CMOS integration of inkjet-printed graphene for humidity sensing.

We report on the integration of inkjet-printed graphene with a CMOS micro-electro-mechanical-system (MEMS) microhotplate for humidity sensing. The graphene ink is produced via ultrasonic assisted liquid phase exfoliation in isopropyl alcohol (IPA) using polyvinyl pyrrolidone (PVP) polymer as the stabilizer. We formulate inks with different graphene concentrations, which are then deposited through inkjet printing over predefined interdigitated gold electrodes on a CMOS microhotplate. The graphene flakes form a percolating network to render the resultant graphene-PVP thin film conductive, which varies in presence of humidity due to swelling of the hygroscopic PVP host. When the sensors are exposed to relative humidity ranging from 10-80%, we observe significant changes in resistance with increasing sensitivity from the amount of graphene in the inks. Our sensors show excellent repeatability and stability, over a period of several weeks. The location specific deposition of functional graphene ink onto a low cost CMOS platform has the potential for high volume, economic manufacturing and application as a new generation of miniature, low power humidity sensors for the internet of things.S.S. acknowledges Department of Science and Technology (DST), India for Ramanujan Fellowship to support the work (project no. SR/S2/RJN-104/2011). This work was (partly) supported through the EU FP7 project MSP (611887). T.H. acknowledges support from the Royal Academy of Engineering through a fellowship (Graphlex).This is the final version of the article. It was first available from NPG via http://dx.doi.org/10.1038/srep1737

Enhanced spectroscopic gas sensors using in-situ grown carbon nanotubes

In this letter, we present a fully complementary-metal-oxide-semiconductor (CMOS) compatible microelectromechanical system thermopile infrared (IR) detector employing vertically aligned multi-walled carbon nanotubes (CNT) as an advanced nano-engineered radiation absorbing material. The detector was fabricated using a commercial silicon-on-insulator (SOI) process with tungsten metallization, comprising a silicon thermopile and a tungsten resistive micro-heater, both embedded within a dielectric membrane formed by a deep-reactive ion etch following CMOS processing. In-situ CNT growth on the device was achieved by direct thermal chemical vapour deposition using the integrated micro-heater as a micro-reactor. The growth of the CNT absorption layer was verified through scanning electron microscopy, transmission electron microscopy, and Raman spectroscopy. The functional effects of the nanostructured ad-layer were assessed by comparing CNT-coated thermopiles to uncoated thermopiles. Fourier transform IR spectroscopy showed that the radiation absorbing properties of the CNT adlayer significantly enhanced the absorptivity, compared with the uncoated thermopile, across the IR spectrum (3 μm–15.5 μm). This led to a four-fold amplification of the detected infrared signal (4.26 μm) in a CO2 non-dispersive-IR gas sensor system. The presence of the CNT layer was shown not to degrade the robustness of the uncoated devices, whilst the 50% modulation depth of the detector was only marginally reduced by 1.5 Hz. Moreover, we find that the 50% normalized absorption angular profile is subsequently more collimated by 8°. Our results demonstrate the viability of a CNT-based SOI CMOS IR sensor for low cost air quality monitoring.This work was partly supported through the EU FP7 project SOI-HITS (No. 288481). MTC thanks the Oppenheimer Trust and the EPSRC IAA for their generous financial support.This is the author accepted manuscript. The final version is available from AIP at http://scitation.aip.org/content/aip/journal/apl/106/19/10.1063/1.4921170

Improving the mechanical behavior of pervious concrete using polypropylene and waste rope fibers

Urbanization has led to the damage of infrastructure due to floods and water accumulation on roads and sidewalks. To address this problem, pervious concrete was designed to drain water smoothly. However, pervious concrete has certain drawbacks, such as brittleness and poor tensile strength. To overcome these shortcomings, it is reinforced with fiber. Polypropylene fibers are commonly used for this purpose. On the other hand, managing waste plastic is a major problem as it has a significant environmental impact and requires large areas for landfills. Waste rope fibers (WRF) are among these wastes. There have been very limited investigations on the use of WRF in pervious concrete. Therefore, this study aims to investigate the effect of polypropylene (PP) fibers and waste rope fibers (WRF) on the mechanical and structural properties of pervious concrete. PP and WRF fibers were added in proportions of 0.25%, 0.5%, and 0.75% by volume of concrete. A range of tests (compressive strength, tensile strength, density, permeability, load-deflection behavior, and ductility) were conducted to evaluate the resulting concrete. The results indicated that although the permeability was decreased by adding fibers, the fibers significantly improved the mechanical and structural properties of pervious concrete. The highest values for compressive strength, splitting tensile strength, and ultimate load were 83.4%, 72.4%, and 89.62% for PP fibers-based mixtures, while they were 49.9%, 41.9%, and 102.83% for mixtures made with WRF at an addition rate of 0.5% for both types of fibers. The results also demonstrated that the existence of fibers improved the ductility of the concrete, which means that WRF can be used successfully in producing eco-friendly pervious concrete with better performance than the control specimen.</jats:p

Metric operators, generalized hermiticity and lattices of Hilbert lpaces

A quasi-Hermitian operator is an operator that is similar to its adjoint in some sense, via a metric operator, i.e., a strictly positive self-adjoint operator. Whereas those metric operators are in general assumed to be bounded, we analyze the structure generated by unbounded metric operators in a Hilbert space. It turns out that such operators generate a canonical lattice of Hilbert spaces, that is, the simplest case of a partial inner product space (PIP-space). We introduce several generalizations of the notion of similarity between operators, in particular, the notion of quasi-similarity, and we explore to what extend they preserve spectral properties. Then we apply some of the previous results to operators on a particular PIP-space, namely, a scale of Hilbert spaces generated by a metric operator. Finally, motivated by the recent developments of pseudo-Hermitian quantum mechanics, we reformulate the notion of pseudo-Hermitian operators in the preceding formalism.Comment: 51pages; will appear as a chapter in \textit{Non-Selfadjoint Operators in Quantum Physics: Mathematical Aspects}; F. Bagarello, J-P. Gazeau, F. H. Szafraniec and M. Znojil, eds., J. Wiley, 201

Experimental study of the morphine de-addiction properties of Delphinium denudatum Wall.

BACKGROUND: Our aim was to explore the de-addiction properties of Delphinium denudatum Wall. in morphine dependent rats. METHODS: Charles Foster male albino rats were made morphine dependent by injecting morphine sulphate in increasing doses twice a day for 7 days. The spontaneous withdrawal signs observed 12 h after the last dose were quantified by the 'counted' and 'checked' signs. The drug (alcoholic extract of Delphinium denudatum) was administered p.o. in different regimen: a) single dose (700 mg/kg) 10 h before the first dose of morphine, b) single dose (700 mg/kg) 10 h after the last dose of morphine, c) multiple doses (350 mg/kg) along with morphine twice a day for 7 days. RESULT: Administration of Delphinium denudatum extract caused significant reduction in the frequency of counted signs as well as the presence of checked signs of morphine withdrawal. The maximum reduction was observed in regimen 'b' followed by regimen 'c' and 'a'. CONCLUSION: Delphinium denudatum Wall. significantly reduces the aggregate scores for all parameters in morphine withdrawal syndrome by central action and thus may prove to be an alternative remedy in morphine de-addiction

CMOS-compatible SOI micro-hotplate-based oxygen sensor

© 2016 IEEE. The paper reports upon the design and characterization of a resistive O2 sensor, which is fully CMOS-compatible and is based on an ultra-low-power Silicon on Insulator (SOI) micro-hotplate membrane. The microsensor employs SrTi0.4Fe0.6O2.8 (STFO60) as sensing layer. Thermo-Gravimetric Analysis (TGA) Energy-Dispersive X-ray Spectroscopy (EDX), X-ray Diffraction (XRD) and Scanning Electron Microscope (SEM) techniques have been used to assess the quality of both the sensing layer and STFO-SOI interface. At room temperature, the SOI sensor shows good sensitivity and fast response time (≤ 6 seconds) to O2 concentration ranging from 0% to 20% in a nitrogen atmosphere. This is the first experimental result showing the potential of this structure as O2 sensor

Nanostructured metal oxides semiconductors for oxygen chemiresistive sensing

Nanostructured metal oxide semiconductors have been widely investigated and are commonly used in gas sensing structures. After a brief review which will be focused on chemiresistive oxygen sensing employing this type of sensing materials, for both room temperature and harsh environment applications (particularly, at high ambient temperature and high relative humidity levels), paper reports new results concerning O2detection of a structure using a sensing layer comprising nanostructured (typical grain size of 50 nm) SrTi0.6Fe0.4O2.8(STFO40), synthesized by sonochemical methods, mixed with single wall carbon nanotubes. The structure is a Microelectromechanical System (MEMS), based on a Silicon-on-Insulator (SOI), Complementary Metal-Oxide-Semiconductor (CMOS)-compatible micro-hotplate, comprising a tungsten heater which allows an excellent control of the sensing layer working temperature. Oxygen detection tests were performed in both dry (RH = 0%) and humid (RH = 60%) nitrogen atmosphere, varying oxygen concentrations between 1% and 20% (v/v), at a constant heater temperature of 650 °C

Study of Exclusive Radiative B Meson Decays

We have investigated exclusive, radiative B meson decays to charmless mesons (\rho, \omega, \phi, K^*(892), K^*_2(1430)) in 9.7\times 10^6 BBbar decays accumulated with the CLEO detector. The B -> K^*(892)\gamma branching fractions are determined to be Br(B^0 -> K^{*0}(892)\gamma) = (4.55 +0.72-0.68 +-0.34)\times 10^-5 and Br(B^+ -> K^{*+}(892)\gamma) = (3.76 +0.89-0.83 +-0.28)\times 10^-5. We have searched for CP asymmetry in B -> K^*(892)\gamma decays and measure Acp = +0.08 +-0.13 +-0.03. We also report the first observation of the decay B -> K^*_2(1430)\gamma with a branching fraction of (1.66 +0.59-0.53 +-0.13)\times 10^-5 and determine $Br(B -> K^*_2(1430)\gamma)/Br(B -> K^*(892)\gamma) = 0.39 +0.15-0.13 consistent with only one of two available theoretical models. No significant evidence for the decays B -> \rho\gamma and B^0 -> \omega\gamma is found and we limit Br(B -> (\rho/\omega)\gamma)/Br(B -> K^{*}(892)\gamma) < 0.32 at 90% CL. We also find no evidence for the exotic decay B^0 -> \phi\gamma.Comment: 12 pages, 3 figures, submitted to Phys. Rev. Letter