Investigation of the Influence of Triboactive CrAlMoN Coating on the Joint Wear of Grease-Lubricated Roller Chains

Physical vapor deposition (PVD) coatings are vital for enhancing wear resistance. However this technology faces challenges when coating inaccessible surfaces due to its line-of-sight characteristic. A potential remedy is utilizing triboactive CrAlMoN coatings. These form a tribofilm in the contact zone when applied to one contact partner along with a suitable lubricant. This tribofilm can subsequently safeguard inaccessible yet tribologically stressed surfaces. One of the main applications for this method is roller chain drives, whose longevity depends on the joint wear and the resulting chain elongation. Large-scale pin coatings have proven effective in curbing wear and prolonging chain life. However, the inaccessibility of bushes complicates standard PVD coating procedures. Triboactive coatings offer the possibility of forming transfer layers on the bushes, thereby enhancing friction reduction and wear protection. Experimental material studies for chain drives can be cost-intensive due to complexity and numerous components. This article demonstrates that CrAlN and CrAlMoN coatings in combination with greases with the additives phosphorus and sulfur can reduce friction and wear in chain joints. Furthermore, it is shown that a reasonable selection of tribometer testing can significantly reduce costs. Comparing the results of tests on a pin-on-disk tribometer and component tests show that model tests cannot completely replace component tests. But the combination offers an efficient way to optimize test matrices. Triboactive coatings like CrAlMoN hold promise for addressing the challenge of inaccessible surfaces. Reasonable tribometer test selection can help mitigate the costs of experimental studies, making these coatings a more practical solution

A new strategy for aromatic ring alkylation in cylindrocyclophane biosynthesis

Alkylation of aromatic rings with alkyl halides is an important transformation in organic synthesis, yet an enzymatic equivalent is unknown. Here, we report that cylindrocyclophane biosynthesis in Cylindrospermum licheniforme ATCC 29412 involves chlorination of an unactivated carbon center by a novel halogenase, followed by a previously uncharacterized enzymatic dimerization reaction featuring sequential, stereospecific alkylations of resorcinol aromatic rings. Discovery of the enzymatic machinery underlying this unique biosynthetic carbon–carbon bond formation has implications for biocatalysis and metabolic engineering