Discovery of Water Vapor in the High-redshift Quasar APM 08279+5255 at z = 3.91

We report a detection of the excited 2_(20)-2_(11) rotational transition of para-H_2O in APM 08279+5255 using the IRAM Plateau de Bure Interferometer. At z = 3.91, this is the highest-redshift detection of interstellar water to date. From large velocity gradient modeling, we conclude that this transition is predominantly radiatively pumped and on its own does not provide a good estimate of the water abundance. However, additional water transitions are predicted to be detectable in this source, which would lead to an improved excitation model. We also present a sensitive upper limit for the hydrogen fluoride (HF) J = 1-0 absorption toward APM 08279+5255. While the face-on geometry of this source is not favorable for absorption studies, the lack of HF absorption is still puzzling and may be indicative of a lower fluorine abundance at z = 3.91 compared with the Galactic interstellar medium

Models for Dense Molecular Cloud Cores

We present a detailed model for the thermal balance, chemistry, and radiative transfer within quiescent dense molecular cloud cores that contain a central protostar. Large variations in the gas temperature are expected to affect the gas-phase chemistry dramatically; with the predicted H2O abundance varying by more than a factor of 1000 within cloud cores. Based on our predicitions for the thermal and chemical structure of the cores, we have constructed self-consistent radiative transfer models to compute line strengths and profiles for transitions of various isotopomers of CO, H2O, and OI. We predict the high lying transitions of water to be in absorption, and low gain maser emission at 183 GHz. We predict the 63 micron line of OI to be in absorption against the continuum for many sources. Finally, our model can also account successfully for recent ISO observations of absorption in rovibrational transitions of water toward the source AFGL 2591.Comment: 36 pages, 18 figures, LaTex, Accepted for publication by ApJ (11/97

A Herschel/HIFI Legacy Survey of HF and H2O in the Galaxy: Probing Diffuse Molecular Cloud Chemistry

We combine Herschel observations of a total of 12 sources to construct the most uniform survey of HF and H2O in our Galactic disk. Both molecules are detected in absorption along all sight lines. The high spectral resolution of the Heterodyne Instrument for the Far-Infrared (HIFI) allows us to compare the HF and H2O distributions in 47 diffuse cloud components sampling the disk. We find that the HF and H2O velocity distributions follow each other almost perfectly and establish that HF and H2O probe the same gas-phase volume. Our observations corroborate theoretical predictions that HF is a sensitive tracer of H2 in diffuse clouds, down to molecular fractions of only a few percent. Using HF to trace H2 in our sample, we find that the N(H2O)-to-N(HF) ratio shows a narrow distribution with a median value of 1.51. Our results further suggest that H2O might be used as a tracer of H2 -within a factor 2.5- in the diffuse interstellar medium. We show that the measured factor of ~2.5 variation around the median is driven by true local variations in the H2O abundance relative to H2 throughout the disk. The latter variability allows us to test our theoretical understanding of the chemistry of oxygen-bearing molecules in the diffuse gas. We show that both gas-phase and grain-surface chemistry are required to reproduce our H2O observations. This survey thus confirms that grain surface reactions can play a significant role in the chemistry occurring in the diffuse interstellar medium n_H < 1000 cm^-3.Comment: 53 pages; 12 figures, accepted for publication in ApJ main journa