Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants

The aim of this study is to perform a review of the state-of-the-art of the reactors available in the literature, which are used for solid-gas reactions or thermal decomposition processes around 1000 ºC that could be further implemented for thermochemical energy storage in CSP (concentrated solar power) plants, specifically for SPT (solar power tower) technology. Both direct and indirect systems can be implemented, with direct and closed systems being the most studied ones. Among direct and closed systems, the most used configuration is the stacked bed reactor, with the fixed bed reactor being the most frequent option. Out of all of the reactors studied, almost 70% are used for solid-gas chemical reactions. Few data are available regarding solar efficiency in most of the processes, and the available information indicates relatively low values. Chemical reaction efficiencies show better values, especially in the case of a fluidized bed reactor for solid-gas chemical reactions, and fixed bed and rotary reactors for thermal decompositions.The work is partially funded by the Spanish government (ENE2015-64117-C5-1-R (MINECO/FEDER) and ENE2015-64117-C5-2-R (MINECO/FEDER)). The authors would like to thank the Catalan Government for the quality accreditation given to their research groups GREA (2017 SGR 1537) and DIOPMA (2017 SGR 118). GREA and DIOPMA are certified agents TECNIO in the category of technology developers from the Government of Catalonia. Dr. Aran Solé would like to thank Ministerio de Economía y Competitividad de España for Grant Juan de la Cierva, FJCI-2015-25741

Thermophysical characterization and thermal cycling stability of two TCM: CaCl2 and zeolite

At this moment, the global energy consumption in buildings is around 40% of the total energy consumption in developed countries. Thermal energy storage (TES) is presented as one way to address this energy-related problem proposing an alternative to reduce the gap between energy supply and energy demand. One way to store energy is using thermochemical materials (TCM). These types of materials allow accumulating energy through a chemical process at low temperature, almost without heat losses. In addition, it is a stable way to perform the heat storage and TCM can be implemented for seasonal storage or/and long term storage. This study compares the cyclability, from the thermophysical point of view, CaCl2 which follows a chemical reaction and zeolite which follows a sorption process to be used as TCM for seasonal/long term storage. The main results show that the chemical reaction TCM is more energy-efficient than the sorption TCM. The CaCl2 calculated energy density is 1.47 GJ/m3, being the best option to be considered to be used as TCM, even though the dehydration process of the zeolite is simpler and it occurs at higher temperatures its calculated energy density is only 0.2 GJ/m3

Characterization of Supplementary Cementitious Materials and Fibers to be Implemented in High Temperature Concretes for Thermal Energy Storage (TES) Application

Six supplementary cementitious materials (SCMs) were identified to be incorporated in concrete exposed to high-temperature cycling conditions within the thermal energy storage literature. The selected SCMs are bauxite, chamotte, ground granulated blast furnace slag, iron silicate, silica fume, and steel slag. A microstructural characterization was carried out through an optical microscope, X-ray diffraction analysis, and FT-IR. Also, a pozzolanic test was performed to study the reaction of SCMs silico-aluminous components. The formation of calcium silica hydrate was observed in all SCMs pozzolanic test. Steel slag, iron silicate, and ground granulated blast furnace slag required further milling to enhance cement reaction. Moreover, the tensile strength of three fibers (polypropylene, steel, and glass fibers) was tested after exposure to an alkalinity environment at ambient temperature during one and three months. Results show an alkaline environment entails a tensile strength decrease in polypropylene and steel fibers, leading to corrosion in the later ones.Funding This work was partially funded by the Ministerio de Ciencia, Innovación y Universidades de España (RTI2018-093849-B-C31—MCIU/AEI/FEDER, UE and RTI2018-093849-B-C32—MCIU/AEI/FEDER) and by the Ministerio de Ciencia, Innovación y Universidades—Agencia Estatal de Investigación (AEI) (RED2018-102431-T). This work is partially supported by ICREA under the ICREA Academia programme. This study was partially funded by AEI—Spanish Ministry of Science, Innovation and Universities (PCI2020-120695-2/AEI/10.13039/501100011033 and PCI2020-120682-2/AEI/10.13039/501100011033 through PCI call). Acknowledgments The authors would like to thank the Catalan Government for the quality accreditation given to their research groups (2017 SGR 1537 and 2017 SGR 118). GREiA and DIOPMA are certified agents TECNIO in the category of technology developers from the Government of Catalonia. The authors also thank the companies that provided the material to make possible this experimental research: Gestión Medioambiental de Neumáticos S.L., Arciresa, EDERSA—Masaveu Industria and Promsa—Megasa