36,255 research outputs found
Origin of conductivity cross over in entangled multi-walled carbon nanotube network filled by iron
A realistic transport model showing the interplay of the hopping transport
between the outer shells of iron filled entangled multi-walled carbon nanotubes
(MWNT) and the diffusive transport through the inner part of the tubes, as a
function of the filling percentage, is developed. This model is based on
low-temperature electrical resistivity and magneto-resistance (MR)
measurements. The conductivity at low temperatures showed a crossover from
Efros-Shklovski (E-S) variable range hopping (VRH) to Mott VRH in 3 dimensions
(3D) between the neighboring tubes as the iron weight percentage is increased
from 11% to 19% in the MWNTs. The MR in the hopping regime is strongly
dependent on temperature as well as magnetic field and shows both positive and
negative signs, which are discussed in terms of wave function shrinkage and
quantum interference effects, respectively. A further increase of the iron
percentage from 19% to 31% gives a conductivity crossover from Mott VRH to 3D
weak localization (WL). This change is ascribed to the formation of long iron
nanowires at the core of the nanotubes, which yields a long dephasing length
(e.g. 30 nm) at the lowest measured temperature. Although the overall transport
in this network is described by a 3D WL model, the weak temperature dependence
of inelastic scattering length expressed as L_phi ~T^-0.3 suggests the
possibility for the presence of one-dimensional channels in the network due to
the formation of long Fe nanowires inside the tubes, which might introduce an
alignment in the random structure.Comment: 29 pages,10 figures, 2 tables, submitted to Phys. Rev.
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Remarkably high abundance of presolar grains in interplanetary dust particles collected from the comet Grigg-Skjellerup dust stream
Isotopic studies of IDPs collected from the comet Grigg-Skjellerup dust stream reveal extremely high abundances of presolar grains in two of four IDPs. These abundances exceed those of any other extraterrestrial material analyzed and support a cometary origin for these IDPs
Coordinated NanoSIMS and TEM Analysis of a Large 26Mg-Rich AGB Silicate from the Meteorite Hills 00426 CR2 Chondrite
Silicates are one of the most abundant presolar phases around evolved stars, in the inter-stellar medium (ISM), and in our Solar System. These grains afford the opportunity for O, Si, Mg, Fe, and Ca isotopic analyses to constrain stellar nucleosynthetic and mixing processes, and Galactic chemical evolution (GCE). While Mg and Fe isotopic studies have been successfully conducted on presolar silicates, isotopic analyses beyond O and Si are often hampered by the small grain sizes (average ~250 nm). This also makes coordinated mineral and chemical characterization challenging. These studies provide insight into the dust condensation conditions as well as subsequent alteration in the ISM and/or the Solar System. TEM studies of presolar silicates have shown that they are much more mineralogically and chemically diverse than other presolar phases [1 and references therein]. Large (>500nm) presolar silicate grains are rare, but they allow for detailed isotopic, mineral, and chemical characterization. We identified a large presolar silicate grain in the MET 00426 CR2 chondrite and report the O, Si, Mg, and Fe isotopic compositions and TEM study of this grain
Luby Transform Coding Aided Iterative Detection for Downlink SDMA Systems
A Luby Transform (LT) coded downlink Spatial Division Multiple Access (SDMA) system using iterative detection is proposed, which invokes a low-complexity near-Maximum-Likelihood (ML) Sphere Decoder (SD). The Ethernet-based Internet section of the transmission chain inflicts random packet erasures, which is modelled by the Binary Erasure Channel (BEC), which the wireless downlink imposes both fading and noise. A novel log-Likelihood Ratio based packet reliability metric is used for identifying the channel-decoded packets, which are likely to be error-infested. Packets having residual errors must not be passed on to the KT decoder for the sake of avoiding LT-decoding –induced error propagation. The proposed scheme is capable of maintaining an infinitesimally low packet error ratio in the downlink of the wireless Internet for Eb/n0 values in excess of about 3dB
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Relationship between the molecular composition, visible light absorption, and health-related properties of smoldering woodsmoke aerosols
Organic aerosols generated from the smoldering combustion of wood critically impact air quality and health for billions of people worldwide; yet, the links between the chemical components and the optical or biological effects of woodsmoke aerosol (WSA) are still poorly understood. In this work, an untargeted analysis of the molecular composition of smoldering WSA, generated in a controlled environment from nine types of heartwood fuels (African mahogany, birch, cherry, maple, pine, poplar, red oak, redwood, and walnut), identified several hundred compounds using gas chromatography mass spectrometry (GCMS) and nano-electrospray high-resolution mass spectrometry (HRMS) with tandem multistage mass spectrometry (MSn). The effects of WSA on cell toxicity as well as gene expression dependent on the aryl hydrocarbon receptor (AhR) and estrogen receptor (ER) were characterized with cellular assays, and the visible mass absorption coefficients (MACvis) of WSA were measured with ultraviolet-visible spectroscopy. The WSAs studied in this work have significant levels of biological and toxicological activity, with exposure levels in both an outdoor and indoor environment similar to or greater than those of other toxicants. A correlation between the HRMS molecular composition and aerosol properties found that phenolic compounds from the oxidative decomposition of lignin are the main drivers of aerosol effects, while the cellulose decomposition products play a secondary role; e.g., levoglucosan is anticorrelated with multiple effects. Polycyclic aromatic hydrocarbons (PAHs) are not expected to form at the combustion temperature in this work, nor were they observed above the detection limit; thus, biological and optical properties of the smoldering WSA are not attributed to PAHs. Syringyl compounds tend to correlate with cell toxicity, while the more conjugated molecules (including several compounds assigned to dimers) have higher AhR activity and MACvis. The negative correlation between cell toxicity and AhR activity suggests that the toxicity of smoldering WSA to cells is not mediated by the AhR. Both mass-normalized biological outcomes have a statistically significant dependence on the degree of combustion of the wood. In addition, our observations support the fact that the visible light absorption of WSA is at least partially due to charge transfer effects in aerosols, as previously suggested. Finally, MACvis has no correlation with toxicity or receptor signaling, suggesting that key chromophores in this work are not biologically active on the endpoints tested
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