15 research outputs found
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Crystal structure of (E)-undec-2-enoic acid
In the molecule of the title low-melting [alpha],[beta]-unsaturated carboxylic acid, C11H20O2, the least-squares mean line through the octyl chain forms an angle of 60.10 (13)° with the normal to plane of the acrylic acid fragment (r.m.s. deviation = 0.008 Å). In the crystal, centrosymmetrically related molecules are linked by pairs of O-H...O hydrogen bonds into dimers, forming layers parallel to the (041) plane
Crystal structure of (E)-pent-2-enoic acid
The molecule of the title compound, C5H8O2, a low-melting [alpha],[beta]-unsaturated carboxylic acid, is essentially planar [maximum displacement = 0.0239 (13) Å]. In the crystal, molecules are linked into centrosymmetric dimers via pairs of O-H...O hydrogen bonds
Regioselective Suzuki–Miyaura Cross-Coupling Reactions of the Bis(triflate) of 1,4-Dihydroxy-9H-fluoren-9-one
1,4-Diaryl-9H-fluoren-9-ones were prepared by regioselective Suzuki–Miyaura cross-coupling reaction of the bis(triflate) of 1,4-dihydroxy-9H-fluoren-9-one. The reactions proceeded with excellent site selectivity. The first attack occurs at position 1, due to electronic reason
Synthesis and Molecular Structures of (E)-non-2-enoic Acid and (E)-dec-2-enoic Acid
The molecular structures of (E)-non-2-enoic acid (C9) and (E)-dec-2-enoic acid (C10) are reported. The title compounds were crystallized by slow evaporation of ethanolic solutions at −30 °C. C9 crystallizes in the monoclinic space group P21/c and C10 in the triclinic space group P-1, each with 4 molecules in the unit cell. The unit cell parameters for C9 are: a = 10.6473(4) Å, b = 5.2855(2) Å, c = 17.0313(7) Å; β = 106.0985(10)° and V = 920.87(6) Å3. The unit cell parameters for C10 are: a = 4.1405(2) Å, b = 15.2839(6) Å, c = 17.7089(7) Å; α = 68.3291(11)°, β = 83.3850(13)°, γ = 85.0779(12)° and V = 1033.39(8) Å3
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Crystal structure of (E)-dodec-2-enoic acid
The crystal structure of (E)-dodec-2-enoic acid, C12H22O2, an [alpha],[beta]-unsaturated carboxylic acid with a melting point (295 K) near room temperature, is characterized by carboxylic acid inversion dimers linked by pairs of O-H...O hydrogen bonds. The carboxylic acid group and the following three carbon atoms of the chain of the (E)-dodec-2-enoic acid molecule lie almost in one plane (r.m.s. deviation for the four C atoms and two O atoms = 0.012 Å), whereas the remaining carbon atoms of the hydrocarbon chain adopt a nearly fully staggered conformation [moduli of torsion angles vary from 174.01 (13) to 179.97 (13)°]
Synthesis and Molecular Structures of the Lowest Melting Odd- and Even-Numbered α,β-Unsaturated Carboxylic Acids—(E)-Hept-2-Enoic Acid and (E)-Oct-2-Enoic Acid
The molecular structures of the two lowest melting odd- and even-numbered α,β-unsaturated carboxylic acids—(E)-hept-2-enoic acid (C7) and (E)-oct-2-enoic acid (C8)—are herein reported. The title compounds were crystallized by slow evaporation of ethanolic solutions at −30 °C. C7 crystallizes in the triclinic space group P 1 ¯ with two molecules in the unit cell and C8 in the monoclinic space group C2/c with eight molecules in the unit cell. The unit cell parameters for C7 are: a = 5.3049(2) Å, b = 6.6322(3) Å, c = 11.1428(5) Å, α = 103.972(3)°, β = 97.542(3)°, γ = 90.104(3)°, and V = 376.92(3) Å3 (T = 150(2) K). The unit cell parameters for C8 are: a = 19.032(10) Å, b = 9.368(5) Å, c = 11.520(6) Å, β = 123.033(11)°, and V = 1721.80(16) Å3 (T = 200(2) K)
3-Ethylindan-1-one
The title compound, C11H12O, has been prepared as a side product in the attempted room-temperature synthesis of (E)-1-phenylpent-2-en-1-one. The molecular structure consists of an approximately planar indanone core (r.m.s. deviation = 0.042 Å) with the ethyl group protruding from this plane. In the crystal, centrosymmetrically related molecules are linked into dimers by pairs of C—H...O hydrogen bonds, forming rings of R22(10) graph-set motif. The dimers are further connected by C—H...π interactions into chains running parallel to [-101]
Crystal structure of (E)-hex-2-enoic acid
The crystal structure of the title compound, C6H10O2, an α,β-unsaturated carboxylic acid, displays carboxylic acid inversion dimers linked by pairs of O—H...O hydrogen bonds. The packing is characterized by layers of acid dimers. All the non-H atoms of the (E)-hex-2-enoic acid molecule lie almost in the same plane (r.m.s. deviation for the non-H atoms = 0.018 Å)
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Crystal structure of (E)-hex-2-enoic acid
The crystal structure of the title compound, C6H10O2, an [alpha],[beta]-unsaturated carboxylic acid, displays carboxylic acid inversion dimers linked by pairs of O-H...O hydrogen bonds. The packing is characterized by layers of acid dimers. All the non-H atoms of the (E)-hex-2-enoic acid molecule lie almost in the same plane (r.m.s. deviation for the non-H atoms = 0.018 Å)
Synthesis and Molecular Structures of (E)-non-2-enoic Acid and (E)-dec-2-enoic Acid
The molecular structures of (E)-non-2-enoic acid (C9) and (E)-dec-2-enoic acid (C10) are reported. The title compounds were crystallized by slow evaporation of ethanolic solutions at −30 °C. C9 crystallizes in the monoclinic space group P21/c and C10 in the triclinic space group P-1, each with 4 molecules in the unit cell. The unit cell parameters for C9 are: a = 10.6473(4) Å, b = 5.2855(2) Å, c = 17.0313(7) Å; β = 106.0985(10)° and V = 920.87(6) Å3. The unit cell parameters for C10 are: a = 4.1405(2) Å, b = 15.2839(6) Å, c = 17.7089(7) Å; α = 68.3291(11)°, β = 83.3850(13)°, γ = 85.0779(12)° and V = 1033.39(8) Å3