Rhombohedral calcite precipitation from CO2-H2O-Ca(OH)2 slurry under supercritical and gas CO2 media

The formation of solid calcium carbonate (CaCO3) from aqueous solutions or slurries containing calcium and carbon dioxide (CO2) is a complex process of considerable importance in the ecological, geochemical and biological areas. Moreover, the demand for powdered CaCO3 has increased considerably recently in various fields of industry. The aim of this study was therefore to synthesize fine particles of calcite with controlled morphology by hydrothermal carbonation of calcium hydroxide at high CO2 pressure (initial PCO2=55 bar) and at moderate and high temperature (30 and 90 degrees C). The morphology of precipitated particles was identified by transmission electron microscopy (TEM/EDS) and scanning electron microscopy (SEM/EDS). In addition, an X-ray diffraction analysis was performed to investigate the carbonation efficiency and purity of the solid product. Carbonation of dispersed calcium hydroxide in the presence of supercritical (PT=90 bar, T=90 degrees C) or gaseous (PT=55 bar, T=30 degrees C) CO2 led to the precipitation of sub-micrometric isolated particles (<1$\mu$m) and micrometric agglomerates (<5$\mu$m) of calcite. For this study, the carbonation efficiency (Ca(OH)2-CaCO3 conversion) was not significantly affected by PT conditions after 24 h of reaction. In contrast, the initial rate of calcium carbonate precipitation increased from 4.3 mol/h in the "90bar-90 degrees C" system to 15.9 mol/h in the "55bar-30 degrees C" system. The use of high CO2 pressure may therefore be desirable for increasing the production rate of CaCO3, carbonation efficiency and purity, to approximately 48 kg/m3h, 95% and 96.3%, respectively in this study. The dissipated heat for this exothermic reaction was estimated by calorimetry to be -32 kJ/mol in the "90bar-90 degrees C" system and -42 kJ/mol in the "55bar-30 degrees C" system

Metodología para determinar la distribución de puntos de acceso a servicios de gobierno electrónico

Este trabajo es de interés para territorios en países en vías de desarrollo que tengan información escasa o limitada sobre la cual planificar Puntos de Acceso a Servicios (PAS). Está pensado para territorios que actualmente no cuenten con ningún o con escasos PAS y que estén interesados en aplicar esta estrategia para proveer de servicios a los ciudadanos de su territorio. Aquí se dan claves para tener una respuesta con base técnica para decidir cuántos PAS poner en el territorio y dónde ubicarlos. Ante la pregunta de ¿cómo realizar una distribución de puntos de acceso a servicios de gobierno electrónico sobre un territorio determinado?, este trabajo toma en cuenta tres variables: tamaño de la población, distancia entre poblaciones y costo de implantación de los puntos de acceso. Este proceso se basa en la teoría de localización de instalaciones y usa algoritmos genéticos como herramienta técnica. Se ha hecho la aplicación de esta metodología en dos contextos: el Municipio de Santa Elena (Ecuador) y en la provincia de Asturias (España). La selección de estos dos territorios se ha planteado para resaltar las diferencias de esfuerzos en la aplicación de una misma metodología en ambos contextos

“APLICACIÓN DE LA NUTRICIÓN EN LA ALIMENTACIÓN SUSTENTABLE Y EL PAPEL DEL NUTRIÓLOGO EN EL CUIDADO DEL MEDIO AMBIENTE”

La sustentabilidad se refiere a todo aquello que contribuye con las necesidades de las generaciones presentes sin colocar en riesgo las necesidades de las futuras generaciones. Esto quiere decir que se busca la manera de aprovechar de la mejor manera posible, los recursos con los que se cuenta, procurando que esos mismos se renueven o no se exploten en demasía para que futuras generaciones puedan aprovechar sus beneficios también. En cuanto a la nutrición, la sustentabilidad pretende que la dieta actual cumpla con los requisitos de ser equilibrada, variada, completa, suficiente, inocua y adecuada para cada individuo, procurando que los alimentos sean de la mayor calidad posible y buscando maneras de que no se afecte al ecosistema en la producción de los mismos. Por lo tanto, los hábitos alimenticios deben ser considerados saludables desde un punto de vista nutricional y ambientalmente compatibles. La salud es la principal preocupación de todos los seres humanos y la alimentación es parte inseparable de una buena salud. La producción y venta de alimentos ecológicos, y por lo tanto sustentables, vienen a dar respuestas a los consumidores y a la cada vez mayor atención que se presta a la alimentación en la actualidad. La alimentación sustentable consiste, principalmente, en buscar la manera de consumir productos orgánicos o ecológicos. Este tipo de productos son aquellos que son producidos sin pesticidas ni agroquímicos de síntesis y que son controlados durante toda la cadena productiva, de tal forma que se garantizan alimentos sanos para el consumidor y con grandes beneficios al ambiente antes, durante y después de su producción

Experimental assessment of CO2-mineral-toxic ion interactions in a simplified freshwater aquifer: Implications for CO2 leakage from deep geological storage

International audienceThe possible intrusion of CO2 into a given freshwater aquifer due to leakage from deep geological storage involves a decrease in pH, which has been directly associated with the remobilization of hazardous trace elements via mineral dissolution and/or via desorption processes. In an effort to evaluate the potential risks to potable water quality, the present study is devoted to experimental investigation of the effects of CO2 intrusion on the mobility of toxic ions in simplified equilibrated aquifers. We demonstrate that remobilization of trace elements by CO2 intrusion is not a universal physicochemical effect. In fact goethite and calcite, two minerals frequently found in aquifers, could successfully prevent the remobilization of adsorbed Cu(II), Cd(II), Se(IV) and As(V) if CO2 is intruded into a drinking water aquifer. Furthermore, a decrease in pH resulting from CO2 intrusion could reactivate the adsorption of Se(IV) and As(V) if goethite and calcite are sufficiently available in underground layers. Our results also suggest that adsorption of cadmium and copper could be promoted by calcite dissolution. These adsorbed ions on calcite are not remobilized when CO2 is intruded into the system, but it intensifies calcite dissolution. On the other hand, arsenite As(III) is significantly adsorbed on goethite, but is partially remobilized by CO2 intrusion

Gas-solid carbonation of Ca(OH)2 and CaO particles under non-isothermal and isothermal conditions by using a thermogravimetric analyzer: Implications for CO2 capture

International audienceThe gas-solid carbonation of alkaline sorbents has been actively investigated as an alternative method to CO2 capture from industrial combustion sources and CO2 contained in the air. This study has a two-fold objective: firstly, quantify the gas-solid carbonation extent and the carbonation kinetics of Ca(OH)2 and CaO; and secondly, propose a reaction mechanism of gas-solid carbonation for CaO under dry conditions (relative humidity close to 0), i.e., when the action of water is negligible. The main results of our study have revealed that a high proportion of Ca(OH)2 nanoparticles were transformed into CaCO3 particles by gas-solid carbonation (carbonation extent, >0.94) under non-isothermal conditions. Moreover, this gas-solid reaction requires low activation energy (Ea≈6kJ/mol) at a constant heating rate of 5 or 10K/min. A similar carbonation extent was determined for gas-solid carbonation of in-situ synthesized CaO under non-isothermal conditions. However, the gas-solid carbonation of CaO takes place in a broader temperature range, implying a more complex thermokinetic behavior (overlapping of carbonation regimes or steps). Concerning the gas-solid carbonation of Ca(OH)2 and CaO under isothermal conditions, a high carbonation extent (>0.9) was determined for CaO at 600 (873K) and 800°C (1073K). Conversely, the gas-solid carbonation of Ca(OH)2 particles was relatively low (<0.56) at 400°C (673K) after 6h of reaction. This case is in agreement with the formation of a dense non-porous layer of carbonate mineral around the core of the reacting Ca(OH)2 particles, thereby limiting the transfer of CO2. Finally, an alternative reaction mechanism is proposed for the gas-solid carbonation of CaO, when the relative humidity is close to 0. This macroscopic control at high temperature avoids CO2 dissociation with molecular water at the CaO-CO2 interface. For these specific conditions, the mineralization of adsorbed CO2 on CaO particles implies a solid state transformation, i.e., CaCO3 formation from CaO-CO2 interactions. This could be explained by an atomic excitation than at high temperature allows the local migration of one oxygen atom from the solid towards the adsorbed CO2 leading to its mineralization into carbonate (porous or non-porous layer) around the reacting particles; chemically the mineralization of CO2 also implies the breaking of one covalent bond in the CO2 molecule

No surviving evolved companions to the progenitor of supernova SN 1006

Type Ia supernovae are thought to occur as a white dwarf made of carbon and oxygen accretes sufficient mass to trigger a thermonuclear explosion$^{1}$. The accretion could occur slowly from an unevolved (main-sequence) or evolved (subgiant or giant) star$^{2,3}$, that being dubbed the single-degenerate channel, or rapidly as it breaks up a smaller orbiting white dwarf (the double- degenerate channel)$^{3,4}$. Obviously, a companion will survive the explosion only in the single-degenerate channel$^{5}$. Both channels might contribute to the production of type Ia supernovae$^{6,7}$ but their relative proportions still remain a fundamental puzzle in astronomy. Previous searches for remnant companions have revealed one possible case for SN 1572$^{8,9}$, though that has been criticized$^{10}$. More recently, observations have restricted surviving companions to be small, main-sequence stars$^{11,12,13}$, ruling out giant companions, though still allowing the single-degenerate channel. Here we report the result of a search for surviving companions to the progenitor of SN 1006$^{14}$. None of the stars within 4' of the apparent site of the explosion is associated with the supernova remnant, so we can firmly exclude all giant and subgiant companions to the progenitor. Combined with the previous results, less than 20 per cent of type Iae occur through the single degenerate channel.Comment: Published as a letter in Nature (2012 September 27

Precipitation of ordered dolomite via simultaneous dissolution of calcite and magnesite: New experimental insights into an old precipitation enigma

7International audienceIn the present study, we demonstrate that ordered dolomite can be precipitated via simultaneous dissolution of calcite and magnesite under hydrothermal conditions (from 100 to 200°C). The temperature and high-carbonate alkalinity have significantly co-promoted the dolomite formation. For example, when high-purity water was initially used as interacting fluid, only a small proportion of disordered dolomite was identified at 200°C from XRD patterns and FESEM observations. Conversely, higher proportion of ordered dolomite, i.e. clear identification of superstructure ordering reflections in XRD patterns, was determined when high-carbonate alkalinity solution was initially used in our system at the same durations of reaction. For this latter case, the dolomite formation is favorable therefrom 100°C and two kinetic steps were identified (1) proto-dolomite formation after about five days of reaction, characterized by rounded sub-micrometric particles from FESEM observations and by the absence of superstructure ordering reflections at 22.02 (101), 35.32 (015), 43.80 (021), etc. 2thetha on XRD patterns; (2) proto-dolomite to dolomite transformation, probably produced by a coupled dissolution-recrystallization process. Herein, the activation energy was estimated to 29 kJ/mol by using conventional Arrhenius linear-equation. This study provides new experimental conditions to which dolomite could be formed in hydrothermal systems. Temperature and carbonate alkalinity are particularly key physicochemical parameters to promote dolomite precipitation in abiotic systems

Rapid precipitation of magnesite micro-crystals from Mg(OH)2-H2O-CO2 slurry enhanced by NaOH and a heat-ageing step (from 20 to 90°C)

International audienceThis study proposes a simple and novel synthesis route for rhombohedral single crystals (90°C) and its synthesis requires several days or weeks depending on experimental conditions. For this reason, industrial-scale magnesite production has been limited. The proposed magnesite synthesis method, requiring only 48h and moderate temperature, could easily be extrapolated on an industrial scale. Moreover, a simple and novel synthesis route for the production of fine platy particles of hydromagnesite is reported, with synthesis requiring only 5h. Based on their chemical compositions and textural properties, there are potential applications for both minerals, for example as a mineral filler and/or as a flame-retardant

Gas-solid carbonation as a possible source of carbonates in cold planetary environments

International audienceCarbonates are abundant sedimentary minerals at the surface and sub-surface of the Earth and they have been proposed as tracers of liquid water in extraterrestrial environments. Their formation mechanism is since generally associated with aqueous alteration processes. Recently, carbonate minerals have been discovered on Mars' surface by different orbital or rover missions. In particular, the phoenix mission has measured from 1 to 5% of calcium carbonate (calcite type) within the soil (Smith P.H. et al., 2009). These occurrences have been reported in area were the relative humidity is significantly high (Boynton et al., 2009). The small concentration of carbonates suggests an alternative process on mineral grain surfaces (as suggested by Shaheen et al., 2010) than carbonation in aqueous conditions. Such an observation could rather point toward a possible formation mechanism by dust-gas reaction under current Martian conditions. To understand the mechanism of carbonate formation under conditions relevant to current Martian atmosphere and surface, we designed an experimental setup consisting of an infrared microscope coupled to a cryogenic reaction cell (IR-CryoCell setup). Three different mineral precursors of carbonates (Ca and Mg hydroxides, and a hydrated Ca silicate formed from Ca2SiO4), low temperature (from -10 to +30°C), and reduced CO2 pressure (from 100 to 2000 mbar) were utilized to investigate the mechanism of gas-solid carbonation at mineral surfaces. These mineral materials are crucial precursors to form Ca and Mg carbonates in humid environments (0 < relative humidity < 100%) at dust-CO2 or dust-water ice-CO2 interfaces. Our results reveal a significant and fast carbonation process for Ca hydroxide and hydrated Ca silicate. Conversely, only a moderate carbonation is observed for the Mg hydroxide. These results suggest that gas-solid carbonation process or carbonate formation at the dust-water ice-CO2 interfaces could be a currently active Mars' surface process. To the best of our knowledge, we report for the first time that calcium carbonate can be formed at a negative temperature (-10°C) via gas-solid carbonation of Ca hydroxide. We note that the carbonation process at low temperature (<0°C) described in the present study could also have important implications on the dust-water ice-CO2 interactions in cold terrestrial environments (e.g. Antarctic)