Water quality index in the high-andean micro-basin of the Chumbao river, Andahuaylas, Apurímac, Perú

The water quality index (WQI) of a water body, indicates the degree of contamination for a given use, and it is related to the anthropic activities that they provoke around. The objective was to determine the WQI, in the high-Andean micro-basin of the Chumbao River, Andahuaylas, Peru. The section of study was included between the head of the basin (13°46'42.5" S, 73°13'50.0" W and 4 295 m of altitude), and last sampling point (13°35'26.4" S, 73°27'0.8" W and 2 529 m of altitude), with an average slope of 4%. The WQI Dinius was evaluated considering parameters such as oxygen level (DO and BOD5), eutrophication level (NO3 - and PO4 3-), physical characteristics (temperature, turbidity, color and TDS), dissolved substances (alkalinity, hardness, pH, conductivity and chlorides), and microbiological parameters (E. coli and total coliforms); it was sampled during the avenues season (02 lentic points and 08 lotics). The data were collected in triplicate, and analyzed through an ANOVA, Tukey test and Pearson's correlation at 5% significance. It was found that the predominant use of river water is for agriculture, pasture and urbanization; the WQI is divided into three categories Excellent (M1, M2, M3, M4 and M5) close to the head of the micro-basin and the lentic points (Pampahuasi and Paccoccocha lagoons), Acceptable (M6), and excessively contaminated points M7 and M8 outside the urban area downstream (p-value < 0.05); presenting a good negative correlation with the study parameters. In conclusion, the water in areas of low population density is good

Capacidad floculante de coagulantes naturales en el tratamiento de agua

La coagulación es el proceso más importante en el tratamiento del agua, que incluye la remoción de especies en suspensión, mediante la adición de coagulantes químicos, cuyo uso trae desventajas asociadas a altos costos de adquisición, producción de grandes volúmenes de lodo y el hecho de que afectan el pH del agua tratada. Es así que el objetivo fue evaluar la capacidad floculante de tres variedades de Cactáceas Echinopsis pachanoi, Neoraimondia arequipensis y Opuntia ficus en el tratamiento de agua residual artificial. Se aplicaron dosis del 1 %, 2 % y 3 % de coagulante de las tres variedades de Cactáceas extraídas con los tres solventes al agua residual artificial, observándose un incremento significativo (p-value0,05), la DBO del agua con coagulante se incrementó con el porcentaje de aplicación

Cafeína y barrido UV-Vis y el índice de calidad de agua en la microcuenca altoandina del río Chumbao, Andahuaylas, Apurímac, Perú

Las fuentes de agua superficial son recursos para las actividades socioeconómicas, sin embargo estas causan alteración y deterioro, este impacto es medido por el índice de calidad del agua (ICA) y recientemente por contaminantes emergentes. El objetivo fue evaluar el nivel de cafeína y el ICA, en la micro cuenca altoandina del rio Chumbao, situada entre 73°38' - 73°11'O y 13°49' - 13°34'S, de 4 800 a 2 000 msnm y área 767,4 km2 . Se evaluó el ICA según la NSF y Dinius considerando parámetros: Nivel de oxigeno (OD y DBO5), Nivel de eutrofización (NO3- y PO4- ), Características físicas (Temperatura, Turbidez, Color y TDS), Sustancias disueltas (Alcalinidad, Dureza, pH, Conductividad y Cloruros), Aspectos de salud (E. coli y Coliformes); la cafeína se determinó por la cromatografía líquida de alta eficacia (HPLC); el muestreo fue en temporada de avenidas, en 02 puntos lénticos y 08 lóticos. Se encontró que el uso predominante del agua es para agricultura, pastura y urbanización; la microcuenca presenta pendientes de 5,4 % (18,3 km), 2,2 % (11,8 km) y 4,3 % (5,6 km), los parámetros muestran correlación Rs positiva (p-value < 0,05), superando los estándares de calidad para vida acuática en los puntos urbanizados. No se detectó niveles de cafeína (n.d.>1,09 μg/L). El ICA según NSF y Dinius muestra dos categorías Buena y Muy mala para puntos lóticos; y excelente para las lagunas de la cabecera de cuenca, estas características se evidenciaron por un barrido UV-Vis de 200 a 700 nm

Study of the pollution by surfactants in a river of a high Andean micro basin

The surfactants linear alkylbenzene sulfonate (LAS), is used in large quantities in modern society, and wastewater containing it can contaminate groundwaters through runoff and sewers. The study aimed to determine the level of LAS in the Huatanay river; in Cusco city, Peru. Water samples were taken from nine points along the river, in the rainy and dry season in 2018. LAS surfactants were determined spectrometrically using methylene blue as indicator; dissolved oxygen (DO) and conductivity were also determined; both were correlated through Pearson coefficient at 5% significance, and analyzed in triplicate. The concentration of LAS in the dry season varied between 0.01 to 23.17 mg/L and in rains from 0.09 to 1.47 mg/L; the DO level shows values between 0.11 to 5.04 mg O2/L, and the conductivity varied from 777.7 to 2688.9 µS/cm. In conclusion, high levels of LAS considerably decrease the DO and increase the conductivit

Proposal of a water-quality index for high andean basins: application to the Chumbao river, Andahuaylas, Peru

Thewater fromthe high Andean rivers is peculiar due to its composition and the geomorphology of its sources, and naturally or anthropogenically contamination is not discarded along its course. This water is used for agriculture and human consumption, therefore knowing its quality is important. This research aimed to proposing and formulate a water-quality index for high Andean basins through the Delphimethod, and its application in the Chumbao River located in Andahuaylas-Peru. Forty-three water-quality parameters were evaluated through the Delphi method, and the water-quality index (WQIHA) was formulated with a weighted average of the weights of the selected parameters, it was compared with the WQI Dinius. For this purpose, ten sampling points were considered along the Chumbao River located between 4274 and 2572 m of altitude and theWQIHA was applied. In addition, field and laboratory analyses were carried out in 2018, 2019, and 2021, in dry and rainy seasons. Twenty parameters were grouped in the physicochemical sub-index (SIPC), heavy metals sub-index (SIHM), and organic matter sub-index (SIOM). Each group contributed with weights of 0.30, 0.30, and 0.40, respectively, for theWQIHA formulation. The SIPC and SIOM showed that the areas near the head of the basin presented excellent and good quality, while the urbanized areas were qualified as marginal to poor; SIHM reported good quality in all points and seasons. Regarding the WQIHA, the index shows good quality in the zones above 3184 m of altitude, contrasting with poor quality downstream, decreasing notably in both seasons, suggesting continuous degradation of the water body

Residuos β-lactámicos y tetraciclinas en la leche fresca adquirida por Comités de Vaso de Leche de los distritos de San Jerónimo y Andahuaylas, Apurímac, Perú

The aim of this study was to evaluate the effect of the presence of residues of β- lactam antibiotics and tetracyclines, as well as the physicochemical properties of fresh milk acquired by the Glass of Milk Committees of two districts of Apurimac, Peru. Triplicate milk samples were analyzed from 37 and 32 committees in the districts of San Jerónimo and Andahuaylas respectively. Density, acidity, pH, total solids (TS) and alcohol test were determined and compared with the Peruvian Technical Standards (NTP) for fresh milk. The presence of β-lactam and tetracycline antibiotic compounds was determined through the Betastar® colorimetric kit. The physicochemical properties were correlated with the presence of antibiotics through the Pearson coefficient. A principal component analysis (PCA) was performed. Results showed that 10.8% of the milk samples from the San Jerónimo committees were positive for tetracycline, while 9.4 and 3.1% of the San Jerónimo and Andahuaylas committees, respectively, were positive for β-lactams. A high percentage of milk samples were outside the ranges established by the NTP for density, pH, acidity and TS. The PCA analysis shows that acidity and density are the main variables that would would determine the presence of antibiotics.El objetivo del trabajo fue evaluar el efecto de la presencia de residuos de antibióticos β-lactámicos y tetraciclinas, así como las propiedades fisicoquímicas de la leche fresca adquirida por los Comités de Vaso de Leche de dos distritos de Apurímac, Perú. Se analizaron muestras de leche por triplicado, provenientes de 37 y 32 comités de los distritos de San Jerónimo y Andahuaylas, respectivamente. Se determinaron las propiedades fisicoquímicas: densidad, acidez, pH, sólidos totales (ST) y prueba de alcohol, las cuales se compararon con las Normas Técnicas Peruanas (NTP) para leche fresca. La presencia de compuestos antibióticos β-lactámicos y tetraciclinas se determinó a través del kit colorimétrico Betastar®. Las propiedades fisicoquímicas se correlacionaron con la presencia de antibióticos a través del coeficiente de Pearson. Se realizó un análisis de componentes principales (ACP). El 10.8% de las muestras de leche provenientes de los comités de San Jerónimo fue positivo para tetraciclina, mientras que el 9.4 y 3.1% de los comités de San Jerónimo y Andahuaylas, respectivamente, fueron positivos para β- lactámicos. Un alto procentaje de las muestras de leche estuvieron fuera de los rangos establecidos por las NTP para densidad, pH, acidez y ST. Del análisis ACP se desprende que la acidez y la densidad son las principales variables que pemitirían determinar la presencia de antibioticos

Insights from Water Quality of High Andean Springs for Human Consumption in Perú

The headwaters of the high Andean basin in Peru accumulate water from the mist, rain, snow, and hail, and it is transported superficially and underground to low-lying areas, mostly used for drinkable purposes. The natural water in these areas might be altered due to legal and illegal mining extraction. The aim of the study was to evaluate the water quality for human consumption. Seventeen water samples were examined from Andahuaylas (A), San Jerónimo (S), Talavera (T), and Chiara (CH) districts located between 2813 and 4004 m altitude in the Andes. We used physic ochemical, microbiological, and metal parameters, and the results were compared to permissible levels established by the WHO and ECA-Peru to examine samples collected in the dry and rainy seasons in 2019. Application of principal component analysis (PCA) identified areas and conditioning parameters. Extractive mining activity influences the quality of springs due to the presence of metals, especially antimony (Sb), arsenic (As), cadmium (Cd), and lead (Pb), values of which are higher than values permissible for human consumption, being higher in the dry season (p < 0.05). In addition, the presence of cations and particulate matter affects physico-chemical parameters, for example turbidity. PCA showed that parameters for water characterization are season-independent, and water quality in the springs would be conditioned by the presence of metals, especially in Andahuaylas and Talavera zones, as well as the parameters that are associated with dissolved solids in the water (turbidity and fluorides). A frequent monitoring program of springs and groundwater is recommended, with the purpose to protect water from contamination and guarantee safe water availability in low-lying and urbanized areas

Optimization of the flocculating capacity of natural coagulants in water treatment

The objective was optimize the flocculating capacity of three varities of cacti Echinopsis pachanoi (San Pedro), Neoraimondia arequipenses (Ulluquite) and Opuntia ficus (Tuna) in the artificial wastewater treatment. They were applied 1%, 2% and 3% coagulant doses of the three varieties of cactaceae extracted with 96% ethanol. It was evaluated the flocculating activity (FA) and removal percentage (%R); a significant increase was observed (p-value < 0.05) with the increase in the coagulant dose. The optimization was carried out considering as objective function the %R which were subjected to FA, pH, hardness, alkalinity and BOD5 of water treatment. Which were reported values of 99.09 %R for San Pedro variety, 92.42 %R for Ulluquite variety and 98.98 %R for tuna variety, for doses of 0.207%, 0.246% and 0.754% of coagulant respectivelyEl objetivo del trabajo fue optimizar la capacidad floculante de tres variedades de Cactáceas Echinopsis pachanoi (San Pedro), Neoraimondia arequipensis (Ulluquite) y Opuntia ficus (Tuna) en el tratamiento de agua residual artificial. Se aplicaron dosis al 1%, 2% y 3% de coagulante de las tres variedades de cactáceas extraídas con etanol al 96%, se evaluó la actividad floculante (AF) y el porcentaje de remoción (%R), observándose incremento significativo (p-value < 0.05) con el aumento de dosis de los coagulantes. La optimización se realizó considerando como función objetivo el %R sujetas a las restricciones para AF, pH, Dureza, Alcalinidad y DBO5 del agua tratada, reportándose valores de 99.09 %R para la variedad San Pedro, 92.42 %R para la variedad Ulluquite y 98.98 %R para la variedad Tuna, para dosis de 0.207%, 0.246% y 0.754% de coagulante respectivament

Drying and color in punamuña leaves (Satureja boliviana)

Drying allows water to be removed and food to be preserved, however, this operation can degrade color. Punamuña leaves are aromatic and used for medicinal purposes in the Peruvian Andes. This research aimed to determine and model the drying kinetics, the diffusivity coefficient (Def), the activation energy (Ea), and the color of punamuña leaves. A horizontal dryer was used at 40, 50, and 60 °C and airspeed of 1.0 and 0.5 m / s; drying kinetics was modeled with 10 models. Def was determined with the Fick equation, Ea with the Arrhenius equation; the color was determined in the L* a* b* space. It was found that the triple exponential model with six parameters better represented the drying kinetics (R2> 99.73 and E 99.73 y E < 3.04%); Def se incrementó con la temperatura y velocidad de aire. Ease encontró entre 43.62 a 44.52 kJ/mol para velocidades de 1.0 a 0.5 m/s respectivamente; L* y a*/b* disminuyeron, la diferencia de color ΔE* se incrementó con el aumento de la temperatura y a menor velocidad de air

Stability in Aqueous Solution of a New Spray-Dried Hydrocolloid of High Andean Algae <i>Nostoc sphaericum</i>

There is a growing emphasis on seeking stabilizing agents with minimal transformation, prioritizing environmentally friendly alternatives, and actively contributing to the principles of the circular economy. This research aimed to assess the stability of a novel spray-dried hydrocolloid from high Andean algae when introduced into an aqueous solution. Nostoc sphaericum freshwater algae were subject to atomization, resulting in the production of spray-dried hydrocolloid (SDH). Subsequently, suspension solutions of SDH were meticulously prepared at varying pH levels and gelling temperatures. These solutions were then stored for 20 days to facilitate a comprehensive evaluation of their stability in suspension. The assessment involved a multifaceted approach, encompassing rheological analysis, scrutiny of turbidity, sedimentation assessment, ζ-potential, and measurement of particle size. The findings from these observations revealed that SDH exhibits a dilatant behavior when in solution, signifying an increase in with higher shear rate. Furthermore, it demonstrates commendable stability when stored under ambient conditions. SDH is emerging as a potential alternative stabilizer for use in aqueous solutions due to its easy extraction and application