561 research outputs found

    Creating 3D Foldable Papercraft from Dynamically Generated Scalable Vector

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    This project demonstrates the advantages of using Scalable Vector Graphics (SVG) over traditional image types (JPEG, GIF, PNG, etc.) for 3D modeling on the Web. The project uses an SVG to dynamically update the colors and layers, and apply it as a texture on a 3D model. Since the 3D model is based on a 2D texture, the project also demonstrates how to print and fold it back into a 3D papercraft

    Time-Resolved Ultrafast Transient Polarization Spectroscopy to Investigate Nonlinear Processes and Dynamics in Electronically Excited Molecules on the Femtosecond Time Scale

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    We report a novel experimental technique to investigate ultrafast dynamics in photoexcited molecules by probing the third-order nonlinear optical susceptibility. A non-colinear 3-pulse scheme is developed to probe the ultrafast dynamics of excited electronic states using the optical Kerr effect by time-resolved polarization spectroscopy. Optical heterodyne and optical homodyne detection are demonstrated to measure the third-order nonlinear optical response for the S1 excited state of liquid nitrobenzene, which is populated by 2-photon absorption of a 780 nm 35 fs excitation pulse.Comment: 12 pages, 4 figures. Changes from previous version: added panel labels to figures 3-

    Automated Mobile System for Accurate Outdoor Tree Crop Enumeration Using an Uncalibrated Camera.

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    This paper demonstrates an automated computer vision system for outdoor tree crop enumeration in a seedling nursery. The complete system incorporates both hardware components (including an embedded microcontroller, an odometry encoder, and an uncalibrated digital color camera) and software algorithms (including microcontroller algorithms and the proposed algorithm for tree crop enumeration) required to obtain robust performance in a natural outdoor environment. The enumeration system uses a three-step image analysis process based upon: (1) an orthographic plant projection method integrating a perspective transform with automatic parameter estimation; (2) a plant counting method based on projection histograms; and (3) a double-counting avoidance method based on a homography transform. Experimental results demonstrate the ability to count large numbers of plants automatically with no human effort. Results show that, for tree seedlings having a height up to 40 cm and a within-row tree spacing of approximately 10 cm, the algorithms successfully estimated the number of plants with an average accuracy of 95.2% for trees within a single image and 98% for counting of the whole plant population in a large sequence of images

    Distinguishing resonance symmetries with energy-resolved photoion angular distributions from ion-pair formation in O2_2 following two-photon absorption of a 9.3 eV femtosecond pulse

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    We present a combined experimental and theoretical study on the photodissociation dynamics of ion-pair formation in O2_2 following resonant two-photon absorption of a 9.3 eV femtosecond pulse, where the resulting O+^+ ions are detected using 3-D momentum imaging. Ion-pair formation states of 3Σg−^3\Sigma^-_g and 3Πg^3\Pi_g symmetry are accessed through predissociation of optically dark continuum Rydberg states converging to the B 2Σg−^2\Sigma^-_g ionic state, which are resonantly populated via a mixture of both parallel-parallel and parallel-perpendicular two-photon transitions. This mixture is evident in the angular distribution of the dissociation relative to the light polarization, and varies with the kinetic energy release (KER) of the fragmenting ion-pair. The KER-dependent photoion angular distribution reveals the underlying two-photon absorption dynamics involved in the ion-pair production mechanism and indicates the existence of two nearly degenerate continuum resonances possessing different symmetries, which can both decay by coupling to ion-pair states of the same total symmetry through internal conversion.Comment: 8 pages, 5 figures, 1 tabl

    Ultrafast Dynamics of Excited Electronic States in Nitrobenzene Measured by Ultrafast Transient Polarization Spectroscopy.

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    We investigate ultrafast dynamics of the lowest singlet excited electronic state in liquid nitrobenzene using ultrafast transient polarization spectroscopy, extending the well-known technique of optical Kerr effect spectroscopy to excited electronic states. The third-order nonlinear response of the excited molecular ensemble is measured using a pair of femtosecond pulses following a third femtosecond pulse that populates the S1 excited state. By measuring this response, which is highly sensitive to details of the excited state character and structure, as a function of time delays between the three pulses involved, we extract the dephasing time of the wave packet on the excited state. The dephasing time, measured as a function of time delay after pump excitation, shows oscillations indicating oscillatory wave packet dynamics on the excited state. From the experimental measurements and supporting theoretical calculations, we deduce that the wave packet completely leaves the S1 state potential energy surface after three traversals of the intersystem crossing between the singlet S1 and triplet T2 states

    The Absolute Age of M92

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    The \textit{absolute age} of a simple stellar population is of fundamental interest for a wide range of applications but is difficult to measure in practice, as it requires an understanding of the uncertainties in a variety of stellar evolution processes as well as the uncertainty in the distance, reddening and composition. As a result, most studies focus only on the \textit{relative age} by assuming that stellar evolution calculations are accurate and using age determinations techniques that are relatively independent of distance and reddening. Here, we construct 20,00020,000 sets of theoretical isochrones through Monte Carlo simulation using the Dartmouth Stellar Evolution Program to measure the absolute age of the globular cluster M92. For each model, we vary a range of input physics used in the stellar evolution models, including opacities, nuclear reaction rates, diffusion coefficients, atmospheric boundary conditions, helium abundance, and treatment of convection. We also explore variations in the distance and reddening as well as its overall metallicity and α\alpha enhancement. We generate simulated Hess diagrams around the main-sequence turn-off region from each set of isochrones and use a Voronoi binning method to fit the diagrams to HST ACS data. We find the age of M92 to be 13.80±0.7513.80 \pm 0.75 Gyr. The 5.4%5.4\% error in the absolute age is dominated by the uncertainty in the distance to M92 (∼80%\sim 80\% of the error budget); of the remaining parameters, only the total metallicity, α\alpha element abundance, and treatment of helium diffusion contribute significantly to the total error.Comment: 15 Pages, 14 Figures, 2 Tables; Accepted for Publication A

    Mass-selected ion–molecule cluster beam apparatus for ultrafast photofragmentation studies

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    We describe an apparatus for investigating the excited-state dissociation dynamics of mass-selected ion–molecule clusters by mass-resolving and detecting photofragment-ions and neutrals, in coincidence, using an ultrafast laser operating at high repetition rates. The apparatus comprises a source that generates ion–molecule clusters, a time-of-flight spectrometer, and a mass filter that selects the desired anions, and a linear-plus-quadratic reflectron mass spectrometer that discriminates the fragment anions after the femtosecond laser excites the clusters. The fragment neutrals and anions are then captured by two channeltron detectors. The apparatus performance is tested by measuring the photofragments: I−, CF3I−, and neutrals from photoexcitation of the ion–molecule cluster CF3I⋅I− using femtosecond UV laser pulses with a wavelength of 266 nm. The experimental results are compared with our ground state and excited state electronic structure calculations as well as the existing results and calculations, with particular attention to the generation mechanism of the anion fragments and dissociation channels of the ion–molecule cluster CF3I⋅I− in the charge-transfer excited state
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