A one dimensional model for the prediction of extraction yields in a two phases modified twin-screw extruder

Solid/liquid extraction is performed on raw plant substrate with a modified twin-screw extruder (TSE) used as a thermo-mecanochemical reactor. Visual observations and experimental residence time distributions (RTD) are used to develop a solid transport model based on classical chemical engineering method. Modeled and experimental residence times are compared. The transport model is then coupled with a reactive extraction model in order to predict extraction yields

Field-Driven Domain-Wall Dynamics in GaMnAs Films with Perpendicular Anisotropy

We combine magneto-optical imaging and a magnetic field pulse technique to study domain wall dynamics in a ferromagnetic (Ga,Mn)As layer with perpendicular easy axis. Contrary to ultrathin metallic layers, the depinning field is found to be smaller than the Walker field, thereby allowing for the observation of the steady and precessional flow regimes. The domain wall width and damping parameters are determined self-consistently. The damping, 30 times larger than the one deduced from ferromagnetic resonance, is shown to essentially originate from the non-conservation of the magnetization modulus. An unpredicted damping resonance and a dissipation regime associated with the existence of horizontal Bloch lines are also revealed

Field-induced domain wall propagation: beyond the one-dimensional model

We have investigated numerically the field-driven propagation of perpendicularly magnetized ferromagnetic layers. It was then compared to the historical one-dimensional domain wall (DW) propagation model widely used in spintronics studies of magnetic nanostructures. In the particular regime of layer thickness (h) of the order of the exchange length, anomalous velocity peaks appear in the precessional regime, their shape and position shifting with h. This has also been observed experimentally. Analyses of the simulations show a distinct correlation between the curvature of the DW and the twist of the magnetization vector within it, and the velocity peak. Associating a phenomenological description of this twist with a four-coordinate DW propagation model, we reproduce very well these kinks and show that they result from the torque exerted by the stray field created by the domains on the twisted magnetization. The position of the peaks is well predicted from the DW's first flexural mode frequency, and depends strongly on the layer thickness. Comparison of the proposed model to DW propagation data obtained on dilute semiconductor ferromagnets GaMnAs and GaMnAsP sheds light on the origin of the measured peaks

Biodégradation anaérobie de l'acide crotonique par une biomasse bactérienne spécialisée dans la dégradation de l'acide butyrique

La connaissance, actuellement très limitée, du métabolisme des bactéries acétogènes intervenant dans la biodégradation anaérobie de l'acide butyrique et d'un de ses sous-produits, l'acide crotonique, est à l'origine de cette étude.Après avoir mis au point un réacteur anaérobie à biomasse fixée, cette dernière a, dans un premier temps, été adaptée à la biodégradation exclusive du butyrate. La dégradation du crotonate a ensuite été étudiée, selon différents protocoles expérimentaux (pulses de crotonate en alimentation continue avec du butyrate puis alimentation continue avec du crotonate). Des injections de crotonate ont également été effectuées en circuit fermé, avec une biomasse adaptée dans un premier temps à la dégradation d'un mélange d'AGV, le réacteur étant ensuite alimenté avec du propionate puis du butyrate seuls.Contrairement à ce que laissait penser la bibliographie, il a été constaté que les bactéries adaptées à la dégradation exclusive du butyrate sons très rapidement à même de dégrader le crotonate.Les résultats obtenus permettent d'approcher les spécificités bactériennes, la voie catabolique suivie par le crotonate, son mode de régulation enzymatique et les équilibres qui la gouvernent. C'est ainsi qu'il est possible de proposer un modèle explicatif relativement simple du mécanisme de biodégradation du crotonate.Volatile Fatty Acids (VFAs) are intermediate metabolites formed in the anaerobic biodegradation of organic matter. They are commonly found in sewage, municipal sanitary landfill leachate and effluents from agricultural and food-processing industries. A good knowledge of the microorganisms involved in VFA biodegradation is necessary to operate satisfactory biotreatment of those effluents.The objective of the present study is to better understand the metabolism of the anaerobic bacteria responsible for the degradation of butyric acid and one of its metabolites (crotonic acid), which is still poorly known.Syntrophomonaswolfei is one of the few butyrate-degrading acetogenic bacteria that bas been documented. First studios have shown that this microorganism is not capable of degrading crotonic acid (MCINERNEY et al., 1979, 1981). This is surprising since crotonyl-Coenzyme A, in its activated form, is an intermediate metabolite of n-butyrate ß-oxidation, which is the most common mechanism of butyrate biodegradation. In addition, ß-oxidatlon of crotonate is thermodynamically possible, even under standard conditions.These observations are al the origin of the present study, which investigates the anaerobic biodegradation of crotonate. Other Investigators have followed a similar approach and isolated S. wolfei in pure culture on crotonate.The degradation of crotonate was studied in a bench-scale up-flow anaerobic filter of twenty liters, operated in the dark, at 35 °C.A first set of experiments was carried out with a biomass exclusively adapted to the biodegradation of butyrate. Heat-expansed vermiculite was used as a packing medium. Various experimental protocols were successive followed. First, pulses of crotonate were injected into the reactor under conditions of continuous feeding with butyrate, and then, the reactor was continuously fed with crotonate. The objective was to determine whether a bacterial population exclusively adapted to butyrate biodegradation would be capable of degrading crotonate.It was found that crotonate was actually biodegraded in the reactor. Woth the first protocol, when pulses of crotonate were injected into the reactor, crotonate was totally removed in 55 hours (fig. 3). Butyrate and acetate concentrations increased as crotonate was degraded, but no significant increase in biogas production was observed. On the other hand, under the same conditions, it was found that iso-butyrate was not degraded, which is consistent with other published data (MCINERNEY et al., 1979, 1981 ; STIEB and SCHINK, 1985,1989).With the second protocol (continuous feeding with crotonate at 5.2 gg/l), crotonate was totally biodegraded in 48 hours after a 24 hours lag period. This biodegradation resulted in the accumulation of acetate and, in a lower extend, butyrate (fig.4).Following this stage, the reactor was fed with a higher crotonate concentration (12 g/l), and it was observed that crotonate was totally degraded in 20 hours, without any lag period (fig. 5).These results showed that butyrate-degrading bacteria were capable of degrading crotonate effectively after a short period of adaptation.Further experiments were conducted with a biomass previously adapted to the degradation of a mixture of VFAs (acetate, propionate, iso-butyrate, butyrate and caproate). Berl saddles were used as a support for bacterial growth. The reactor was operated in a recirculated batch mode and spiked with crotonate. Finally, the reactor was successively fed for four weeks with propionate and for two weeks with butyrate, before being spiked with crotonate.In all these experiments, crotonate biodegradation was observed, but, in contrast to the results obtained with the “vermiculite reactor”, no butyrate accumulation occured (fig.6).These results show that a bacterial population adapted to the degradation of a mixture of VFAs or to the degradation of individual VFAs such as propionate and n-butyrate, is capable of degrading crotonate.Based on the present study and on literature data, the following mechanism can be proposed for the biodegradation of crotonate (fig.7). The first stage is the activation of crotonate into crotonyl-Coenzyme A by an acetyl-CoA/crotonyl-CoA transferase, as recently isolated from S. wolfei (BEATY and MCINERNEY, 1987). When present at low concentrations, crotonate is probably directly degraded into acetate, as shown by the results obtained with the “selles de Berl reactor”, in which no intermediate metabolite has been detected. At higher concentrations, enzymatic sites may be saturated and an equilibrium be established with butyrate, which is then released into the medium. This has been shown by the accumulation of butyrate under conditions of continuous feeding with crotonate. In addition, another intermediate metabolite has been formed, which has not been identified in the present study. This product is most probably poly-ß-hydroxy-butyrate, which has been found in S.wolfei (MCINERNEY et al, 1979) although if is not very common in chemiotrophic bacteria

Two phase residence time distribution in a modified twin screw extruder

Biomass fractionation is performed with a modified Clextral twin-screw extruder used as a thermo-mechano-chemical reactor. This new process is firstly analyzed. Visual observations, residence time distributions, and global mass balances are used to obtain information about the process phenomena and their coupling. Residence time distributions (RTD) classical models are adopted to represent the experimental plots. The influence of continuous and discrete process parameters upon the RTD of the solid and liquid phases is analyzed

Determination of the micromagnetic parameters in (Ga,Mn)As using domain theory

The magnetic domain structure and magnetic properties of a ferromagnetic (Ga,Mn)As epilayer with perpendicular magnetic easy-axis are investigated. We show that, despite strong hysteresis, domain theory at thermodynamical equilibrium can be used to determine the micromagnetic parameters. Combining magneto-optical Kerr microscopy, magnetometry and ferromagnetic resonance measurements, we obtain the characteristic parameter for magnetic domains $\lambda_c$, the domain wall width and specific energy, and the spin stiffness constant as a function of temperature. The nucleation barrier for magnetization reversal and the Walker breakdown velocity for field-driven domain wall propagation are also estimated

Nucleation and Collapse of the Superconducting Phase in Type-I Superconducting Films

The phase transition between the intermediate and normal states in type-I superconducting films is investigated using magneto-optical imaging. Magnetic hysteresis with different transition fields for collapse and nucleation of superconducting domains is found. This is accompanied by topological hysteresis characterized by the collapse of circular domains and the appearance of lamellar domains. Magnetic hysteresis is shown to arise from supercooled and superheated states. Domain-shape instability resulting from long-range magnetic interaction accounts well for topological hysteresis. Connection with similar effects in systems with long-range magnetic interactions is emphasized

Scale invariant correlations and the distribution of prime numbers

Negative correlations in the distribution of prime numbers are found to display a scale invariance. This occurs in conjunction with a nonstationary behavior. We compare the prime number series to a type of fractional Brownian motion which incorporates both the scale invariance and the nonstationary behavior. Interesting discrepancies remain. The scale invariance also appears to imply the Riemann hypothesis and we study the use of the former as a test of the latter.Comment: 13 pages, 8 figures, version to appear in J. Phys.

Impeded Growth of Magnetic Flux Bubbles in the Intermediate State Pattern of Type I Superconductors

Normal state bubble patterns in Type I superconducting Indium and Lead slabs are studied by the high resolution magneto-optical imaging technique. The size of bubbles is found to be almost independent of the long-range interaction between the normal state domains. Under bubble diameter and slab thickness proper scaling, the results gather onto a single master curve. On this basis, in the framework of the "current-loop" model [R.E. Goldstein, D.P. Jackson and A.T. Dorsey, Phys. Rev. Lett. 76, 3818 (1996)], we calculate the equilibrium diameter of an isolated bubble resulting from the competition between the Biot-and-Savart interaction of the Meissner current encircling the bubble and the superconductor-normal interface energy. A good quantitative agreement with the master curve is found over two decades of the magnetic Bond number. The isolation of each bubble in the superconducting matrix and the existence of a positive interface energy are shown to preclude any continuous size variation of the bubbles after their formation, contrary to the prediction of mean-field models.Comment: \'{e}quipe Nanostructures Quantique

Lubrication at physiological pressures by polyzwitterionic brushes

The very low sliding friction at natural synovial joints, which have friction coefficients of mu < 0.002 at pressures up to 5 megapascals or more, has to date not been attained in any human-made joints or between model surfaces in aqueous environments. We found that surfaces in water bearing polyzwitterionic brushes that were polymerized directly from the surface can have m values as low as 0.0004 at pressures as high as 7.5 megapascals. This extreme lubrication is attributed primarily to the strong hydration of the phosphorylcholine-like monomers that make up the robustly attached brushes, and may have relevance to a wide range of human-made aqueous lubrication situations