11.3
microns SiC emission band of carbon stars had been obtained only for alpha-SiC
grains. We present thin film infrared (IR) absorption spectra measured in a
diamond anvil cell for both the alpha- and beta- polymorphs of synthetic SiC
and compare the results with previously published spectra taken using the KBr
matrix method. We find that our thin film spectra have positions nearly
identical to those obtained previously from finely ground samples in KBr.
Hence, we show that this discrepancy has arisen from inappropriate `KBr
corrections' having been made to laboratory spectra of SiC particles dispersed
in KBr matrices. We re-fit a sample of carbon star mid-IR spectra, using
laboratory data with no KBr correction applied, and show that beta-SiC grains
fit the observations, while alpha-SiC grains do not. The discrepancy between
meteoritic and astronomical identifications of the SiC-type is therefore
removed. This work shows that the diamond anvil cell thin film method can be
used to produce mineral spectra applicable to cosmic environments without
further manipulation.Comment: to be published in Astrophysical Journal Letter 4 pages, 3 figure
Optical properties of silicon carbide for astrophysical applications I. New laboratory infrared reflectance spectra and optical constants
Silicon Carbide (SiC) optical constants are fundamental inputs for radiative
transfer models of astrophysical dust environments. However, previously
published values contain errors and do not adequately represent the bulk
physical properties of the cubic (beta) SiC polytype usually found around
carbon stars. We provide new, uncompromised optical constants for beta- and
alpha-SiC derived from single-crystal reflectance spectra and investigate
quantitatively whether there is any difference between alpha- and beta-SiC that
can be seen in infrared spectra and optical functions.
Previous optical constants for SiC do not reflect the true bulk properties,
and they are only valid for a narrow grain size range. The new optical
constants presented here will allow narrow constraints to be placed on the
grain size and shape distribution that dominate in astrophysical environments.
In addition, our calculated absorption coefficients are much higher than
laboratory measurements, which has an impact on the use of previous data to
constrain abundances of these dust grains.Comment: 12 pages; 10 figures; laboratory optical constants available from
CDS. Accepted by Astronomy & Astrophysic
Characterizing Potentials by a Generalized Boltzmann Factor
Based on the concept of a nonequilibrium steady state, we present a novel
method to experimentally determine energy landscapes acting on colloidal
systems. By measuring the stationary probability distribution and the current
in the system, we explore potential landscapes with barriers up to several
hundred \kT. As an illustration, we use this approach to measure the
effective diffusion coefficient of a colloidal particle moving in a tilted
potential
On the hyperbolicity and causality of the relativistic Euler system under the kinetic equation of state
We show that a pair of conjectures raised in [11] concerning the construction
of normal solutions to the relativistic Boltzmann equation are valid. This
ensures that the results in [11] hold for any range of positive temperatures
and that the relativistic Euler system under the kinetic equation of state is
hyperbolic and the speed of sound cannot overcome .Comment: 6 pages. Abridged version; full version to appear in Commun. Pure
Appl. Ana
Measurement of Stochastic Entropy Production
Using fluorescence spectroscopy we directly measure entropy production of a
single two-level system realized experimentally as an optically driven defect
center in diamond. We exploit a recent suggestion to define entropy on the
level of a single stochastic trajectory (Seifert, Phys. Rev. Lett. {\bf 95},
040602 (2005)). Entropy production can then be split into one of the system
itself and one of the surrounding medium. We demonstrate that the total entropy
production obeys various exact relations for finite time trajectories.Comment: Phys. Rev. Lett., in pres
- …