Angle-susceptible sensing metasurface in terahertz regime

Trabajo presentado a la 3rd International Conference "Terahertz and Microwave Radiation: Generation, Detection and Applications (TERA 2018)", celebrada en Rusia del 22 al 25 de octubre de 2018Nowadays thin-film coatings and structures are widely used in advanced industrial and scientific ap-plications that makes the tasks of thin-film sensing highly demanded in practice. Last decade, stimulated by progress in terahertz (THz) instrumentation, a keen interest has been attracted to the THz spectral range to develop its potential for detecting and measuring properties of thin films. The THz radiation can be an alternative to visible and IR waves when examining optically opaque coatings. Meanwhile, due to a rela-tively large wavelength λ, the conventional spectro-scopic methods (TDS-, FDS-, FTIR-, BWO-based) are ill-suited for direct characterization of films with the thickness d of about 2−4 orders of magnitude smaller than λ. This problem can be solved with met-amaterials, in particular, with plasmonic metasurfaces (PMSs) [1–5]. The plasmonic resonance exhibits a high sensitivity of its spectral response to the dielec-tric environment due to a strong field localization what makes possible measuring of analyte layers sat-isfying d << λ condition. The traditional approach of THz thin-film sensing with PMSs is based on detecting a frequency shift of the resonance when the analyte is deposited onto the PMS. In this work, we present the idea to substitute THz spectral measurements for tracking the PMS re-sponse at a fixed wavelength upon changing the incidence angle θ of the exciting THz beam. This concept works well for the PMS with a narrowband resonance sensitive to θ. The results of the numerical investigations and experimental study of such PMS designed as a single-layer array of hexagon-shaped annular slots (Fig. 1) with angle-susceptible resonant transmission near 0.85 THz are presented.The work is partially supported by the Russian Foundation for Basic Research (Project #17-32-80039)

Detailed study on optical properties of Li2B4O7 for down conversion to millimeter waves

For the first time, we measured the laser damage threshold of LB4 nonlinear crystal (≥ 10 TW/cm2) for an fs- (60 fs, 950 nm) pulses. Refractive index components for a THz range 0.15-1.6 THz were measured and carefully reapproximated in terms of Sellmeier dispersion equations. Using the equations and the measured optical breakdown threshold, the efficiency of THz radiation generation is estimated for all possible types of three wave interactions. For e–e → e type of interaction deff = (2d15 + d31)cos2sin + d33sin3, o–o → e type deff = d31sin, and for o–e → o type deff = d15sin. The angle at which the phase matching conditions are achieved for THz radiation generation at frequencies < 1.5 THz is ≤ 10. Small values of the phase matching angles and, accordingly, small values of effective nonlinear coefficients explain the lack of experimental studies on the THz generation. The extremely high optical breakdown threshold and high atmospheric transmission in the longwavelength part of the THz range overcompensate low efficient nonlinear coefficients of LB4. Which makes it prospective for long trace high sensitivity probing of the atmosphere composition and parameters

Detailed study on optical properties of Li2B4O7 for down-conversion to millimeter waves

Optical properties of single axes Li2B4O7 (LB4) crystal are defined at room temperature in the spectral range 0.03˗0.5 THz. Dispersion of the refractive index components are approximated in the form of Sellmeier equations. Dispersion properties were used to determine phase-matching conditions for THz wave generation by collinear difference frequency generation processes. To the damage threshold under the pump by train of hundreds of 60 fs pulses of Ti:sapphire laser operating at 950 nm is found to be 250 TW/cm2, as well as the coherence length and efficiency of all possible types of three wave interactions are defined

THz sensing with anomalous extraordinary optical transmission hole arrays

Subwavelength hole array (HA) metasurfaces support the so-called extraordinary optical transmission (EOT) resonance that has already been exploited for sensing. In this work, we demonstrate the superior performance of a different resonant regime of HA metasurfaces called anomalous EOT, by doing a thorough numerical and experimental study of its ability in thin-film label-free sensing applications in the terahertz (THz) band. A comprehensive analysis using both the regular and anomalous EOT resonances is done by depositing thin layers of dielectric analyte slabs of different thicknesses on the structures in different scenarios. We carry out a detailed comparison and demonstrate that the best sensing performance is achieved when the structure operates in the anomalous EOT resonance and the analyte is deposited on the non-patterned side of the metasurface, improving by a factor between 2 and 3 the results of the EOT resonance in any of the considered scenarios. This can be explained by the comparatively narrower linewidth of the anomalous EOT resonance. The results presented expand the reach of subwavelength HAs for sensing applications by considering the anomalous EOT regime that is usually overlooked in the literature.This research was funded by the Spanish Ministerio de Economía y Competitividad with European Union Fondo Europeo de Desarrollo Regional (FEDER) funds, grant number TEC2014-51902-C2-2-R. The work was partially supported by the Russian Foundation for Basic Research (Project No. 17-32-80039, experimental study; Project No. 18-29-20066, technological implementation)

Dielectric properties of BiB3O6 crystal in the sub-THz range

We present the thorough studies of dielectric properties of BiB3O6 (BIBO) crystal in the sub-THz range. We observe a large birefringence Δn = nZ −nX = 1.5 and the values of absorption coefficients of all three axes to be less than 0.5 cm−1. The difference from visible range in angle ϕ between the axes z and X is found to be more than 6°. The simulated phase-matching curves show the optimal value of the angle θ to be around 25.5°±1° for an efficient millimeter-wave generation under the pump of 1064 nm laser radiation

Millimetre-wave range optical properties of BIBO

We present the thorough studies of optical properties of BiB3O6 (BIBO) crystal in the millimeter-wave (subterahertz) range. We observe a large birefringence Δn = nZ −nX = 1.5 and the values of absorption coefficients of all three axes to be less than 0.5 cm−1 at the frequency of 0.3 THz. The difference from visible range in angle ϕ between the dielectric axis z and crystallophysical axis X is found to be more than 6°. The simulated phase-matching curves in the xz plane of the crystal show the optimal value of the angle θ to be around 25.5°±1° for an efficient millimeter-wave generation under the pump of 1064 nm laser radiation

Potential of sub-THz-wave generation in Li2B4O7 nonlinear crystal at room and cryogenic temperatures

Due to their high optical damage threshold, borate crystals can be used for the efficient nonlinear down-conversion of terawatt laser radiation into the terahertz (THz) frequency range of the electromagnetic spectrum. In this work, we carried out a thorough study of the terahertz optical properties of the lithium tetraborate crystal (Li2B4O7; LB4) at 295 and 77 K. Approximating the terahertz refractive index in the form of Sellmeier’s equations, we assessed the possibility of converting the radiation of widespread high-power laser sources with wavelengths of 1064 and 800 nm, as well as their second and third harmonics, into the THz range. It was found that four out of eight types of three-wave mixing processes are possible. The conditions for collinear phase matching were fulfilled only for the o - e -o type of interaction, while cooling the crystal to 77 K did not practically affect the phase-matching curves. However, a noticeable increase of birefringence in the THz range with cooling (from 0.12 to 0.16) led to an increase in the coherence length for o-o-e and e-e-e types of interaction, which are potentially attractive for the down-conversion of ultrashort laser pulses