303 research outputs found
In-situ early age hydration of cement-based materials by synchrotron X-ray powder diffraction
Cement based binders are building materials of worldwide importance. Since these samples are very complex, the knowledge/control of their mineralogical composition are essential to design and predict materials with specific/improved performance. Rietveld quantitative phase analysis (RQPA) allows the quantification of crystalline phases and, when combined with specific methodologies, as the addition of an internal standard or the external standard approach (G-factor), amorphous and non-crystalline phases can also be quantified. However, to carry out a proper RQPA in hydrated cementitious-materials, a good powder diffraction pattern is necessary. In this work, synchrotron X-ray powder diffraction (SXRPD) has been used, allowing in-situ measurements during the early-age hydration process.
This work deals with the early hydration study of cement-based materials. The studied samples were: a laboratory-prepared belite calcium sulphoaluminate (BCSAF) clinker (non-active) mixed with 10wt% gypsum, labelled G10B0; two active laboratory-prepared BCSAF clinkers (activated with 2wt% borax), one mixed with 10wt% gypsum and the other one with 10wt% monoclinic-bassanite, hereafter named G10B2 and B10B2, respectively; and an environmentally-friendly cement sample from Henkel, composed of bassanite mixed with 15wt% Portland cement and 10wt% Metakaolin, labelled H1.
Anhydrous G10B0 contains beta-belite and orthorhombic-ye'elimite as main phases, while alpha'H-belite and pseudo-cubic-ye'elimite are stabilized in G10B2 and B10B2, with the corresponding sulphate source. Anhydrous H1 contains monoclinic and hexagonal bassanite and alite as main phases.
Ye'elimite, in the non-active BCSAF cement pastes, dissolves at a higher pace than in the active one (degree of reaction is α~25% and α~10% at 1 h, respectively) (both prepared with gypsum), with the corresponding differences in ettringite crystallisation (degree of precipitation is α~30% and α~5%, respectively).
Moreover, the type of sulphate source has important consequences on the hydration of the active BCSAF cement pastes. Bassanite is quickly dissolved and it precipitates as gypsum within the first hour of hydration (in B10B2). At that time, ettringite starts to crystallize, and after 12 hours is almost fully crystallized, similar to G10B2.
In H1, bassanite transforms into gypsum within the first hour, being the principal hydration product; ettringite starts to be formed just after few hydration minutes.
These results are crucial in the understanding and development of improved cement materials.Universidad de MĂĄlaga. Campus de Excelencia Internacional AndalucĂa Tech
Separated cross sections in \pi^0 electroproduction at threshold at Q^2 = 0.05 GeV^2/c^2
The differential cross sections \sigma_0=\sigma_T+\epsilon \sigma_L,
\sigma_{LT}, and \sigma_{TT} of \pi^0 electroproduction from the proton were
measured from threshold up to an additional center of mass energy of 40 MeV, at
a value of the photon four-momentum transfer of Q^2= 0.05 GeV^2/c^2 and a
center of mass angle of \theta=90^\circ. By an additional out-of-plane
measurement with polarized electrons \sigma_{LT'} was determined. This showed
for the first time the cusp effect above the \pi^+ threshold in the imaginary
part of the s-wave. The predictions of Heavy Baryon Chiral Perturbation Theory
are in disagreement with these data. On the other hand, the data are somewhat
better predicted by the MAID phenomenological model and are in good agreement
with the dynamical model DMT.Comment: 6 pages, 4 figure
Measurements of the \gamma * p --> \Delta(1232) reaction at low Q2
We report new p measurements in the
resonance at the low momentum transfer region utilizing the
magnetic spectrometers of the A1 Collaboration at MAMI. The mesonic cloud
dynamics are predicted to be dominant and appreciably changing in this region
while the momentum transfer is sufficiently low to be able to test chiral
effective calculations. The results disagree with predictions of constituent
quark models and are in reasonable agreement with dynamical calculations with
pion cloud effects, chiral effective field theory and lattice calculations. The
reported measurements suggest that improvement is required to the theoretical
calculations and provide valuable input that will allow their refinements
New detectors for the kaon and hypernuclear experiments with KaoS at MAMI and with PANDA at GSI
The KaoS spectrometer at the Mainz Microtron MAMI, Germany, is perceived as
the ideal candidate for a dedicated spectrometer in kaon and hypernuclei
electroproduction. KaoS will be equipped with new read-out electronics, a
completely new focal plane detector package consisting of scintillating fibres,
and a new trigger system. First prototypes of the fibre detectors and the
associated new front-end electronics are shown in this contribution. The Mainz
hypernuclei research program will complement the hypernuclear experiments at
the planned FAIR facility at GSI, Germany. At the proposed antiproton storage
ring the spectroscopy of double Lambda hypernuclei is one of the four main
topics which will be addressed by the PANDA Collaboration. The experiments
require the operation of high purity germanium (HPGe) detectors in high
magnetic fields (B= 1T) in the presence of a large hadronic background. The
performance of high resolution Ge detectors in such an environment has been
investigated.Comment: Presentation at International Symposium on the Development of
Detectors for Particle, Astroparticle and Synchrotron Radiation Experiments,
Stanford, Ca (SNIC06), 6 pages, LaTeX, 11 eps figure
The f_LT Response Function of D(e,e'p)n at Q^2=0.33(GeV/c)^2
The interference response function f_LT (R_LT) of the D(e,e'p)n reaction has
been determined at squared four-momentum transfer Q^2 = 0.33 (GeV/c)^2 and for
missing momenta up to p_miss= 0.29 (GeV/c). The results have been compared to
calculations that reproduce f_LT quite well but overestimate the cross sections
by 10 - 20% for missing momenta between 0.1 (GeV/c) and 0.2 (GeV/c) .Comment: 12 Pages, 10 figure
Coherent \pi^0 threshold production from the deuteron at Q^2 = 0.1 GeV^2/c^2
First data on coherent threshold \pi^0 electroproduction from the deuteron
taken by the A1 Collaboration at the Mainz Microtron MAMI are presented. At a
four-momentum transfer of q^2=-0.1 GeV^2/c^2 the full solid angle was covered
up to a center-of-mass energy of 4 MeV above threshold. By means of a
Rosenbluth separation the longitudinal threshold s wave multipole and an upper
limit for the transverse threshold s wave multipole could be extracted and
compared to predictions of Heavy Baryon Chiral Perturbation Theory.Comment: 7 pages, 7 figures, latex2
Lowest Q^2 Measurement of the gamma*p -> Delta Reaction: Probing the Pionic Contribution
To determine nonspherical angular momentum amplitudes in hadrons at long
ranges (low Q^2), data were taken for the p(\vec{e},e'p)\pi^0 reaction in the
Delta region at Q^2=0.060 (GeV/c)^2 utilizing the magnetic spectrometers of the
A1 Collaboration at MAMI. The results for the dominant transition magnetic
dipole amplitude and the quadrupole to dipole ratios at W=1232 MeV are:
M_{1+}^{3/2} = (40.33 +/- 0.63_{stat+syst} +/- 0.61_{model})
(10^{-3}/m_{\pi^+}),Re(E_{1+}^{3/2}/M_{1+}^{3/2}) = (-2.28 +/- 0.29_{stat+syst}
+/- 0.20_{model})%, and Re(S_{1+}^{3/2}/M_{1+}^{3/2}) = (-4.81 +/-
0.27_{stat+syst} +/- 0.26_{model})%. These disagree with predictions of
constituent quark models but are in reasonable agreement with lattice
calculations with non-linear (chiral) pion mass extrapolations, with chiral
effective field theory, and with dynamical models with pion cloud effects.
These results confirm the dominance, and general Q^2 variation, of the pionic
contribution at large distances.Comment: 6 pages, 3 figures, 1 tabl
A measurement of the axial form factor of the nucleon by the p(e,e'pi+)n reaction at W=1125 MeV
The reaction p(e,e'pi+)n was measured at the Mainz Microtron MAMI at an
invariant mass of W=1125 MeV and four-momentum transfers of Q^2=0.117, 0.195
and 0.273 (GeV/c)^2. For each value of Q^2, a Rosenbluth separation of the
transverse and longitudinal cross sections was performed. An effective
Lagrangian model was used to extract the `axial mass' from experimental data.
We find a value of M_A=(1.077+-0.039) GeV which is (0.051+-0.044) GeV larger
than the axial mass known from neutrino scattering experiments. This is
consistent with recent calculations in chiral perturbation theory.Comment: 14 pages, 5 figures, uses elsart.cl
Final State Interaction Effects in pol 3He(pol e,e'p)
Asymmetries in quasi-elastic pol 3He(pol e,e'p) have been measured at a
momentum transfer of 0.67 (GeV/c)^2 and are compared to a calculation which
takes into account relativistic kinematics in the final state and a
relativistic one-body current operator. With an exact solution of the Faddeev
equation for the 3He-ground state and an approximate treatment of final state
interactions in the continuum good agreement is found with the experimental
data.Comment: 11 pages, 6 figures, submitted to Phys. Lett. B, revised version,
sensitivity study to relativity and NN-potential adde
Measurement of Rlt and Atl in the 4He(e,e'p)3H Reaction at pmiss of 130-300 MeV/c
We have measured the 4He(e,e'p)3H reaction at missing momenta of 130-300
MeV/c using the three-spectrometer facility at the Mainz microtron MAMI. Data
were taken in perpendicular kinematics to allow us to determine the response
function Rlt and the asymmetry term Atl. The data are compared to both
relativistic and non-relativistic calculations.Comment: To be published in the European Physical Journal
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