Radicals, Metals and Magnetism

The interaction between unpaired electrons governs many physical properties of materials. Although in a fundamental sense the interaction is simple, a full understanding of the interaction in molecular systems is complicated by the presence of other bonding and non-bonding electrons. The resulting many body problem is very challenging. Nevertheless, much qualitative understanding can be obtained from applying simple molecular orbital theory and considering only the partly filled orbitals. The resulting model can be used to describe existing diradical and metal-radical systems and also has predicative value in the search for molecular magnets and design of nanoscale devices

A Comparison of Risk Exposure in Aquaculture and Agricultural Businesses

Agriculture and aquaculture have common features associated with their biological nature affecting risk exposure of the businesses. The aim of this paper is to compare risk exposure in salmon farming and agricultural enterprises in Norway by using an implicit error component model to examine the risk structure of yields, prices and economic returns at the farm level. Results indicate a higher farm-level year-to-year variability in yields, prices and economic returns in salmon farming than in agricultural enterprises. The variability in livestock enterprises was generally lower than for crop enterprises. Return on assets was highest in salmon farming with an average annual return of 9.2%. All of the agricultural farm types exhibited a negative average return on assets on average. Stochastic dominance tests of the distribution of economic returns from aquaculture and agricultural farm types showed salmon farming to be the most risk efficient alternative and salmon farming was most attractive from an investor’s perspective.Risk analysis, variability, Norway, Risk and Uncertainty,

Volcanic smog and cardiometabolic health: Hawaiian hypertension?

Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/149349/1/jch13500.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/149349/2/jch13500_am.pd

Nighttime observations of thunderstorm electrical activity from a high altitude airplane

Nocturnal thunderstorms were observed from above and features of cloud structure and lightning which are not generally visible from the ground are discussed. Most, lightning activity seems to be associated with clouds with strong convective cauliflower tops. In both of the storms lightning channels were visible in the clear air above the cloud. It is shown that substances produced by thunderstorm electrical discharges can be introduced directly into the stratosphere. The cause and nature of the discharges above the cloud are not clear. They may be produced by accumulations of space charge in the clear air above the cloud. The discharges may arise solely because of the intense electric fields produced by charges within the cloud. In the latter case the ions introduced by these discharges will increase the electrical conductivity of the air above the cloud and increase the conduction current that flows from the cloud to the electrosphere. More quantitative data at higher resolution may show significant spectral differences between cloud to ground and intracloud strokes. It is shown that electric field change data taken with an electric field change meter mounted in an airplane provide data on lightning discharges from above that are quite similar to those obtained from the ground in the past. The optical signals from dart leaders, from return strokes, and from continuing currents are recognizable, can be used to provide information on the fine structure of lightning, and can be used to distinguish between cloud to ground and intracloud flashes

Hierarchical formation of bulgeless galaxies II: Redistribution of angular momentum via galactic fountains

Within a fully cosmological hydrodynamical simulation, we form a galaxy which rotates at 140 km/s, and is characterised by two loose spiral arms and a bar, indicative of a Hubble Type SBc/d galaxy. We show that our simulated galaxy has no classical bulge, with a pure disc profile at z=1, well after the major merging activity has ended. A long-lived bar subsequently forms, resulting in the formation of a secularly-formed "pseudo" bulge, with the final bulge-to-total light ratio B/T=0.21. We show that the majority of gas which loses angular momentum and falls to the central region of the galaxy during the merging epoch is blown back into the hot halo, with much of it returning later to form stars in the disc. We propose that this mechanism of redistribution of angular momentum via a galactic fountain, when coupled with the results from our previous study which showed why gas outflows are biased to have low angular momentum, can solve the angular momentum/bulgeless disc problem of the cold dark matter paradigm.Comment: 9 Pages, 10 Figures, accepted MNRAS version. Comments welcom

Correlated emission and spin-down variability in radio pulsars

The recent revelation that there are correlated period derivative and pulse shape changes in pulsars has dramatically changed our understanding of timing noise as well as the relationship between the radio emission and the properties of the magnetosphere as a whole. Using Gaussian processes we are able to model timing and emission variability using a regression technique that imposes no functional form on the data. We revisit the pulsars first studied by Lyne et al. (2010). We not only confirm the emission and rotational transitions revealed therein, but reveal further transitions and periodicities in 8 years of extended monitoring. We also show that in many of these objects the pulse profile transitions between two well-defined shapes, coincident with changes to the period derivative. With a view to the SKA and other telescopes capable of higher cadence we also study the detection limitations of period derivative changes.Comment: 4 pages, 2 Figures, Proceedings of IAU Symposium 337 "Pulsar Astrophysics - The Next 50 Years" held at Jodrell Bank Observatory, UK Sept. 4-8 201

A revised parameterization for gaseous dry deposition in air-quality models

International audienceA parameterization scheme for calculating gaseous dry deposition velocities in air-quality models is revised based on recent study results on non-stomatal uptake of O3 and SO2 over 5 different vegetation types. Non-stomatal resistance, which includes in-canopy aerodynamic resistance, soil resistance and cuticle resistance, for SO2 and O3 is parameterized as a function of friction velocity, relative humidity, leaf area index, and canopy wetness. Non-stomatal resistance for all other species is scaled to those of SO2 and O3 based on their chemical and physical characteristics. Stomatal resistance is calculated using a leaf-stomatal-resistance model for all gaseous species of interest. The improvements in the present model compared to its earlier version include a newly developed non-stomatal resistance formulation, a realistic treatment of cuticle and ground resistance in winter and the handling of seasonally-dependent input parameters. Model evaluation shows that the revised parameterization can provide more realistic deposition velocities for both O3 and SO2, especially for wet canopies. Example model output shows that the parameterization provides reasonable estimates of dry deposition velocities for different gaseous species, land types and diurnal and seasonal variations. Maximum deposition velocities from model output are close to reported measurement values for different land types. The current parameterization can be easily adopted into different air-quality models that require inclusion of dry deposition processes