4,643 research outputs found
Three-body interactions in complex fluids: virial coefficients from simulation finite-size effects
A simulation technique is described for quantifying the contribution of
three-body interactions to the thermodynamical properties of coarse-grained
representations of complex fluids. The method is based on comparing the third
virial coefficient for a complex fluid with that of an approximate
coarse-grained model described by a pair potential. To obtain we
introduce a new technique which expresses its value in terms of the measured
volume-dependent asymptote of a certain structural function. The strategy is
applicable to both Molecular Dynamics and Monte Carlo simulation. Its utility
is illustrated via measurements of three-body effects in models of star polymer
and highly size-asymmetrical colloid-polymer mixtures.Comment: 13 pages, 8 figure
Nonlinear hydroelastic waves on a linear shear current at finite depth
This work is concerned with waves propagating on water of finite depth with a constant-vorticity current under a deformable flexible sheet. The pressure exerted by the sheet is modelled by using the Cosserat thin shell theory. By means of multi-scale analysis, small amplitude nonlinear modulation equations in several regimes are considered, including the nonlinear Schrödinger equation (NLS) which is used to predict the existence of small-amplitude wavepacket solitary waves in the full Euler equations and to study the modulational instability of quasi-monochromatic wavetrains. Guided by these weakly nonlinear results, fully nonlinear steady and time-dependent computations are performed by employing a conformal mapping technique. Bifurcation mechanisms and typical profiles of solitary waves for different underlying shear currents are presented in detail. It is shown that even when small-amplitude solitary waves are not predicted by the weakly nonlinear theory, we can numerically find large-amplitude solitary waves in the fully nonlinear equations. Time-dependent simulations are carried out to confirm the modulational stability results and illustrate possible outcomes of the nonlinear evolution in unstable cases
Plasma arginine vasopressin concentrations in epileptics under monotherapy
Plasma arginine vasopressin concentrations were determined by radio-immunoassay in 112 adult epileptics who were taking carbamazepine, phenytoin, primidone, or sodium valproate in long-term monotherapy, and in 19 controls. No significant difference was found between the groups, but some epileptics taking carbamazepine and primidone showed low values. Serum
concentrations of carbamazepine did not correlate with the concentrations of plasma arginine vasopressin.
In conclusion, there was no evidence of a stimulating
effect of chronic carbamazepine medication or a special inhibiting effect of phenytoin on the release of vasopressin arginine from the posterior pituitary
German Lexical Personality Factors: Relations with the HEXACO Model
We correlated the scales of the HEXACO Personality Inventory (HEXACO-PI) with adjective scale markers of factors previously obtained in indigenous lexical studies of personality structure in the German language. Self-ratings obtained from a sample of 323 German participants showed a pattern of strong convergent and weak discriminant correlations, supporting the content-based interpretation of the German lexical factors in terms of the HEXACO dimensions. Notably, convergent correlations were strong for both the broader and the narrower variants of the Honesty-Humility factor as observed in German lexical studies. Also, convergent correlations for HEXACO Openness to Experience were, as expected, stronger for German adjectives describing a creative and intellectual orientation than for German adjectives describing intellectual ability. Copyright © 2006 John Wiley & Sons, Ltd
The first GCT camera for the Cherenkov Telescope Array
The Gamma Cherenkov Telescope (GCT) is proposed to be part of the Small Size
Telescope (SST) array of the Cherenkov Telescope Array (CTA). The GCT
dual-mirror optical design allows the use of a compact camera of diameter
roughly 0.4 m. The curved focal plane is equipped with 2048 pixels of
~0.2{\deg} angular size, resulting in a field of view of ~9{\deg}. The GCT
camera is designed to record the flashes of Cherenkov light from
electromagnetic cascades, which last only a few tens of nanoseconds. Modules
based on custom ASICs provide the required fast electronics, facilitating
sampling and digitisation as well as first level of triggering. The first GCT
camera prototype is currently being commissioned in the UK. On-telescope tests
are planned later this year. Here we give a detailed description of the camera
prototype and present recent progress with testing and commissioning.Comment: In Proceedings of the 34th International Cosmic Ray Conference
(ICRC2015), The Hague, The Netherlands. All CTA contributions at
arXiv:1508.0589
Revised estimates of ocean-atmosphere CO2 flux are consistent with ocean carbon inventory
This is the final version. Available from the publisher via the DOI in this record.The ocean is a sink for ~25% of the atmospheric CO2 emitted by human activities, an amount
in excess of 2 petagrams of carbon per year (PgC yr−1
). Time-resolved estimates of global
ocean-atmosphere CO2 flux provide an important constraint on the global carbon budget.
However, previous estimates of this flux, derived from surface ocean CO2 concentrations,
have not corrected the data for temperature gradients between the surface and sampling at a
few meters depth, or for the effect of the cool ocean surface skin. Here we calculate a time
history of ocean-atmosphere CO2 fluxes from 1992 to 2018, corrected for these effects.
These increase the calculated net flux into the oceans by 0.8–0.9 PgC yr−1
, at times doubling
uncorrected values. We estimate uncertainties using multiple interpolation methods, finding
convergent results for fluxes globally after 2000, or over the Northern Hemisphere
throughout the period. Our corrections reconcile surface uptake with independent estimates
of the increase in ocean CO2 inventory, and suggest most ocean models underestimate
uptake.European Space AgencyEuropean CommissionBONUS Secretariat (EEIG
Whole-genome sequencing for national surveillance of Shiga toxin–producing Escherichia coli O157
Background. National surveillance of gastrointestinal pathogens, such as Shiga toxin–producing Escherichia coli O157 (STEC O157), is key to rapidly identifying linked cases in the distributed food network to facilitate public health interventions. In this study, we used whole-genome sequencing (WGS) as a tool to inform national surveillance of STEC O157 in terms of identifying linked cases and clusters and guiding epidemiological investigation. Methods. We retrospectively analyzed 334 isolates randomly sampled from 1002 strains of STEC O157 received by the Gastrointestinal Bacteria Reference Unit at Public Health England, Colindale, in 2012. The genetic distance between each isolate, as estimated by WGS, was calculated and phylogenetic methods were used to place strains in an evolutionary context. Results. Estimates of linked clusters representing STEC O157 outbreaks in England and Wales increased by 2-fold when WGS was used instead of traditional typing techniques. The previously unidentified clusters were often widely geographically distributed and small in size. Phylogenetic analysis facilitated identification of temporally distinct cases sharing common exposures and delineating those that shared epidemiological and temporal links. Comparison with multi locus variable number tandem repeat analysis (MLVA) showed that although MLVA is as sensitive as WGS, WGS provides a more timely resolution to outbreak clustering. Conclusions. WGS has come of age as a molecular typing tool to inform national surveillance of STEC O157; it can be used in real time to provide the highest strain-level resolution for outbreak investigation. WGS allows linked cases to be identified with unprecedented specificity and sensitivity that will facilitate targeted and appropriate public health investigations
The Hydro-electro-thermal Performance of Air-cooled, Open-cathode Polymer Electrolyte Fuel Cells: Combined Localised Current Density, Temperature and Water Mapping
In situ diagnostic techniques provide a means of understanding the internal workings of fuel cells so that improved designs and operating regimes can be identified. Here, a novel metrology approach is reported that combines current and temperature mapping with water visualisation using neutron radiography.
The approach enables a hydro-electro-thermal performance map to be generated that is applied to an air-cooled, open-cathode polymer electrolyte fuel cell. This type of fuel cell exhibits a particularly interesting coupled relationship between water, current and heat, as the air supply has the due role of cooling the stack as well as providing the cathode reactant feed via a single source. It is found that water predominantly accumulates under the cooling channels (thickness of 70-100 μm under the cooling channels and 5-25 μm in the active channels at 0.5 A cm−2), in a similar fashion to the lands in a closed-cathode design, but contrary to passive open-cathode systems. The relationship between current, temperature and water accumulation is complex and highly dependent on location within the cell. However, there is a general trend that higher currents and cooling limitations, especially above 0.7 A cm−2 and below 3.9 × 10−3 m3 s−1, leads to temperatures above 60 °C, which dehydrate the membrane (water thickness of 10-25 um) and the cell operates below 0.5 V
Optimisation of air cooled, open-cathode fuel cells: Current of lowest resistance and electro-thermal performance mapping
Selecting the ideal operating point for a fuel cell depends on the application and consequent trade-off between efficiency, power density and various operating considerations. A systematic methodology for determining the optimal operating point for fuel cells is lacking; there is also the need for a single-value metric to describe and compare fuel cell performance. This work shows how the ‘current of lowest resistance’ can be accurately measured using electrochemical impedance spectroscopy and used as a useful metric of fuel cell performance. This, along with other measures, is then used to generate an ‘electro-thermal performance map’ of fuel cell operation. A commercial air-cooled open-cathode fuel cell is used to demonstrate how the approach can be used; in this case leading to the identification of the optimum operating temperature of ∼45 °C
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