1,097 research outputs found
Electronic Correlations in CoO2, the Parent Compound of Triangular Cobaltates
A 59Co NMR study of CoO2, the x=0 end member of AxCoO2 (A = Na, Li...)
cobaltates, reveals a metallic ground state, though with clear signs of strong
electron correlations: low-energy spin fluctuations develop at wave vectors q
different from 0 and a crossover to a Fermi-liquid regime occurs below a
characteristic temperature T*~7 K. Despite some uncertainty over the exact
cobalt oxidation state n this material, the results show that electronic
correlations are revealed as x is reduced below 0.3. The data are consistent
with NaxCoO2 being close to the Mott transition in the x -> 0 limit.Comment: 4 pages, submitte
The antiferromagnetic insulator Ca3FeRhO6: characterization and electronic structure calculations
We investigate the antiferromagnetic insulating nature of Ca3FeRhO6 both
experimentally and theoretically. Susceptibility measurements reveal a Neel
temperature T_N = 20 K, and a magnetic moment of 5.3 muB/f. u., while
Moessbauer spectroscopy strongly suggests that the Fe ions, located in trigonal
prismatic sites, are in a 3+ high spin state. Transport measurements display a
simple Arrhenius law, with an activation energy of 0.2 eV. The experimental
results are interpreted with LSDA band structure calculations, which confirm
the Fe 3+ state, the high-spin/low-spin scenario, the antiferromagnetic
ordering, and the value for the activation energy.Comment: 5 pages, 6 figure
Ferromagnetic to spin glass cross over in (La,Tb)_{2/3}Ca_{1/3}MnO_{3}
In the series La_{2/3-x}Tb_{x}Ca_{1/3}MnO_{3}, it is known that the
compositions are ferromagnetic for smaller values of x and show spin glass
characteristics at larger values of x. Our studies on the magnetic properties
of various compositions in the La_{2/3-x}Tb_{x}Ca_{1/3}MnO_{3} series show that
the cross over from ferromagnetic to spin glass region takes place above x ~
1/8. Also, a low temperature anomaly at 30 K, observed in the ac susceptibility
curves, disappears for compositions above this critical value of x. A mixed
phase region coexists in the narrow compositional range 0.1 <= x <= 0.125,
indicating that the ferromagnetic to spin glass cross over is not abrupt.Comment: 5 pages, 5 figure
Rhodium Doped Manganites : Ferromagnetism and Metallicity
The possibility to induce ferromagnetism and insulator to metal transitions
in small A site cation manganites Ln_{1-x}Ca_xMnO_3 by rhodium doping is shown
for the first time. Colossal magnetoresistance (CMR) properties are evidenced
for a large compositional range (0.35 \leq x < 0.60). The ability of rhodium to
induce such properties is compared to the results obtained by chromium and
ruthenium doping. Models are proposed to explain this behavior.Comment: 11 pages, 8 figure
Competition between ferromagnetism and spin glass: the key for large magnetoresistance in oxygen deficient perovskites SrCo1-xMxO3-d (M = Nb, Ru)
The magnetic and magnetotransport properties of the oxygen deficient
perovskites, SrCo1-xMxO3-d with M = Nb and Ru, were investigated. Both Nb- and
Ru-substituted cobaltites are weak ferromagnets, with transition temperatures
Tm of 130-150 K and 130-180 K, respectively, and both exhibit a spin glass
behavior at temperatures below Tf = 80-90 K. It is demonstrated that there
exists a strong competition between ferromagnetism and spin glass state, where
Co4+ induces ferromagnetism, whereas Nb or Ru substitution at the cobalt sites
induces magnetic disorder, and this particular magnetic behavior is the origin
of large negative magnetoresistance of these oxides, reaching up to 30% at 5 K
in 7 T. The differences between Nb- and Ru-substituted cobaltites are discussed
on the basis of the different electronic configuration of niobium and ruthenium
cations.Comment: 32 pages, 9 figures, to appear in Phys. Rev.
Field-Induced Magnetization Steps in Intermetallic Compounds and Manganese Oxides: The Martensitic Scenario
Field-induced magnetization jumps with similar characteristics are observed
at low temperature for the intermetallic germanide Gd5Ge4and the mixed-valent
manganite Pr0.6Ca0.4Mn0.96Ga0.04O3. We report that the field location -and even
the existence- of these jumps depends critically on the magnetic field sweep
rate used to record the data. It is proposed that, for both compounds, the
martensitic character of their antiferromagnetic-to-ferromagnetic transitions
is at the origin of the magnetization steps.Comment: 4 pages,4 figure
Magneto-elastic coupling and unconventional magnetic ordering in triangular multiferroic AgCrS2
The temperature evolution of the crystal and magnetic structures of
ferroelectric sulfide AgCrS2 have been investigated by means of neutron
scattering. AgCrS2 undergoes at TN = 41.6 K a first-order phase transition,
from a paramagnetic rhombohedral R3m to an antiferromagnetic monoclinic
structure with a polar Cm space group. In addition to being ferroelectric below
TN, the low temperature phase of AgCrS2 exhibits an unconventional collinear
magnetic structure that can be described as double ferromagnetic stripes
coupled antiferromagnetically, with the magnetic moment of Cr+3 oriented along
b within the anisotropic triangular plane. The magnetic couplings stabilizing
this structure are discussed using inelastic neutron scattering results.
Ferroelectricity below TN in AgCrS2 can possibly be explained in terms of
atomic displacements at the magneto-elastic induced structural distortion.
These results contrast with the behavior of the parent frustrated
antiferromagnet and spin-driven ferroelectric AgCrO2
Stability of geometrically frustrated magnetic state of Ca3CoRhO6 to applications of positive and negative pressure
The influence of negative chemical pressure induced by gradual replacement of
Ca by Sr as well as of external pressure (up to 10 kbar) on the magnetism of
Ca3CoRhO6 has been investigated by magnetization studies. It is found that the
solid solution, Ca(3-x)Sr(x)CoRhO6, exists at least till about x= 1.0 without
any change in the crystal structure. Apart from insensitivity of the spin-chain
feature to volume expansion, the characteristic features of geometrical
frustration interestingly appear at the same temperatures for all compositions,
in sharp contrast to the response to Y substitution for Ca (reported
previously). Interestingly, huge frequency dependence of ac susceptibility
known for the parent compound persists for all compositions. We do not find a
change in the properties under external pressure. The stability of the magnetic
anomalies of this compound to the volume change (about 4%) is puzzling
Magnetic behavior of spin-chain compounds, Sr3ZnRhO6 and Ca3NiMnO6, from heat capacity and ac susceptibility studies
Heat-capacity (C) and ac susceptibility measurements have been performed on
the spin-chain compounds, Sr3ZnRhO6 and Ca3NiMnO6, to establish their magnetic
behavior and to explore whether there are magnetic frustration effects due to
antiferromagnetic coupling of the chains arranged in a triangular fashion.
While the paramagnetic Curie temperatures have been known to be large with a
negative sign, as though antiferromagnetic interaction is very strong, the
results establish that (i) the former apparently undergoes inhomogeneous
magnetic ordering only around 15 K, however without spin-glass anomalies, and
(ii) the latter orders antiferromagnetically at a relatively low temperature
(17 K). Thus, the magnetic frustration manifests differently in these
compounds.Comment: J. Solid State Chemistry, in pres
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